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    • 2. 发明公开
    • PROCEDE DE COPRECIPITATION D'ACTINIDES A DES ETATS D'OXYDATION DISTINCTS ET PROCEDE DE PREPARATION DE COMPOSES MIXTES D'ACTINIDES
    • 不同氧化态的锕系元素共沉淀方法及其制备混合锕系化合物方法
    • EP1756839A1
    • 2007-02-28
    • EP05766696.8
    • 2005-05-26
    • COMMISSARIAT A L'ENERGIE ATOMIQUECOMPAGNIE GENERALE DES MATIERES NUCLEAIRES
    • GRANDJEAN, StéphaneBERES, AndréMAILLARD, ChristopheROUSSELLE, Jérôme
    • G21C3/62C01G56/00
    • G21C3/62C01G56/00C01G56/004G21C3/623Y02E30/38
    • The invention relates to a method for co-precipitation (or simultaneous preparation) of at least one actinide in oxidation state (IV) with at least one actinide in oxidation state (III), in which a mixed solution of actinide(s) in oxidation state (IV) and actinide(s) in oxidation state (III) is prepared with addition of either a mono-charged cation which stabilises the oxidation states in the mixture, or a mono-charged cation with no stabilizing role for the oxidation states in the mixture and a solution containing oxalate ions is added to said mixture of actinides to produce a co-precipitation, or simultaneous precipitation of said actinides of oxidation state (IV) and (III) and a fraction of the mono-charged cation. According to another embodiment, a mixed solution of actinide(s) in oxidation state (IV) and actinide(s) in oxidation state (III) is prepared and a solution containing oxalate ions and a mono-charged cation is added to said mixture of actinides to produce the co-precipitation. The invention further relates to mixed actinide compounds from calcination of the precipitate above. Said mixed compounds such as oxides, carbides or nitrides are particularly of use in the production of nuclear fuel, for the production of transmutation targets or for the stable storage of nuclear material.
    • 氧化态为至少一种锕系的共沉淀(或同时沉淀)法(IV)与氧化态(III)至少一种锕系元素,worin:一个溶液,即 在(IV)和氧化态(III)锕系元素(一个或多个)通过向它制备氧化态多种锕系元素的混合物中的单电荷阳离子,其存在使得有可能稳定在混合物中的前述的氧化态,或 单电荷阳离子,它不采取行动来稳定混合上述氧化态; 含草酸离子的溶液与锕系元素,以便在所说的混合物混合,进行共沉淀,即 同时沉淀,的所述氧化态(IV)和(III)和单电荷的阳离子的一部分锕系元素。 。根据另一实施例,即解 在氧化态氧化态多种锕系元素(IV)和锕系元素(一个或多个)的混合物(III)的制备和含草酸根离子的溶液和单电荷的阳离子添加到锕系元素的所述混合物,以进行 共沉淀。 为通过煅烧沉淀所有这一切都得到制备锕系元素的混合化合物的方法。 这些混合氧化物:例如混合的氧化物,氮化物或碳化物,可以使用爱特别是在核燃料中的嬗变目标的制造中的制造或核材料的稳定包装。