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1. 发明授权

EP2013302B1 AQUEOUS RADIATION CURABLE POLYURETHANE COMPOSITIONS 有权转让
公开(公告)号：EP2013302B1
公开(公告)日：2019-02-20
申请号：EP07727581.6
申请日：2007-03-30
申请人： Allnex Belgium S.A.
发明人： TIELEMANS, Michel , BONTINCK, Dirk , VAN OVERVELT, Jean-Claude
IPC分类号： C09D175/16

2. 发明授权

EP3063200B1 WATERBORNE CURING COMPOSITIONS FOR ELECTRODEPOSITION AND RADIATION CURING 有权转让
公开(公告)号：EP3063200B1
公开(公告)日：2019-01-16
申请号：EP14789244.2
申请日：2014-10-23
申请人： ALLNEX AUSTRIA GmbH , Allnex Belgium S.A.
发明人： PAAR, Willibald , TIELEMANS, Michel , PEETERS, Stephan
IPC分类号： C08F283/10 , C08G18/62 , C08G18/64 , C08G18/67 , C08G18/79 , C08G59/14 , C08G59/18 , C09D163/10 , C09D175/16 , C25D13/18 , C09D5/44 , C25D13/22

3. 发明授权

EP2598551B1 RADIATION CURABLE AQUEOUS COMPOSITIONS 有权转让
标题翻译：辐射固化水性组合物
公开(公告)号：EP2598551B1
公开(公告)日：2017-06-21
申请号：EP11733662.8
申请日：2011-07-12
申请人： Allnex Belgium, S.A.
发明人： TIELEMANS, Michel , BAURANT, Jean-Noël
IPC分类号： C08G18/67 , C09D175/16
CPC分类号： C08L33/14 , C08G18/6254 , C08G18/673 , C08G18/706 , C08G18/73 , C09D175/16 , Y10T428/31551

4. 发明公开

EP4015548A1 AQUEOUS BIO-BASED ENERGY CURABLE POLYURETHANE COMPOSITION 审中-公开
公开(公告)号：EP4015548A1
公开(公告)日：2022-06-22
申请号：EP20215276.5
申请日：2020-12-18
申请人： Allnex Belgium, S.A.
发明人： TIELEMANS, Michel
IPC分类号： C08G18/08 , C09D175/16 , C08G18/75 , C08G18/72 , C08G18/73 , C08G18/79 , C08G18/67 , C08G18/68
摘要： The invention is related to an aqueous bio-based energy-curable polyurethane composition comprising at least one ethylenically unsaturated polyurethane pre-polymer (A) obtained from the reaction of at least one aliphatic, cycloaliphatic or aromatic polyisocyanate compound (Ai), at least one hydrophilic compound (Aii) containing at least one reactive group capable to react with an isocyanate and which is capable to render the polyurethane pre-polymer dispersible in an aqueous medium either directly or after the reaction with an organic or inorganic neutralizing agent to provide a salt therefrom, at least one ethylenically unsaturated compound (Aiii), containing essentially one reactive group capable to react with an isocyanate, at least one ethylenically unsaturated compound (Aiv), containing at least two reactive groups capable to react with an isocyanate.

5. 发明授权

EP2545124B1 RADIATION CURABLE AQUEOUS COATING COMPOSITIONS 有权转让
标题翻译：辐射固化水性涂料组合物
公开(公告)号：EP2545124B1
公开(公告)日：2017-08-16
申请号：EP11708769.2
申请日：2011-03-04
申请人： Allnex Belgium S.A.
发明人： PEETERS, Stephan , DE MICHELI, Philippe , URBANO, Edmund , TIELEMANS, Michel
IPC分类号： C09D4/06 , C09D11/00 , C09D133/00 , C09D167/00 , C09D175/00
CPC分类号： C09D4/06 , C08G18/683 , C08G18/8175 , C08G63/47 , C09D11/101 , C09D133/14 , C09D135/00 , C09D167/07 , C09D175/14 , C09J167/07 , C08L67/00

6. 发明公开

EP3145972A1 RADIATION CURABLE AQUEOUS COMPOSITIONS WITH CONTROLLED POLYMER FLOW 有权转让
标题翻译： S EN S EN E E S S S S S S S S S S S S S S S S S
公开(公告)号：EP3145972A1
公开(公告)日：2017-03-29
申请号：EP15723934.4
申请日：2015-05-19
申请人： Allnex Belgium, S.A.
发明人： TIELEMANS, Michel , SALVIATO, Jean-Yves , BAURANT, Jean-Noël
IPC分类号： C08G18/67 , C08G18/73 , C08G18/81 , C08G18/08 , C08G18/22 , C08L75/16
CPC分类号： C09D175/16 , C08G18/0823 , C08G18/227 , C08G18/673 , C08G18/73 , C08G18/8175
摘要： Provided in the invention is an aqueous radiation curable composition (I) comprising : - at least one ethylenically unsaturated polyurethane (A) obtained from the reaction of at least one polyisocyanate compound (Ai); at least one ethylenically unsaturated compound (Aii) containing at least one reactive group capable to react with isocyanate groups; at least one hydrophilic compound (Aiii) containing at least one reactive group capable to react with isocyanate groups and at least one other group which is capable to render the polyurethane polymer dispersible in aqueous medium as such or after the formation of a salt; optionally, at least one polyol (Aiv); optionally, at least one further compound (Av) different from the polyol (Aiv) and comprising at least one reactive group capable to react with isocyanate groups; and optionally, at least one reactive electrophilic compound (Avi); said ethylenically unsaturated polyurethane (A) preferably being characterized by a molecular weight that is above 1,000 Daltons; - at least one ethylenically unsaturated polyurethane (B), different from the polyurethane (A), obtained from the reaction of at least one polyisocyanate compound (Bi); at least one ethylenically unsaturated compound (Bii) containing at least one reactive group capable to react with isocyanate groups; optionally, at least one polyol (Biv); optionally, at least one further compound (Bv) different from the polyol (Biv) and comprising at least one reactive group capable to react with isocyanate groups; and optionally, at least one reactive electrophilic compound (Bvi); said ethylenically unsaturated polyurethane (B) preferably being characterized by a molecular weight that is below 10,000 Daltons; and optionally, at least one ethylenically unsaturated compound (C) different from (A) and (B); wherein the radiation curable composition (I) in dry form has a steady-state creep viscosity η30, expressed as the apparent viscosity after a deformation time of 30 minutes with a load σ0 = 50 Pa at 23°C, that is above 1.10
3 Pa.s, more preferably above 1.10
4 Pa.s. Compositions (I) of the invention are characterized by a n improved creep viscosity r|3oand provide polymer materials with a good flow and mirror effect. In general these materials are less sensitive to dust pick-up and fingerprints. Further provided in the invention is a one-vessel solvent free process for preparing such materials.
摘要翻译：本发明提供一种水性可辐射固化组合物（I），其包含：至少一种由至少一种多异氰酸酯化合物（A 1）的反应得到的烯属不饱和聚氨酯（A）; 至少一种含有至少一个能够与异氰酸酯基团反应的反应性基团的烯属不饱和化合物（Aii）; 至少一种亲水性化合物（Aiii）含有至少一个能够与异氰酸酯基团反应的反应性基团和至少一种能够使聚氨酯聚合物本身在水性介质中分散或形成盐的其它基团; 任选地，至少一种多元醇（Aiv）; 任选地，至少一种不同于多元醇（Aiv）的另外的化合物（Av），并且包含至少一个能够与异氰酸酯基反应的反应性基团; 和任选的至少一种反应性亲电子化合物（Avi）; 所述烯键式不饱和聚氨酯（A）优选的特征在于分子量高于1,000道尔顿; - 至少一种由至少一种多异氰酸酯化合物（Bi）的反应得到的不同于聚氨酯（A）的烯属不饱和聚氨酯（B）; 至少一种含有至少一个能够与异氰酸酯基反应的反应性基团的烯属不饱和化合物（Bii）; 任选地，至少一种多元醇（Biv）; 任选地至少一种不同于多元醇（Biv）的另外的化合物（Bv），并且包含至少一个能够与异氰酸酯基反应的反应性基团; 和任选的至少一种反应性亲电子化合物（Bvi）; 所述烯键式不饱和聚氨酯（B）优选的特征在于分子量低于10,000道尔顿; 和 - 任选地至少一种不同于（A）和（B）的烯属不饱和化合物（C）; 其中干燥形式的可辐射固化组合物（I）具有稳态蠕变粘度·30，表示为在23℃下负载≥0.50的变形时间30分钟之后的表观粘度，高于1.10 3 Pa.s，更优选1.10 4 Pa.s 本发明的组合物（I）的特征在于改进的蠕变粘度·30，并提供具有良好流动性和镜面效果的聚合物材料。一般来说，这些材料对吸尘和指纹不那么敏感。本发明还提供了一种用于制备这种材料的单容器无溶剂方法。

7. 发明公开

EP3986948A1 BIOBASED URETHANE (METH)ACRYLATE FOR USE IN CLADDING 审中-公开
公开(公告)号：EP3986948A1
公开(公告)日：2022-04-27
申请号：EP20733271.9
申请日：2020-06-16
申请人： Allnex Belgium, S.A.
发明人： VAN HOLEN, Jurgen , VANMEULDER, Guido , TIELEMANS, Michel
IPC分类号： C08G18/24 , C08G18/32 , C08G18/67 , C08G18/81 , C09D175/16 , C08G18/79

8. 发明公开

EP2922625A1 PROCESS FOR THE PREPARATION OF COLLOIDAL POLYMERIZED PARTICLES 审中-公开
标题翻译：用于生产胶体聚合粒子
公开(公告)号：EP2922625A1
公开(公告)日：2015-09-30
申请号：EP13795707.2
申请日：2013-11-19
申请人： Allnex Belgium, S.A.
发明人： ROOSE, Patrice , TIELEMANS, Michel , SALVIATO, Jean-Yves , BAURANT, Jean-Noël , BERGIERS, Francis , PEETERS, Stephan
IPC分类号： B01J13/14 , C04B20/00 , C08F2/32 , C08F2/48
CPC分类号： B01J13/00 , B01J13/0021 , B01J13/0039 , C04B24/2641 , C04B24/281 , C04B24/282 , C04B24/283 , C04B24/286 , C04B24/32 , C08F2/48 , C08F2/50 , C08F283/006 , C08F283/008 , C08J3/28 , C08J2351/08 , C08J2375/16
摘要： The present invention relates to a process for the preparation of dipersions of colloidal polymerized particles and to the colloidal polymerized particles obtained and/or obtainable by the process as well as to their use.

9. 发明公开

EP2658934A1 RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：辐射固化组合物
公开(公告)号：EP2658934A1
公开(公告)日：2013-11-06
申请号：EP11799704.9
申请日：2011-12-21
申请人： Allnex Belgium, S.A.
发明人： SALVIATO, Jean-Yves , VAN HOLEN, Jurgen , TIELEMANS, Michel , DECAUX, Marc
IPC分类号： C09D175/16 , C08G18/08 , C08G18/34 , C08G18/42 , C08G18/66 , C08G18/67 , C08G18/76 , C08F283/00
CPC分类号： C09D175/16 , C08F283/008 , C08G18/0823 , C08G18/348 , C08G18/4238 , C08G18/6659 , C08G18/6705 , C08G18/765 , C08L33/00 , C08L2666/04
摘要： The present invention relates to an ethylenically unsaturated hydroxyl-terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and, optionally, at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; with (iv) at least one polyisocyanate (D) selected from a tetramethylxylenediisocyanate. The present invention further relates to dispersions in water containing same, to their production and uses.
摘要翻译：本发明涉及通过（i）至少一种含有至少两个能够与异氰酸酯基团反应的反应性基团和至少一个烯属不饱和基团的烯属不饱和化合物（A）反应获得的烯属不饱和羟基封端的聚氨酯（I）（ii）至少一种饱和醇组分（B），其包含：（iia）至少一种含有亲水基团的饱和羟基化化合物（B1），所述亲水基团能够使聚氨酯直接或在与中和剂反应之后分散于含水介质中，提供盐和任选的至少一种选自饱和聚酯多元醇（B21）和/或饱和聚碳酸酯多元醇（B22）的化合物（B2）; 和/或（iib）至少一种选自含有化合物（B1）部分的饱和聚酯多元醇（B31）和/或含有化合物（B1）部分的饱和聚碳酸酯多元醇（B32）的化合物（B3）和任选的一种或多种化合物（B1）和/或（B2）; （iii）任选地，至少一种烯属不饱和化合物（C），其基本上含有一个能够与异氰酸酯基团反应的反应性基团; 与（iv）至少一种选自四甲基二甲苯二异氰酸酯的聚异氰酸酯（D）。本发明进一步涉及含有它的水中的分散体，它们的生产和用途。

10. 发明公开

EP2658890A1 RADIATION CURABLE COMPOSITIONS 有权转让
标题翻译：辐射固化组合物
公开(公告)号：EP2658890A1
公开(公告)日：2013-11-06
申请号：EP11802359.7
申请日：2011-12-16
申请人： Allnex Belgium, S.A.
发明人： TIELEMANS, Michel , VAN HOLEN, Jurgen , DECAUX, Marc , SALVIATO, Jean-Yves
IPC分类号： C08G18/08 , C08G18/66 , C08G18/67 , C09D175/14 , C08F283/00 , C08F290/06
CPC分类号： C08G18/003 , C08F290/067 , C08G18/0823 , C08G18/0866 , C08G18/6659 , C08G18/675 , C09D4/00 , C09D175/14
摘要： The present invention provides for an ethylenically unsaturated hydroxyl- terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; and with (iv) at least one polyisocyanate (D). The present invention further relates to radiation curable coating compositions comprising same, to their preparation process and their uses.

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