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91. 发明公开

EP1506273A4 METHOD FOR CONTROLLING DEPOSITS IN THE FUEL REFORMER OF A FUEL CELL SYSTEM 审中-公开
标题翻译：用于控制存款燃料的燃料电池系统的改革者
公开(公告)号：EP1506273A4
公开(公告)日：2010-12-15
申请号：EP03755343
申请日：2003-05-01
申请人： CHEVRON ORONITE CO
发明人： DIECKMANN GUNTHER H , KRAMER JAMES D , CHERPECK RICHARD E
IPC分类号： C01B3/38 , C10L1/18 , C01B3/34 , C10G75/04 , C10L1/14 , C10L1/22 , C10L1/222 , C10L1/224 , C10L1/238 , C10L1/2383 , C10L10/00 , C10L10/04 , H01M8/06 , H01M8/10
CPC分类号： C10L10/04 , C01B3/382 , C01B2203/066 , C01B2203/1058 , C01B2203/1064 , C01B2203/1288 , C10L1/143 , C10L1/1905 , C10L1/238 , C10L1/2383 , C10L1/2387 , H01M8/0612
摘要： A method for controlling the deposits in the fuel vaporizer of a fuel reformer used to prepare a liquid hydrocarbon for use as a fuel in a fuel cell which comprises introducing into the fuel vaporizer a liquid hydrocarbon containing an effective deposit controlling amount of a nitrogen-containing detergent additive and a fuel composition suitable for use in a fuel cell which comprises a liquid hydrocarbon having a boiling range at atmospheric pressure falling between about 77 degrees F. (25 degrees C.) and about 437 degrees F. (225 degrees C.), a total sulfur content of less than 3 ppm, and containing an effective deposit controlling amount of a nitrogen-containing detergent additive.

92. 发明公开

EP2080735A4 HYDROGEN GAS SEPARATION METHOD AND SEPARATION APPARATUS 审中-公开
标题翻译：方法和装置分离氢气
公开(公告)号：EP2080735A4
公开(公告)日：2010-12-01
申请号：EP07830932
申请日：2007-10-31
申请人： SUMITOMO SEIKA CHEMICALS
发明人： HARUNA KAZUO , SASANO HIROAKI , SUMIDA TOSHIHIKO , FUKUSHIMA MAYUMI
IPC分类号： C01B3/56 , B01D53/04 , B01J20/18 , B01J20/20
CPC分类号： C01B3/382 , B01D53/047 , B01D2253/102 , B01D2253/108 , B01D2256/16 , B01D2259/40071 , B01D2259/403 , B01D2259/4146 , C01B3/56 , C01B2203/0244 , C01B2203/043 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048

93. 发明公开

EP2027909A3 Liners for ion transport membrane systems 审中-公开
标题翻译：内胆为Iontransport膜系统
公开(公告)号：EP2027909A3
公开(公告)日：2010-11-03
申请号：EP08162388.6
申请日：2008-08-14
申请人： Air Products and Chemicals, Inc.
发明人： Carolan, Michael Francis , Miller, Christopher Francis
IPC分类号： B01D53/22 , B01D53/04 , B01D67/00
CPC分类号： B01D53/22 , B01D53/228 , B01D63/06 , B01D63/08 , B01D2256/12 , B01D2313/14 , B01D2313/42 , B01D2317/02 , B01D2317/04 , C01B3/382 , C01B13/0251 , C01B13/0255 , C01B2203/0233 , C01B2203/0811 , C01B2203/143 , C01B2210/0046 , Y02P20/52
摘要： An ion transport membrane system comprising
(a) a pressure vessel (413) comprising an interior, an exterior, an inlet, an inlet conduit (415), an outlet, and an outlet conduit (421);
(b) a plurality of planar ion transport membrane modules (401,403,405,407) disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules;
(c) a gas manifold (445b) having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and
(d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.

94. 发明公开

EP2238084A1 WASTE WATER TREATMENT FROM A BIOMASS-TO-LIQUID PROCESS COMPRISING SYNTHESIS GAS PRODUCTION AND INTEGRATED FACTORY FACILITY 有权
标题翻译：从生物质液化和纸浆和/或纸张生产过程中，和一个集成的工厂废水的共同治疗
公开(公告)号：EP2238084A1
公开(公告)日：2010-10-13
申请号：EP08775215.0
申请日：2008-07-18
申请人： UPM-Kymmene Oyj
发明人： KUKKONEN, Petri , KNUUTTILA, Pekka , JOKELA, Pekka
IPC分类号： C02F11/10 , C02F9/00
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B3/52 , C01B13/0248 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0465 , C01B2203/048 , C01B2203/049 , C01B2203/1223 , C01B2210/0046 , C02F1/00 , C02F3/00 , C02F2101/34 , C02F2103/023 , C02F2103/16 , C02F2103/28 , C02F2103/365 , C10G2/30 , C10G2/32 , C10G3/00 , C10G3/50 , C10G45/58 , C10G2300/1003 , C10G2300/1011 , C10J3/00 , C10J2300/0916 , C10J2300/0959 , C10J2300/16 , C10J2300/1659 , C10J2300/1678 , C10J2300/169 , C10K1/101 , C10K3/04 , C10L1/04 , C10L2200/0469 , C10L2290/42 , C10L2290/54 , D21C11/0007 , D21C11/06 , Y02E20/16 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： Treatment of waste water from a biomass-to-liquid process, said process comprising producing synthesis gas from biomass and conversion of said synthesis gas into liquid hydrocarbons by a Fisher-Tropsch process. The waste waters obtained are purified in common with waste waters from another industrial process to which said biomass-to- liquid process is integrated, such as in forestry, power and/or heat generation, waste incineration or a process in a metal-, petrochemical and/or oil refining industry. The biomass-to-liquid. process and said another industrial process may have a common feed water process unit, a common cooling water process unit and a common waste water treatment unit. The waste water treatment process may comprise a biological purification process and said Fischer-Tropsch process may utilize a cobalt catalyst. An integrated factory comprising a biomass-to-liquid plant and another industrial facility in which both plants are connected to a common waste water treatment facilit is also described.

96. 发明公开

EP2233433A1 Process for generating electricity and for sequestering carbon dioxide 审中-公开
标题翻译：维尔法恩·祖尔·埃尔绍贡·冯·埃尔克特里奇
公开(公告)号：EP2233433A1
公开(公告)日：2010-09-29
申请号：EP09250831.6
申请日：2009-03-24
申请人： Hydrogen Energy International Limited
发明人： The designation of the inventor has not yet been filed
IPC分类号： C01B3/38 , C01B3/48 , C01B3/50
CPC分类号： C01B3/382 , C01B3/48 , C01B3/50 , C01B3/501 , C01B3/506 , C01B3/52 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/046 , C01B2203/0475 , C01B2203/0495 , C01B2203/06 , C01B2203/0894 , C01B2203/1235 , C01B2203/127 , C01B2203/148 , C01B2203/84 , F01K3/188 , Y02E20/344 , Y02P20/13 , Y02P30/30
摘要： A process for the production of carbon dioxide in concentrated form and electricity from a hydrocarbon feedstock said process comprising the steps of:
a) introducing an oxidant feed stream comprising oxygen or enriched air comprising at least 25 mole% oxygen (on a dry basis) and optionally steam and a fuel feed stream comprising methane and optionally hydrogen and/or steam to an autothermal reactor unit (ATR) for the production of synthesis gas wherein (i) the temperature of the fuel feed stream is in the range 350 to 700°C; and (ii) the molar ratio of oxygen contained in the oxidant feed stream to carbon (in hydrocarbons) in the fuel feed stream is from 0.45:1 to 0.85:1, preferably 0.55:1 to 0.7:1;
b) withdrawing a synthesis gas stream comprising methane, hydrogen, carbon monoxide, carbon dioxide, steam and optionally nitrogen from the ATR and heat exchanging the synthesis gas stream with at least one process stream selected from the group consisting of a water stream for the production of steam, a hydrocarbon feedstock, a pre-reformer feed stream, the fuel feed stream, a hydrogen stream, boiler feed water, a condensate stream, and steam for the production of superheated steam;
c) if necessary, introducing steam to the synthesis gas stream before passing at least a portion of the synthesis gas stream to a shift converter unit where the synthesis gas reacts with steam to generate additional carbon dioxide and hydrogen;
d) withdrawing a shift converted gas stream from the shift converter unit and heat exchanging the shift converted gas stream with at least one process stream selected from the group consisting of a hydrocarbon feedstock, a pre-reformer feed stream, the fuel feed stream, a hydrogen stream, boiler feed water, a condensate stream, water for the production of steam and steam for the production of superheated steam;
e) passing the shift converted gas stream to a carbon dioxide separation unit for the separation of a concentrated carbon dioxide stream from a hydrogen stream comprising hydrogen and optionally nitrogen;
f) combusting at least part of the hydrogen stream in a gas turbine wherein the gas turbine drives an electric generator thereby producing electricity and wherein combustion of the hydrogen stream generates an exhaust gas.
摘要翻译：一种用于从碳氢化合物原料生产浓缩二氧化碳和电的方法，所述方法包括以下步骤：a）引入氧化剂进料流，所述氧化剂进料流包含氧或含有至少25摩尔％氧（基于干燥的）的富集空气和任选的蒸汽和包含甲烷和任选的氢气和/或蒸汽的燃料进料流到用于生产合成气的自热反应器单元（ATR），其中（i）燃料进料流的温度在350-700℃的范围内 ; 和（ii）燃料进料流中氧化剂进料流中的氧与碳（在烃中）的摩尔比为0.45:1至0.85:1，优选0.55:1至0.7:1; b）从ATR中取出包含甲烷，氢气，一氧化碳，二氧化碳，蒸气和任选的氮气的合成气流，并用至少一种选自用于生产的水流的工艺流将所述合成气流热交换蒸汽，烃原料，预重整器进料流，燃料进料流，氢气流，锅炉给水，冷凝物流和用于生产过热蒸汽的蒸汽; c）如果需要，在将至少一部分合成气流送入转换器单元之前将合成气流引入合成气流中，其中合成气与蒸汽反应产生额外的二氧化碳和氢气; d）从所述换档转换器单元中取出换档转换气流并用至少一种选自烃原料，预重整器进料流，所述燃料进料流，氢气流，锅炉给水，冷凝水，用于生产蒸汽和蒸汽的水生产过热蒸汽; e）将转移后的气流送入二氧化碳分离装置，用于从浓氢气和任选的氮气分离浓缩二氧化碳流; f）在燃气轮机中燃烧至少部分氢气流，其中所述燃气轮机驱动发电机从而产生电力，并且其中所述氢气流的燃烧产生废气。

97. 发明公开

EP2223372A1 FUEL CELL-BASED PROCESS FOR GENERATING ELECTRICAL POWER 审中-公开
标题翻译：程序用于燃料电池的基础，产生电流
公开(公告)号：EP2223372A1
公开(公告)日：2010-09-01
申请号：EP08862575.1
申请日：2008-12-15
申请人： Shell Internationale Research Maatschappij B.V.
发明人： CUI, Jingyu , ENGWALL, Erik Edwin , JOSHI, Mahendra Ladharam , WELLINGTON, Scott Lee
IPC分类号： H01M8/06
CPC分类号： H01M8/0618 , C01B3/38 , C01B3/382 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/043 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/0833 , C01B2203/0844 , C01B2203/1058 , C01B2203/1258 , C01B2203/142 , C01B2203/86 , H01M8/04097 , H01M8/0625 , H01M8/0662 , H01M2008/1293 , Y02P30/30
摘要： The present invention is directed to a solid oxide fuel cell system for generating electrical power. The system comprises a solid oxide fuel cell, a reforming reactor, a hydrogen separation apparatus, and an anode exhaust conduit. The reforming reactor includes a reforming region in which a feed comprising one or more hydrocarbons may be steam reformed to produce a reformed product gas containing hydrogen. The hydrogen separation apparatus is located in the reforming reactor positioned to separate hydrogen from the reformed product gas produced in the reforming reactor. The hydrogen separation apparatus is operatively connected to the anode of the solid oxide fuel cell to provide hydrogen to the fuel cell as a fuel to be oxidized to produce electricity. The anode exhaust conduit is located in the reforming region of the reforming reactor and is operatively connected to the anode exhaust of the fuel cell so that hot anode exhaust exiting the fuel cell may pass through the anode exhaust conduit and exchange heat with reactants in the reforming region of the reforming reactor.

98. 发明公开

EP2197816A2 METHOD OF DIRECT SYNTHESIS OF LIGHT HYDROCARBONS FROM NATURAL GAS 有权转让
标题翻译：程序轻烃天然气直接合成
公开(公告)号：EP2197816A2
公开(公告)日：2010-06-23
申请号：EP08838757.6
申请日：2008-09-22
申请人： Korea Research Institute Of Chemical Technology
发明人： BAE, Jong-Wook , KANG, Suk-Hwan , LEE, Yun-Jo , JUN, Ki-won
IPC分类号： C07C1/04
CPC分类号： B01J29/146 , B01J29/072 , B01J29/24 , B01J29/46 , B01J29/68 , B01J2229/186 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0238 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/0475 , C01B2203/062 , C01B2203/0833 , C01B2203/1058 , C01B2203/1241 , C01B2203/1258 , C10G2/332 , C10G2/334 , C10G2300/1025 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y02P30/40
摘要： The present invention relates to a method of direct synthesis of light hydrocarbons from natural gas and carbon dioxide capable of improving production yield of light hydrocarbons and carbon utilization efficiency through a series of process of preparing synthesis gas with a predetermined molar ratio of carbon monoxide and hydrogen by a combined steam reforming of natural gas and carbon dioxide reforming of methane, performing Fischer-Tropsch reaction of the prepared synthesis gas in the presence of a specific catalyst, and recycling the byproducts of methane and carbon dioxide as the source material of the combined reforming.

99. 发明公开

EP2188210A2 VERFAHREN UND ANLAGE ZUR HERSTELLUNG VON SYNTHESEGAS AUS BIOGAS 审中-公开
标题翻译：方法和系统合成气体从沼气生产
公开(公告)号：EP2188210A2
公开(公告)日：2010-05-26
申请号：EP08785493.1
申请日：2008-08-12
申请人： DGE Dr.-Ing. Günther Engineering GmbH
发明人： GÜNTHER, Lothar
IPC分类号： C01B3/36 , C01B3/38 , C01B3/52 , C01B13/02 , B01D53/86 , B01D53/14 , B01D53/48 , B01D53/52
CPC分类号： C01B3/384 , B01D53/1462 , B01D53/526 , B01D53/84 , B01D53/96 , B01D2251/10 , B01D2253/112 , B01D2257/304 , B01D2257/504 , B01D2258/05 , C01B3/36 , C01B3/382 , C01B3/52 , C01B13/0259 , C01B2203/0233 , C01B2203/025 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/0811 , C01B2203/0822 , C01B2203/0872 , C01B2203/0894 , C01B2203/1258 , C01B2203/127 , C01B2203/142 , C01B2203/1604 , C01B2203/84 , C12M21/04 , C12M47/14 , C12M47/18 , C12P5/023 , Y02A50/2358 , Y02C10/02 , Y02C10/04 , Y02C10/08 , Y02E50/343 , Y02P20/128 , Y02P20/129 , Y02P20/152 , Y02P20/52 , Y02P20/59
摘要： The invention relates to a method for the production of synthethis gas made of biogas and a system suitable for carrying out the method. Based on the disadvantages of the known prior art, the invention seeks to provide a method characterized by means of a more economic process control and a higher yield. For this purpose the invention provides the solution that hydrogen sulfide and carbon dioxide of the biogas are nearly completely separated in separate cleaning steps before the catalytic conversion of the biogas, wherein hydrogen sulfide is biologically removed by means of the admixture of oxygen and/or oxidation agents containing oxygen. The oxygen, or the oxidation agent, is dosed such that an excess of oxygen of at least 1.0 vol.-% is present in the cleaned biogas (methane gas). The biogas is concentrated without any dehumidification, heated, and mixed with superheated steam. Due to the excess of oxygen thermal energy is additionally created during the reforming process by means of an exothermal oxidation of oxygen contained in the biogas together with hydrogen in the catalyst bed for the endothermal conversion of methane to synthethis gas.

100. 发明公开

EP2184260A1 Process to prepare a mixture of hydrogen and carbon monoxide 审中-公开
标题翻译： Verfahren zur Herstellung einer Mischung aus Wasserstoff und Kohlenmonoxid
公开(公告)号：EP2184260A1
公开(公告)日：2010-05-12
申请号：EP09174279.1
申请日：2009-10-28
申请人： Shell Internationale Research Maatschappij B.V.
发明人： Fernie, Martin John
IPC分类号： C01B3/36
CPC分类号： C01B3/36 , C01B3/382 , C01B13/02 , C01B13/0248 , C01B13/0251 , C01B2203/0233 , C01B2203/0255 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0894 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1288 , C01B2203/142 , C01B2203/84 , C01B2210/0046 , Y02P20/129 , Y02P20/131
摘要： The invention is directed to a process to prepare a mixture of hydrogen and carbon monoxide from a methane comprising gas. The following steps are performed:
(a) Partial oxidation of the methane comprising gas with an oxygen containing gas at a pressure of above 5 MPa thereby obtaining a raw syngas comprising carbon monoxide and hydrogen having a temperature of above 1100 °C,
(b) expanding the raw syngas in an high temperature/high pressure turbo- expander thereby recovering power and obtaining an expanded syngas having a pressure below 4 MPa and a temperature below 1050 °C,
(c) further cooling the expanded syngas to obtain the mixture of hydrogen and carbon monoxide having a temperature of between 100 and 500 °C.
摘要翻译：本发明涉及从包含甲烷的气体制备氢气和一氧化碳的混合物的方法。执行以下步骤：（a）在高于5MPa的压力下用含氧气体部分氧化包含气体，从而获得包含一氧化碳和氢的原始合成气，其温度高于1100℃，（b）在高温/高压涡轮膨胀机中膨胀粗合成气，从而回收功率并获得压力低于4MPa，温度低于1050℃的膨胀合成气，（c）进一步冷却膨胀合成气，得到氢气混合物和一氧化碳，其温度为100-500℃。

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