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    • 93. 发明公开
    • Method for producing diarylmethanes
    • Verfahren zur Herstellung von Diarylmethanen。
    • EP0428081A1
    • 1991-05-22
    • EP90121488.2
    • 1990-11-09
    • KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
    • Akatsu, MasahiroTakayama, HajimeMatsuoka, Takeshi
    • C07C15/16C07C2/86
    • C07C2/861C07C2529/08C07C2529/60C07C15/16
    • The present invention relates to a method for producing diarylmethanes represented by the following formula (III)
      wherein R¹ to R³ each stand for a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. This method comprises the reaction of a benzyl chloride represented by the following general formula (I) with benzene or an alkylbenzene represented by the following general formula (II):
      wherein R¹ to R³ have the same meanings as defined above. and is characterized in that the catalyst used is an HY or HL type zeolite having a SiO₂/Al₂O₃ molar ratio of 4 -­10 and an alkali metal content of 5% by weight or less, calculated as an alkali metal oxide, or a zeolite obtained by the exchange of said NY or HL type zeolite with cations of a di- or tri-valent metal.
    • 本发明涉及由下式(III)表示的二芳基甲烷的制造方法,其中R 1〜R 3各自表示氢原子或碳原子数1〜3的烷基。 该方法包括由以下通式(I)表示的苄基氯与由下列通式(II)表示的苯或烷基苯的反应:其中R 1至R 3具有相同的含义 如上所定义。 所用的催化剂是SiO 2 / Al 2 O 3摩尔比为4〜10,碱金属含量为5重量%以下的HY或HL型沸石,以碱金属氧化物计,或得到的沸石 通过所述NY或HL型沸石与二价或三价金属的阳离子交换。
    • 100. 发明公开
    • Process for the preparation of cross-linked polyarylene sulfide
    • 制备交联聚亚锡硫化物的方法
    • EP0344977A3
    • 1990-11-28
    • EP89305329.8
    • 1989-05-25
    • KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
    • Iizuka, YoHosokawa, ToshioItoh, YoshinobuYamamoto, ShinjiKusida, KazuoKatto, Takayuki
    • C08G75/02
    • C08G75/0254C08G75/0231
    • A process for the preparation of a granular polyarylene sulfide comprises:
      A) an initial-stage polymerization step for obtaining a polyarylene sulfide by reacting an alkali metal sulfide, a dihaloaromatic compound and a polyhaloaromatic compound, having three or more halogen substituents per molecule, in an organic amide solvent in the presence of from 0.5 to 2.9 moles of water per mol of said alkali metal sulfide at a temperature of from 180 to 235 o C until the total conversion ratio of said dihalo- and polyhaloaromatic compounds reaches from 50 to 98% and the melt viscosity of a polyarylene sulfide obtained is from 0.5 to 500 Pas (5 to 5,000 poise) measured at 310 o C and a shear rate of 1,200/second; (B) a temperature raising step in which, while adjusting the amount of water as necessary to from 2.5 to 7 moles per mol of fed alkali metal sulfide, the temperature is raised from the temperature of step (A) to 240 o C under such conditions that the melt viscosity of the polymer obtained at 240 o C is from 30 to 1000 Pas (300 to 10,000 poise) measured at 310 o C and a shear rate of 1,200/second and the temperature is further raised from 240 o C to the temperature for step (C) at a rate of from 10 to 100 o C/hour; and (C) a second-stage polymerization step for further continuing polymerisation at a temperature of from 245 to 290 o C until the melt viscosity of the final polyarylene sulfide product reaches a value not lower than 1 x 10⁴ Pas (1 x 10⁵ poise) measured at 330 o C and a shear rate of 2/second.