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1. 发明公开

EP1470136A1 VERFAHREN ZUR ABTRENNUNG VON SÄUREN AUS CHEMISCHEN REAKTIONSGEMISCHEN MIT HILFE VON IONISCHEN FLÜSSIGKEITEN 有权
标题翻译：方法用于分离氨基酸而化学反应混合物中使用离子液体
公开(公告)号：EP1470136A1
公开(公告)日：2004-10-27
申请号：EP03704443.5
申请日：2003-01-21
申请人： BASF AKTIENGESELLSCHAFT
发明人： VOLLAND, Martin , SEITZ, Verena , MAASE, Matthias , FLORES, Miguel , PAPP, Rainer , MASSONNE, Klemens , STEGMANN, Veit , HALBRITTER, Klaus , NOE, Ralf , BARTSCH, Michael , SIEGEL, Wolfgang , BECKER, Michael , HUTTENLOCH, Oliver
IPC分类号： C07F9/22 , C07B63/00
CPC分类号： C07C403/12 , C07C1/30 , C07C45/50 , C07C51/412 , C07C51/58 , C07C67/14 , C07C2531/02 , C07C2601/16 , C07D295/185 , C07D317/36 , C07F9/142 , C07F9/145 , C07F9/46 , C07F9/4841 , C07F9/52 , C07F9/5721 , C07F9/5728 , C07F9/65038 , C07F9/65746 , C07F9/65848 , C07C47/02 , C07C13/23 , C07C69/78 , C07C69/24 , C07C69/14 , C07C53/10
摘要： Disclosed is a method for producing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphite diamides, aminophosphines, diaminophosphines, phosphite amide halogenides, and aminophosphine halogenides by separating an acid in the presence of an auxiliary base. Said auxiliary base b) forms a salt with an acid, which is liquid at temperatures at which the valuable product is not significantly decomposed during separation of the liquid salt, and c) the salt of the auxiliary base and the valuable product or the solution of the valuable product form two immiscible phases in a suitable solvent.

2. 发明公开

EP1678113A2 VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG VON ALDEHYDEN 有权
标题翻译：工艺醛连续生产
公开(公告)号：EP1678113A2
公开(公告)日：2006-07-12
申请号：EP04765959.4
申请日：2004-10-14
申请人： BASF Aktiengesellschaft
发明人： VOLLAND, Martin , MACKEWITZ, Thomas , AHLERS, Wolfgang , SCHÄFER, Ansgar , RICHTER, Wolfgang , PACIELLO, Rocco
IPC分类号： C07C45/50 , B01J31/24 , C07C47/02
CPC分类号： B01J31/186 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： The invention relates to a method for the continuous production of aldehydes comprising between 5 and 21 carbon atoms, by the isomerising hydroformylation in a homogenous phase of olefin compositions comprising between 4 and 20 carbon atoms and containing α-olefins and olefins with internal double bonds, by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. Said production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to said method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95 % conversion of the α-olefins is obtained. The hydroformylation product from the first reaction zone or group of several first reaction zones is then reacted in a subsequent reaction zone or group of several reaction zones at a total pressure of between 5 and 30 bar, using a synthesis gas with a CO/H2 molar ratio of between 1:4 and 1:1000. The total pressure in the subsequent reaction zone or zones is respectively 1 to (G1-Gf) bar lower than that of the preceding reaction zone, whereby G1 represents the total pressure in the respective preceding reaction zone and Gf represents the total pressure in the respective reaction zone that succeeds said first reaction zone or zones, with the proviso that the difference between G1 and Gf is greater than 1 bar and the partial CO pressure in the subsequent reaction zone or zones is respectively lower than that of the preceding reaction zone.

3. 发明授权

EP1470136B1 VERFAHREN ZUR ABTRENNUNG VON SÄUREN AUS CHEMISCHEN REAKTIONSGEMISCHEN MIT HILFE VON IONISCHEN FLÜSSIGKEITEN 有权
标题翻译：方法用于分离氨基酸而化学反应混合物中使用离子液体
公开(公告)号：EP1470136B1
公开(公告)日：2007-03-28
申请号：EP03704443.5
申请日：2003-01-21
申请人： BASF Aktiengesellschaft
发明人： VOLLAND, Martin , SEITZ, Verena , MAASE, Matthias , FLORES, Miguel Angel , PAPP, Rainer , MASSONNE, Klemens , STEGMANN, Veit , HALBRITTER, Klaus , NOE, Ralf , BARTSCH, Michael , SIEGEL, Wolfgang , BECKER, Michael , HUTTENLOCH, Oliver
IPC分类号： C07F9/22 , C07B63/00
CPC分类号： C07C403/12 , C07C1/30 , C07C45/50 , C07C51/412 , C07C51/58 , C07C67/14 , C07C2531/02 , C07C2601/16 , C07D295/185 , C07D317/36 , C07F9/142 , C07F9/145 , C07F9/46 , C07F9/4841 , C07F9/52 , C07F9/5721 , C07F9/5728 , C07F9/65038 , C07F9/65746 , C07F9/65848 , C07C47/02 , C07C13/23 , C07C69/78 , C07C69/24 , C07C69/14 , C07C53/10
摘要： Disclosed is a method for producing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphite diamides, aminophosphines, diaminophosphines, phosphite amide halogenides, and aminophosphine halogenides by separating an acid in the presence of an auxiliary base. Said auxiliary base b) forms a salt with an acid, which is liquid at temperatures at which the valuable product is not significantly decomposed during separation of the liquid salt, and c) the salt of the auxiliary base and the valuable product or the solution of the valuable product form two immiscible phases in a suitable solvent.
摘要翻译：一种用于使用辅助碱的除去从反应混合物中的酸处理，其中，所述辅助碱：与酸结合形成盐的所有其处的，其值的产品不除去液体盐的过程中显着分解温度下为液体，与有价值的产物或值在合适的溶剂中的产物的溶液中的辅助碱的盐形成两个不混溶的液相。

4. 发明公开

EP1689760A1 VERFAHREN ZUR ASYMMETRISCHEN SYNTHESE 有权
标题翻译：不对称合成过程
公开(公告)号：EP1689760A1
公开(公告)日：2006-08-16
申请号：EP04803259.3
申请日：2004-11-24
申请人： BASF Aktiengesellschaft
发明人： JÄKEL, Christoph , VOLLAND, Martin , MACKEWITZ, Thomas , PACIELLO, Rocco , BREIT, Bernhard , SEICHE, Wolfgang , WEIS, Martine , WALOCH, Christoph
IPC分类号： C07F9/58
CPC分类号： B01J31/18 , B01J31/182 , B01J31/1865 , B01J31/189 , B01J31/2273 , B01J31/2409 , B01J31/2452 , B01J31/2495 , B01J2231/32 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/341 , B01J2231/342 , B01J2231/44 , B01J2231/52 , B01J2231/543 , B01J2231/645 , B01J2531/0266 , B01J2531/0291 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/847 , C07B53/00 , C07F9/587 , C07F9/65719
摘要： The invention relates to a method for asymmetric synthesis in the presence of a chiral catalyst, comprising at least one complex of a metal of subgroup VIII of the periodic system with ligands that are capable of dimerizing via non-covalent bonds. The invention also relates to the corresponding catalysts and to the use thereof.

5. 发明公开

EP1807437A1 LIGANDEN ZUR ASYMMETRISCHEN HYDROFORMYLIERUNG 审中-公开
标题翻译：配体不对称氢甲酰化
公开(公告)号：EP1807437A1
公开(公告)日：2007-07-18
申请号：EP05799685.2
申请日：2005-10-25
申请人： BASF AKTIENGESELLSCHAFT
发明人： AHLERS, Wolfgang , EGEN, Martina , VOLLAND, Martin , JÄKEL, Christoph , HETTCHE, Frank , PACIELLO, Rocco
IPC分类号： C07F9/572
CPC分类号： B01J31/1855 , B01J31/186 , B01J31/2495 , B01J2231/32 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/342 , B01J2231/44 , B01J2231/52 , B01J2231/543 , B01J2231/643 , B01J2231/645 , B01J2531/0266 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07B2200/07 , C07C45/505 , C07C67/293 , C07F9/5721 , C07F9/5728 , C07F9/65848 , C07F15/008 , C07C47/14 , C07C47/277 , C07C49/86 , C07C47/24 , C07C47/228 , C07C69/003 , C07C69/007 , C07C69/14
摘要： The invention relates to chiral phosphorus chelate compounds, to catalysts comprising such a compound as the ligand, and to asymmetric synthesis methods in the presence of such a catalyst.

6. 发明公开

EP1539666A1 VERFAHREN ZUR HERSTELLUNG VON DIALDEHYDEN UND/ODER ETHYLENISCH UNGESÄTTIGTEN MONOALDEHYDEN DURCH HYDROFORMYLIERUNG ETHYLENISCH UNGESÄTTIGTER VERBINDUNGEN 有权
标题翻译：用于生产二醛和/或烯属不饱和一元醛通过氢甲酰化的烯属不饱和化合物的
公开(公告)号：EP1539666A1
公开(公告)日：2005-06-15
申请号：EP03748014.2
申请日：2003-09-12
申请人： BASF Aktiengesellschaft
发明人： VOLLAND, Martin , AHLERS, Wolfgang , EBEL, Klaus , PACIELLO, Rocco , RÖPER, Michael , MACKEWITZ, Thomas , BÖHM, Volker , SAVA, Xavier , LÖBER, Oliver , BEY, Oliver , STEPHAN, Jürgen , HAESE, Frank
IPC分类号： C07C45/50 , C07C47/21 , C07C47/12 , C07F9/6558
CPC分类号： C07F9/6596 , C07C45/50 , C07F9/5721 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07C47/12 , C07C47/21
摘要： The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.

7. 发明公开

EP1677911A1 STABILISIERUNG VON HYDROFORMYLIERUNGSKATALYSATOREN AUF BASIS VON PHOSPHORAMIDITLIGANDEN 有权
标题翻译：根据亚磷酰胺稳定价格氢甲酰化催化剂
公开(公告)号：EP1677911A1
公开(公告)日：2006-07-12
申请号：EP04790777.9
申请日：2004-10-22
申请人： BASF Aktiengesellschaft
发明人： PAPP, Rainer , AHLERS, Wolfgang , MACKEWITZ, Thomas , PACIELLO, Rocco , VOLLAND, Martin
IPC分类号： B01J31/02 , C07C45/50
CPC分类号： B01J31/186 , B01J2231/321 , B01J2531/0238 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： The invention relates to a method for the hydroformylation of ethylenically unsaturated compounds by reacting carbon monoxide and hydrogen in the presence of a catalytically active fluid containing a dissolved metal complex compound of a metal of the VIIIth subgroup of the periodic system of elements with at least one phosphoramide compound as a ligand, said fluid being brought into contact with a base.

8. 发明公开

EP1667950A1 VERFAHREN ZUR HERSTELLUNG VON 1,7-OCTADIEN UND DESSEN VERWENDUNG 审中-公开
标题翻译：用于生产1,7-辛二烯及其用途
公开(公告)号：EP1667950A1
公开(公告)日：2006-06-14
申请号：EP04765331.6
申请日：2004-09-17
申请人： BASF Aktiengesellschaft
发明人： BÖHM, Volker , RÖPER, Michael , STEPHAN, Jürgen , BENFER, Regina , SCHUBERT, Markus , KARL, Jörn , EBEL, Klaus , LÖBER, Oliver , VOLLAND, Martin
IPC分类号： C07C6/06 , C07C11/12 , C07C45/49 , C07C47/12 , C07C49/385
CPC分类号： C07C49/587 , C07C6/06 , C07C45/50 , C07C45/62 , C07C45/73 , C07C49/385 , C07C2521/04 , C07C2523/20 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/74 , C07C11/12 , C07C47/12 , C07C49/12
摘要： The invention relates to a method for the production of 1.7 octadiene by reacting metathesis of cyclohexene with ethylene. The invention also relates to the production of 1.10-decandiol by hydroformulating 1.7 octadiene produced according to said method. The invention further relates to a method for the production of muscone or olefinically unsaturated analogs thereof using 1.10 decandiol which is obtainable in said manner.

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