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    • 97. 发明公开
    • Inkjet inks
    • Tintenstrahltinten
    • EP1256608A2
    • 2002-11-13
    • EP02253169.3
    • 2002-05-07
    • Hewlett-Packard Company
    • Moffatt, John R.Tsang, Joseph W.
    • C09D11/00C09B67/08C09B67/22
    • C09D11/322C09B67/0008
    • A method for dispersing a pigment in an aqueous solution is provided. The method comprises: (a) providing the pigment, which is distinguished in having an azo group and either a β-diketo structure or a hydroxyl group, each conjugatively associated with the azo group; (b) treating a surface of the pigment with a base having sufficient strength (e.g., a pK a of at least 6) to generate a negative charge on the pigment; and (c) reacting the negatively charged pigment with either (1) a first hydrophilic molecule containing at least one functional group comprising a carbon-carbon double bond and a carbonyl that is alpha to the carbon-carbon double bond which reacts via addition to form a hydrophilic group on the pigment or (2) a second hydrophilic molecule containing at least one functional group selected from the group consisting of anionic functional groups, cationic functional groups, and zwitterionic functional groups and at least one suitable leaving group which reacts via substitution to form a hydrophilic group on the pigment. The treated pigment is rendered comparatively soluble in water-based inks, thereby eliminating the need for any dispersant to disperse the pigment.
    • 提供了将颜料分散在水溶液中的方法。 该方法包括:(a)提供颜料,其特征在于具有与偶氮基团偶联的偶氮基团和β-二酮结构或羟基基团; (b)用具有足够强度的碱(例如pKa至少为6)处理颜料的表面以在颜料上产生负电荷; 和(c)使带负电荷的颜料与(1)含有至少一个包含碳 - 碳双键的官能团的第一亲水性分子和通过加成反应形成的碳 - 碳双键的α的羰基反应 颜料上的亲水基团或(2)含有至少一个选自阴离子官能团,阳离子官能团和两性离子官能团的官能团的第二亲水分子和至少一个通过取代反应的合适的离去基团 在颜料上形成亲水基团。 经处理的颜料比较可溶于水性油墨,因此不需要任何分散剂来分散颜料。