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    • 6. 发明公开
    • VERFAHREN ZUR GERBUNG VON TIERHÄUTEN UND DAMIT HERGESTELLTES, GEGERBTES LEDER
    • VERFAHREN ZUR GERBUNG VONTIERHÄUTENUND DAMIT HERGESTELLTES,GEGERBTES LEDER
    • EP3110978A1
    • 2017-01-04
    • EP15720592.3
    • 2015-02-25
    • Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
    • RENNER, ManfredWEIDNER, EckhardGEIHSLER, Helmut
    • C14C3/06C14C3/30
    • C14C3/06C14C3/30
    • The invention relates to a method for tanning hides, comprising the following steps: softening the hides in liquid at a pH value in a range of approximately 7 to approximately 10, unhairing the hides in liquid at a pH value of up to 13, dewatering the dripping-wet hides by 5 to 40 wt%, treating the moist hides in a pressure vessel at a pressure of 5 to 60 bar for a pressure treatment time of 60 to 360 minutes, wherein the pressure is built up by feeding carbon dioxide, introducing a tanning solution into the pressure vessel, wherein the mass of the tanning solution preferably corresponds at least substantially to the mass by which the dripping-wet hides have been dewatered in the dewatering step, lowering the pressure in the pressure vessel at least substantially continuously to ambient pressure over a pressure-relief time period of 15 to 90 minutes. Consequently, the method according to the invention leads to significantly reduced wastewater, and thus significantly reduced environmental impact, in relation to known tanning methods while achieving at least the same quality of the tanned leather.
    • 本发明涉及一种鞣制皮革的方法,包括以下步骤:将pH值在约7至约10的范围内软化液体中的皮革,将pH值高达13的液体中的皮革脱毛,脱水 滴湿湿皮5〜40重量%,在压力容器中以5〜60巴的压力处理湿皮,压力处理时间为60〜360分钟,其中压力通过进料二氧化碳,引入 鞣制溶液进入压力容器,其中鞣制溶液的质量优选至少基本上对应于脱水步骤中滴水湿皮已经脱水的质量,至少基本上连续地将压力容器中的压力降低至 减压时间为15〜90分钟时的环境压力。 因此,根据本发明的方法导致显着减少的废水,从而相对于已知的鞣制方法显着降低了环境影响,同时达到至少相同质量的鞣制的皮革。
    • 8. 发明公开
    • METHODS AND PRODUCTS USEFUL IN RECOVERING AND RECYCLING TANNINS
    • 方法和产品可用于回收和再循环宁静
    • EP1377711A1
    • 2004-01-07
    • EP02717658.5
    • 2002-03-15
    • McGraw, Wayne G.
    • McGraw, Wayne G.
    • D06P3/32C09B61/00C09B67/34C14C1/06C14C3/00C14C3/10
    • C14C3/32C14C3/10C14C3/30Y02W30/76
    • The present invention relates to a novel method of recovering and recycling active tannins from spent vegetable tanning liquors. Using a low molecular weight alcohol as the extraction agent produces an alcohol fraction or precipitate containing extracted active tannins, and leaves virtually all non-tannins in the aqueous phase of the spent tanning liquor. The methods and resulting chemical mixtures of the present invention have a variety of uses and applications. The method can be applied to freshly produced or aged spent vegetable tanning liquors. The methods are further applicable to dried forms of spent tanning liquors through aqueous reconstitution of dried ReTan, followed by alcohol extraction. The recovered chemical mixture contains recovered tannins which can be recycled through combination with fresh tanning liquors to form an improved tanning liquor.
    • 本发明涉及从废植物鞣革液中回收和再循环活性单宁的新方法。 使用低分子量醇作为提取剂产生含有提取的活性单宁的醇馏分或沉淀物,并且在废鞣液的水相中实际上留下所有非鞣质。 本发明的方法和所得的化学混合物具有各种用途和应用。 该方法可以应用于新鲜生产或陈年的植物鞣制液。 这些方法还可通过干燥的ReTan水溶液重建,然后进行酒精提取,应用于废晒黑液的干燥形式。 回收的化学混合物含有回收的丹宁酸,其可通过与新鲜鞣制液组合而再循环以形成改进的鞣液。