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1. 发明公开

EP3286333A1 HYDROPHOBIC NUCLEIC ACID SALTS AS SECURITY MARKERS 审中-公开
公开(公告)号：EP3286333A1
公开(公告)日：2018-02-28
申请号：EP16783711
申请日：2016-04-20
申请人： APDN (B V I ) INC
发明人： SZCZEPANIK MACIEJ B
IPC分类号： C12Q1/68 , C10L1/10 , C10L1/14 , C10L1/16 , C10L1/238 , C10L1/32 , G01N33/02 , G01N33/26 , G01N33/44
CPC分类号： C12Q1/6804 , C10L1/003 , C10L2270/026 , G01N33/02 , G01N33/26 , G01N33/44
摘要： The invention provides a method of marking a hydrophobic medium with a nucleic acid marker, the method includes: providing a trialkylammonium salt of the nucleic acid marker, a tetraalkylphosphonium salt of the nucleic acid marker or a tetraarylphosphonium salt of the nucleic acid marker; and incorporating the trialkylammonium salt of the nucleic acid marker, the tetraalkylphosphonium salt of the nucleic acid marker or the tetraarylphosphonium salt of the nucleic acid marker into the hydrophobic medium. The hydrophobic medium can be authenticated after shipping or recovery from the stream of commerce by detecting the nucleic acid marker in a sample of the hydrophobic medium.

2. 发明公开

EP3140381A1 TETRARYLMETHANE ETHERS AS FUEL MARKERS 有权
标题翻译：四分之一元素ALS BRENNSTOFFMARKER
公开(公告)号：EP3140381A1
公开(公告)日：2017-03-15
申请号：EP15722807.3
申请日：2015-04-21
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： GREEN, George David , SMITH, Warren E. , SWEDO, Raymond J.
IPC分类号： C10M171/00 , C07C43/205 , C10L1/00 , C10L1/185
CPC分类号： C10L1/1852 , C10L1/003 , C10L2230/16 , C10M171/007
摘要： A method for marking a petroleum hydrocarbon or a liquid biologically derived fuel by adding to the petroleum hydrocarbon or liquid biologically derived fuel a compound having formula C{Ph(R1)i(OR2)j}2{Ph(R3)m(OR4)n}{Ph(R5)o(OR6)p}, wherein Ph represents a benzene ring, R1, R3 and R5 independently are C1-C18 alkyl or C4-C18 heteroalkyl; R2, R4 and R6 independently are C1-C18 alkyl or C4-C18 heteroalkyl, i, j, m, n, o and p independently are zero, one or two. Each compound having formula C{Ph(R1)i(OR2)j}2{Ph(R3)m(OR4)n}{Ph(R5)o(OR6)p} is present at a level from 0.01 ppm to 20 ppm.
摘要翻译：通过向石油烃或液体生物衍生的燃料中加入具有式C {Ph（R 1）i（OR 2）j} 2 {Ph（R 3）m} {OR 4）的化合物来标记石油烃或液体生物衍生的燃料的方法）n} {Ph（R5）o（OR6）p}，其中Ph表示苯环，R1，R3和R5独立地为C1-C18烷基或C4-C18杂烷基; R2，R4和R6独立地为C1-C18烷基或C4-C18杂烷基，i，j，m，n，o和p独立地为0,1或2。具有式C {Ph（R 1）i（OR 2）j} 2 {Ph（R 3）m（OR 4）n} {Ph（R 5）o（0R 6）p}的化合物以0.01ppm至20ppm的水平存在。

3. 发明授权

EP2771439B1 USE OF DYE-STABLE BIOFUEL BLEND COMPOSITIONS 有权
标题翻译：使用颜色稳定BIO燃料混合组合物
公开(公告)号：EP2771439B1
公开(公告)日：2016-06-22
申请号：EP12778929.5
申请日：2012-10-18
申请人： ExxonMobil Research and Engineering Company
发明人： POIRIER, Marc-andre
IPC分类号： C10L1/00 , C10L1/183 , C10L1/14 , C10L1/226
CPC分类号： C10L1/003 , C10L1/14 , C10L1/183 , C10L1/226 , C10L2200/0438 , C10L2200/0446 , C10L2200/0476

4. 发明公开

EP2995606A1 TRITYLATED ETHERS 有权
公开(公告)号：EP2995606A1
公开(公告)日：2016-03-16
申请号：EP15187464.1
申请日：2013-04-26
申请人： Dow Global Technologies LLC
发明人： GREEN, George David , SWEDO, Raymond
IPC分类号： C07C43/23 , C10L1/00 , C10L1/185
CPC分类号： C10L1/1852 , C07C43/23 , C10L1/003 , C10L2200/0453 , C10L2230/16 , C10L2290/24
摘要： A compound having formula (Ph 3 C) m Ar(GR) n , wherein Ph represents a phenyl group, Ar is an aromatic ring system having from six to twenty carbon atoms; G is O, S, SO or SO 2 ; R is: (a) C 1 -C 18 alkyl substituted by at least one of OH, SH, C 1 -C 18 alkoxy and cyano; or (b) C 4 -C 18 heteroalkyl; m is one or two; and n is an integer from one to four.
摘要翻译：具有式（Ph 3 C）mAr（GR）n的化合物，其中Ph表示苯基，Ar是具有6至20个碳原子的芳族环系; G是O，S，SO或SO 2; R为：（a）被OH，SH，C1-C18烷氧基和氰基中的至少一个取代的C1-C18烷基; 或（b）C 4 -C 18杂烷基; m是一个或两个; 并且n是从1到4的整数。

5. 发明公开

EP2959290A1 ANALYTICAL METHOD FOR DETECTING FUEL MARKERS 有权
标题翻译：分析师VERFAHREN ZUR ERKENNUNG VON KRAFTSTOFFMARKERN
公开(公告)号：EP2959290A1
公开(公告)日：2015-12-30
申请号：EP14728762.7
申请日：2014-05-02
申请人： Dow Global Technologies LLC , Rohm and Haas Company
发明人： GRAS, Ronda L. , LUONG, Jim C. , SMITH, Warren E.
IPC分类号： G01N33/28 , G01N30/60 , C10L1/00
CPC分类号： G01N30/7206 , C10L1/003 , G01N30/463 , G01N30/465 , G01N30/6078 , G01N30/7233 , G01N30/88 , G01N33/28 , G01N33/2882 , G01N2030/042 , G01N2030/8854
摘要： A gas chromatographic method for detecting a marker compound in a fuel by (a) introducing a sample of fuel into a first capillary column coated with a stationary phase based on polydimethylsiloxane and allowing the sample to flow through the first column to produce a first effluent; (b) allowing the first effluent to pass through a detector and identifying a retention time range in it which includes a retention time of the marker compound; (c) introducing only a portion of the first effluent stream which is within the retention time range into a second capillary column coated with either (i) an ionic sorbent or (ii) a polyethylene glycol, and allowing said portion to flow through the second capillary column to produce a second effluent stream; and (d) allowing the second effluent to pass through a detector; wherein the marker compound has formula Ar(R
2 )
m (OR
1 )
n and is present in the fuel at a level from 0.01 ppm to 100 ppm.
摘要翻译：一种用于通过以下步骤来检测燃料中的标记化合物的气相色谱法：（a）基于聚二甲基硅氧烷将样品引入到具有固定相的第一毛细管柱中并使样品流过第一柱以产生第一流出物; （b）允许第一流出物通过检测器并鉴定其中包含标记化合物的保留时间的保留时间范围; （c）将仅在保留时间范围内的第一流出物流的一部分引入涂覆有（i）离子吸附剂或（ii）聚乙二醇的第二毛细管柱中，并允许所述部分流过第二流出物流毛细管柱以产生第二流出物流; 和（d）允许第二流出物通过检测器; 其中标记化合物具有式Ar（R 2）m（OR 1）n，并且以0.01ppm至100ppm的水平存在于燃料中。

6. 发明授权

EP2441745B1 Biphenyl benzyl ether marker compounds for liquid hydrocarbons and other fuels and oils 有权
标题翻译：对于液态烃和其他燃料和油联苯苄基标记化合物
公开(公告)号：EP2441745B1
公开(公告)日：2015-08-26
申请号：EP11183192.1
申请日：2011-09-28
申请人： Dow Global Technologies LLC
发明人： Green, George David , Swedo, Raymond John
IPC分类号： C07C43/205 , C10L1/18 , C10L1/00 , C10M171/00 , C10L1/185
CPC分类号： C10L1/003 , C07C43/2055 , C10L1/1852 , C10M171/007 , C10M2207/04 , C10N2240/56

7. 发明公开

EP2707467A1 TRITYLATED ETHERS 有权转让
标题翻译：维多利亚州VERFAHREN ZUR MARKIERUNG VONFLÜSSIGENBRENNSTOFFEN
公开(公告)号：EP2707467A1
公开(公告)日：2014-03-19
申请号：EP12731272.6
申请日：2012-06-22
申请人： ANGUS Chemical Company
发明人： GREEN, George D. , SWEDO, Raymond
IPC分类号： C10L1/185 , C07C43/20 , C10M129/16 , C10M171/00 , C10L1/00
CPC分类号： C07C43/2055 , C07C43/20 , C10L1/003 , C10L1/1852 , C10L2230/16 , C10L2270/026 , C10M129/16 , C10M2207/04 , C10N2230/10 , C10N2240/08 , C10N2270/00
摘要： A compound having formula (Ph
3 C)
m Ar(OR)
n , wherein Ph represents a phenyl group, Ar is an aromatic ring system having from six to twenty carbon atoms, R is C
1 -C
18 alkyl or C
7 -C
12 aralkyl, m is one or two, and n is an integer from one to four.
摘要翻译：具有式（Ph 3 C）mAr（OR）n的化合物，其中Ph表示苯基，Ar是具有6至20个碳原子的芳环体系，R是C 1 -C 18烷基或C 7 -C 12芳烷基，m是一个或两个，n是1到4的整数。

8. 发明公开

EP2707465A1 METHOD OF MARKING HYDROCARBON LIQUIDS 审中-公开
标题翻译：烃液标记方法
公开(公告)号：EP2707465A1
公开(公告)日：2014-03-19
申请号：EP12721898.0
申请日：2012-05-09
申请人： Johnson Matthey Public Limited Company
发明人： STUBBS, David , MCCALLIEN, Duncan William John
IPC分类号： C10L1/00
CPC分类号： C10L1/003 , C10L1/16 , C10L1/1608 , C10L1/201 , C10L1/202 , C10L2230/16 , G01N33/2882 , Y10T436/13
摘要： Method of marking a hydrocarbon liquid includes adding to the liquid, a tracer compound of Formula I or II: wherein at least one of R1-R6 in Formula I and at least one of R7-R14 in Formula II is selected from: i. a bromine or fluorine atom; ii. a partially or fully halogenated alkyl group; iii. a branched or cyclic C4-C20 alkyl group; iv. an aliphatic substituent linking two positions selected from R1-R6 in Formula I to one another or two positions selected from R7-R14 in Formula II to one another; or v. a phenyl group substituted with a halogen atom, an aliphatic group or halogenated aliphatic group and none of R1-R6 and none of R7-R14 being a sulphonate group or COOR15, where R15 represents H, C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, C3-C15 cycloalkyl or aryl.
摘要翻译：本发明涉及一种标记烃液体的方法，该方法包括向所述液体中添加式（I）或式（II）化合物作为示踪化合物的步骤：其中式（I）中的R 1 -R 6中的至少一个 I）中的至少一个和式（II）中的R 7 -R 14中的至少一个选自：i。溴或氟原子; II。部分或完全卤代的烷基; III。支链或环状C 4 -C 20烷基; IV。将选自式（I）中的R 1 -R 6的两个位置彼此连接或将选自式（II）中的R 7 -R 14的两个位置彼此连接的脂族取代基; 或v为被卤素原子，脂族基团或卤代脂族基团取代并且式（I）中的R 1 -R 6均不是磺酸酯基或式（II）中的R 7 -R 14都不是磺酸酯基的苯基或 COOR 15，其中R 15代表H，C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，C 3 -C 15环烷基或芳基。

9. 发明公开

EP2480639A1 DIPYRROMETHENES AND AZADIPYRROMETHENES AS MARKERS FOR PETROLEUM PRODUCTS 有权
标题翻译： Dipyrromethenes和AZADIPYRROMETHENE作为石油产品的标志物
公开(公告)号：EP2480639A1
公开(公告)日：2012-08-01
申请号：EP10760545.3
申请日：2010-09-21
申请人： Authentix, Inc.
发明人： FORSHEE, Philip , HUNDT, Greg, R. , CONROY, Jeffrey, L.
IPC分类号： C10L1/30 , C10L1/00
CPC分类号： C10L1/003 , C10L1/1824 , C10L1/1852 , C10L1/232 , C10L1/303 , G01N33/28
摘要： Marking a petroleum product includes adding a covert dye selected from the group consisting of azadipyrromethene dyes, dipyrromethene dyes, and any combination thereof to the petroleum product and distributing the dye in the petroleum product. A petroleum product selected for analysis may be spectroscopically analyzed for the presence of an azadipyrromethene dye, a dipyrromethene dye, or a combination thereof. A concentration of at least one azadipyrromethene or dipyrromethene dye present in the portion of the petroleum product may be determined to identify the petroleum product as counterfeit, adulterated, or authentic based on the determined concentration of the azadipyrromethene or dipyrromethene dye.

10. 发明公开

EP2441745A1 Biphenyl benzyl ether marker compounds for liquid hydrocarbons and other fuels and oils 有权
标题翻译：联苯基 - 苄基 - 马来酸酐化合物
公开(公告)号：EP2441745A1
公开(公告)日：2012-04-18
申请号：EP11183192.1
申请日：2011-09-28
申请人： ANGUS Chemical Company
发明人： Green, George David , Swedo, Raymond John
IPC分类号： C07C43/205 , C10L1/18 , C10L1/00
CPC分类号： C10L1/003 , C07C43/2055 , C10L1/1852 , C10M171/007 , C10M2207/04 , C10N2240/56
摘要： A compound having formula (I)

wherein G represents at least one substituent selected from the group consisting of C 1 -C 12 alkyl and C 1 -C 12 alkoxy.
摘要翻译：具有式（I）的化合物，其中G表示至少一个选自C 1 -C 12烷基和C 1 -C 12烷氧基的取代基。

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