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    • 9. 发明公开
    • HYDROLYTICALLY STABLE POSTCROSSLINKED SUPERABSORBENTS
    • 水解后交联的超级吸收器
    • EP1856194A1
    • 2007-11-21
    • EP06708497.0
    • 2006-02-24
    • Evonik Degussa GmbH
    • HARREN, JörgISSBERNER, JörgWALDEN, MirkoTENI, RainerFURNO, FranckWERLE, PeterKRIMMER, Hans-peter
    • C08J3/24A61L15/22C08L33/02
    • C08J3/24C08F220/06C08J2333/02
    • The present invention relates to a process for producing postcrosslinked water-absorbing polymeric formations, comprising the steps of contacting water-absorbing polymeric formations P1 obtained by polymerization of ethylenically unsaturated acid-functional monomers or salts thereof in the presence of a crosslinker with a fluid F1 comprising a postcrosslinker, - heating the water-absorbing polymeric formations in contact with the fluid F1 to a temperature in a range from 40 to 300°C to obtain postcrosslinked water- absorbing polymeric formations P2, the water-absorbing polymeric formations P1 having a thermal stability, as determined in accordance with the test method described herein, of less than 3.0%. The invention also relates to water-absorbing polymeric formations, to the water-absorbing polymeric formations obtainable by this process, to water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers, to a composite comprising water-absorbing polymeric formations and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising water-absorbing polymeric formations or a composite, to the use of water-absorbing polymeric formations or of a composite in chemical products and also to the use of triallyl isocyanurate as an internal crosslinker in the production of water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers.