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    • 3. 发明公开
    • BESCHICHTUNGSSTOFFE, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG
    • BESCHICHTUNGSSTOFFE,VERFAHREN ZU IHRER HERSTELLUNG和IHRE VERWENDUNG
    • EP1590384A1
    • 2005-11-02
    • EP04703360.0
    • 2004-01-20
    • BASF Coatings AG
    • BAUMGART, HubertROTERS, AnnetteCOOK, VinceFARWICK, ThomasHASSE, SandraKETTELER, CorneliaRÖCKRATH, Ulrike
    • C08F220/00C08G18/80
    • C08G18/80C09D133/14C08L2666/20
    • Disclosed are coating materials comprising (A) at least one (meth)acrylate (co) polymer which contains hydroxyl groups and has a hydroxyl number of 100 to 250 mg KOH/g, an acid number of 0 to 35 mg KOH/g, a number average molecular weight Mn of 1'200 to 20'000 dalton and a maximum glass transition temperature of +70 °C, (B) at least one compound that contains carbamate groups and hydroxyl groups and has a hydroxyl number of 10 to 150 mg KOH/g, a carbamate equivalent weight CEW of 250 to 700 g/equivalent, and an equivalent ratio of hydroxyl groups to carbamate groups ranging between 1:20 and 1:0.5, and (C) at least one aminoplastic resin. (I) At least 10 equivalent percent of the hydroxyl groups contained in the (meth)acrylate (co)polymers (A) and/or in compounds (B) are primary hydroxyl groups, and (II) the coating material is provided with a storage module (E') in the rubber-elastic range of at least 1.5*107 Pa after hardening, the storage module E' being measured on homogeneous free films having a layer thickness of 40 ± 10 µm by means of dynamic mechanical thermal analysis (DMTA). Also disclosed are a method for producing the inventive coating materials and the use thereof.
    • 本发明公开了一种包衣材料,其包含(A)至少一种含羟基且羟值为100至250mg KOH / g,酸值为0至35mg KOH / g的(甲基)丙烯酸酯(共)聚合物, 数均分子量Mn为1'200至20'000道尔顿,最大玻璃化转变温度为+ 70℃,(B)至少一种含有氨基甲酸酯基团和羟基并且具有10至150mg羟基值的化合物 KOH / g,氨基甲酸酯当量CEW为250至700g /当量,羟基与氨基甲酸酯基团的当量比为1:20至1:0.5,和(C)至少一种氨基塑料树脂。 (I)(甲基)丙烯酸酯(共)聚合物(A)和/或化合物(B)中所含的羟基的至少10当量百分比是伯羟基,并且(II)涂料具有 (E')在硬化后至少为1.5×10 7 Pa的橡胶弹性范围内,储存模块E'通过动态力学热分析在层厚度为40±10μm的均匀自由膜上测量( DMTA)。 还公开了生产本发明涂料的方法及其用途。