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1. 发明授权

EP2490279B1 AROMATIC POLYMER ION EXCHANGE MEMBRANE AND ITS COMPLEX MEMBRANE AND ITS APPLICATION FOR ACIDIC ELECTROLYTE FLOW ENERGY STORAGE BATTERY 有权
标题翻译：芳香族聚合物离子交换膜及其复合膜及其在酸性电解液流动储能电池中的应用
公开(公告)号：EP2490279B1
公开(公告)日：2017-08-02
申请号：EP10823010.3
申请日：2010-06-25
申请人： Dalian Institute Of Chemical Physics, Chinese Academy of Sciences , Dalian Rongke Power Co., Ltd.
发明人： ZHANG, Huamin , LI, Xianfeng , DAI, Hua , BI, Cheng
IPC分类号： H01M8/18 , C08G73/18 , H01M8/103 , H01M8/1048 , H01M8/1051 , H01M8/1027 , H01M8/1032
CPC分类号： H01M8/103 , C08G73/18 , H01M8/1027 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/188 , Y02E60/521 , Y02E60/528

2. 发明公开

EP3214455A1 METHOD AND SYSTEM FOR MONITORING STATE OF CHARGE (SOC) OF FLOW BATTERY SYSTEM, FLOW BATTERY BASED ON REDUNDANCY DESIGN OF SOC DETECTION DEVICE, METHOD AND DEVICE FOR DETERMINING ACTUAL CAPACITY OF FLOW BATTERY, AND METHOD AND SYSTEM FOR ESTIMATING INPUT-OUTPUT CHARACTERISTIC OF FLOW BATTERY ALTERNATING CURRENT SIDE 有权
标题翻译：基于SOC检测装置的冗余设计的用于监测流动电池系统的充电状态（SOC）的方法和系统，用于确定流动电池的实际容量的方法和装置以及用于估计流量的输入 - 输出特性的方法和系统电池交流电流侧
公开(公告)号：EP3214455A1
公开(公告)日：2017-09-06
申请号：EP15856903.8
申请日：2015-11-03
申请人： Dalian Rongke Power Co., Ltd.
发明人： ZHANG, Yu , ZOU, Yi , ZHANG, Huamin , LI, Ying , WANG, Xiaoli , HAN, Xi , HAN, Lecong , ZHANG, Tao , MA, Xiangkun , ZHAO, Honggui
IPC分类号： G01R31/36
CPC分类号： H01M8/04611 , G01R31/3651 , H01M8/188 , H01M8/20 , H01M2250/10 , Y02E60/528
摘要： A method and system for monitoring a state of charge (SOC) of a flow battery system, flow battery based on a redundancy design of an SOC detection device, method and device for determining an actual capacity of the flow battery, and method and system for estimating an input-output characteristic of a flow battery alternating current side, the monitoring method comprising the following steps: determining SOCs of at least two pairs of different monitoring positions, any pair of monitoring positions being as followings: an inside of an anode electrolyte storage tank(2) and an inside of a cathode electrolyte storage tank(3), inside an anode electrolyte outlet pipeline(6) of a stack and inside a cathode electrolyte outlet pipeline(7) of the stack, or inside an anode electrolyte inlet pipeline(8) of the stack and inside a cathode electrolyte inlet pipeline(9) of the stack; and according to the SOCs respectively corresponding to each pair of monitoring positions, acquiring an SOC sum of a flow battery system. The method ensures acquiring an SOC monitoring result timely and accurately, thus facilitating an increase in a usage efficiency of a flow battery, extending the service life of the battery, and accurately managing a flow battery system.
摘要翻译：一种用于监测液流电池系统的充电状态（SOC）的方法和系统，基于SOC检测设备的冗余设计的液流电池，用于确定液流电池的实际容量的方法和设备以及用于估计液流电池交流侧的输入 - 输出特性，所述监测方法包括以下步骤：确定至少两对不同监测位置的SOC，任何一对监测位置如下：阳极电解质储存器（2）和阴极电解质储罐（3）的内部，在电池组的阳极电解液出口管线（6）内部和电池组的阴极电解液出口管线（7）内部，或在阳极电解液入口管线（8）并且在所述堆的阴极电解质入口管线（9）内; 根据分别对应每对监测位置的SOC，获取液流电池系统的SOCCsum。该方法可以及时准确地获取SOC监测结果，有利于提高液流电池的使用效率，延长电池的使用寿命，并且精确地管理液流电池系统。

3. 发明公开

EP3024080A4 ALL-VANADIUM REDOX FLOW BATTERY AND OPERATION METHOD THEREOF 有权
标题翻译： VANADIUM REDOX-DURCHFLUSSBATTERIE UND BETRIEBSVERFAHRENDAFÜR
公开(公告)号：EP3024080A4
公开(公告)日：2017-03-22
申请号：EP14825952
申请日：2014-07-15
申请人： DALIAN RONGKE POWER CO LTD
发明人： GAO XINLIANG , ZHANG HUAMIN , WANG XIAOLI , LIU RUONAN , LI YING , ZHAO YELONG , LIN ZEQING
IPC分类号： H01M8/18
CPC分类号： H01M8/188 , Y02E60/528
摘要： An all-vanadium redox flow battery and an operation method thereof, which belong to the field of flow batteries. The all-vanadium redox flow battery comprises a positive electrolyte and a negative electrolyte. A total vanadium ratio of the positive electrolyte and the negative electrolyte is maintained at the following ratio: positive electrolyte: negative electrolyte =1:1.5-1:1.2. Both the positive electrolyte and negative electrolyte comprise additives, the concentration of the additives being 0.01mol/L-0.5mol/L. the additive is at least one selected from sulfuric acid, sulfate, phosphoric acid, phosphate, pyrophosphate, and polyphosphate. The all-vanadium redox flow battery can operate with high-energy-density, and can also significantly reduce the irreversible discharge capacity attenuation caused by a hydrogen evolution side-reaction.
摘要翻译：属于流动电池领域的全钒氧化还原液电池及其操作方法。全钒氧化还原液流电池包括正电解质和负电解质。正电解质和负电解质的总钒比保持在以下比例：正电解质：负电解质= 1：1.5-1：1.2。正电解质和负电解质都包含添加剂，添加剂的浓度为0.01mol / L-0.5mol / L。添加剂是选自硫酸，硫酸盐，磷酸，磷酸盐，焦磷酸盐和多磷酸盐中的至少一种。全钒氧化还原液流电池可以以高能量密度工作，并且还可以显着降低由析氢反应引起的不可逆放电容量衰减。

4. 发明公开

EP2650947A4 USE OF POROUS MEMBRANE AND COMPOSITE MEMBRANE THEREOF IN REDOX FLOW ENERGY STORAGE BATTERY 审中-公开
标题翻译：使用其在氧化还原液流电池的多孔膜和复合膜BACK
公开(公告)号：EP2650947A4
公开(公告)日：2014-05-21
申请号：EP11846749
申请日：2011-07-08
申请人： DALIAN CHEMICAL PHYSICS INST , DALIAN RONGKE POWER CO LTD
发明人： ZHANG HUAMIN , LI XIANFENG , ZHANG HONGZHANG , SHI DINGQIN
IPC分类号： H01M2/16 , C08J5/22 , H01M2/14 , H01M8/02 , H01M8/10 , H01M8/18 , H01M8/20
CPC分类号： H01M8/0293 , C08J5/22 , C08J5/2293 , C08J2327/16 , H01M8/1018 , H01M8/1067 , H01M8/1088 , H01M8/188 , H01M8/20 , Y02E60/521 , Y02E60/528 , Y02P70/56

5. 发明公开

EP3534444A1 ELECTRODE STRUCTURE OF FLOW BATTERY, FLOW BATTERY STACK, AND SEALING STRUCTURE FOR FLOW BATTERY STACK 有权
公开(公告)号：EP3534444A1
公开(公告)日：2019-09-04
申请号：EP17869180.4
申请日：2017-11-03
申请人： Dalian Rongke Power Co., Ltd.
发明人： LIU, Shenglin , JIANG, Hongdong , ZHANG, Huamin , MA, Xiangkun , ZHANG, Tao , JIANG, Shan , YANG, Zhenkun , SUN, Dan , YI, Kuanrong
IPC分类号： H01M4/86
摘要： An electrode structure of a flow battery, a flow battery stack, and a sealing structure of the flow battery stack, wherein the density of the vertical tow in the electrode fiber is larger than the density of the parallel tow. In the electrode fiber per unit volume, the quantity ratio of the vertical tow to the parallel tow is at least 6:4. The electrode structure is composed of an odd number of layers of the electrode fibers, and the porosity of other layers is larger than the porosity of the center layer. The electrode structure is mainly composed of the vertical tows perpendicular to the surface of the electrode, so that, firstly, the contact area between the outer surface of the electrode and the adjacent component can be increased and the contact resistance can be reduced, secondly, the electrode is endowed with good mechanical properties, compared with the original structure, the contact resistance of such structure is reduced by 30%-50%; and the layers of the electrode have different thickness depending on the porosity, after compression, the layers with optimized thickness have a consistent porosity, this compressed uniform structure avoids uneven mass transfer phenomena when the electrolyte flows through the electrode, and reduces the concentration polarization of the battery and thereby improving the battery energy output under the given power.

6. 发明公开

EP3024080A1 ALL-VANADIUM REDOX FLOW BATTERY AND OPERATION METHOD THEREOF 有权
标题翻译：钒液流电池和操作之方法
公开(公告)号：EP3024080A1
公开(公告)日：2016-05-25
申请号：EP14825952.6
申请日：2014-07-15
申请人： Dalian Rongke Power Co., Ltd.
发明人： GAO, Xinliang , ZHANG, Huamin , WANG, Xiaoli , LIU, Ruonan , LI, Ying , ZHAO, Yelong , LIN, Zeqing
IPC分类号： H01M8/18
CPC分类号： H01M8/188 , Y02E60/528
摘要： An all-vanadium redox flow battery and an operation method thereof, which belong to the field of flow batteries. The all-vanadium redox flow battery comprises a positive electrolyte and a negative electrolyte. A total vanadium ratio of the positive electrolyte and the negative electrolyte is maintained at the following ratio: positive electrolyte: negative electrolyte =1:1.5-1:1.2. Both the positive electrolyte and negative electrolyte comprise additives, the concentration of the additives being 0.01mol/L-0.5mol/L. the additive is at least one selected from sulfuric acid, sulfate, phosphoric acid, phosphate, pyrophosphate, and polyphosphate. The all-vanadium redox flow battery can operate with high-energy-density, and can also significantly reduce the irreversible discharge capacity attenuation caused by a hydrogen evolution side-reaction.

7. 发明公开

EP3627168A1 FLOW BATTERY BASED ON REDUNDANCY DESIGN OF SOC DETECTION DEVICES 有权
公开(公告)号：EP3627168A1
公开(公告)日：2020-03-25
申请号：EP19208348.3
申请日：2015-11-03
申请人： Dalian Rongke Power Co., Ltd.
发明人： ZHANG, Yu , ZOU, Yi , ZHANG, Huamin , LI, Ying , WANG, Xiaoli , HAN, Xi , HAN, Lecong , ZHANG, Tao , MA, Xiangkun , ZHAO, Honggui
IPC分类号： G01R31/36 , H01M8/18 , H01M8/20 , H01M8/04537 , H01M10/48
摘要： A method and system for monitoring a state of charge (SOC) of a flow battery system, flow battery based on a redundancy design of an SOC detection device, method and device for determining an actual capacity of the flow battery, and method and system for estimating an input-output characteristic of a flow battery alternating current side, the monitoring method comprising the following steps: determining SOCs of at least two pairs of different monitoring positions, any pair of monitoring positions being as followings: an inside of an anode electrolyte storage tank(2) and an inside of a cathode electrolyte storage tank(3), inside an anode electrolyte outlet pipeline(6) of a stack and inside a cathode electrolyte outlet pipeline(7) of the stack, or inside an anode electrolyte inlet pipeline(8) of the stack and inside a cathode electrolyte inlet pipeline(9) of the stack; and according to the SOCs respectively corresponding to each pair of monitoring positions, acquiring an SOC sum of a flow battery system. The method ensures acquiring an SOC monitoring result timely and accurately, thus facilitating an increase in a usage efficiency of a flow battery, extending the service life of the battery, and accurately managing a flow battery system.

8. 发明授权

EP3024080B1 ALL-VANADIUM REDOX FLOW BATTERY AND OPERATION METHOD THEREOF 有权
公开(公告)号：EP3024080B1
公开(公告)日：2019-09-04
申请号：EP14825952.6
申请日：2014-07-15
申请人： Dalian Rongke Power Co., Ltd.
发明人： GAO, Xinliang , ZHANG, Huamin , WANG, Xiaoli , LIU, Ruonan , LI, Ying , ZHAO, Yelong , LIN, Zeqing
IPC分类号： H01M8/18

9. 发明公开

EP3246720A1 METHOD AND SYSTEM FOR DETERMINING THE STATE OF CHARGE OF FLOW BATTERY SYSTEM 有权
标题翻译：用于确定流动电池系统的电荷状态的方法和系统
公开(公告)号：EP3246720A1
公开(公告)日：2017-11-22
申请号：EP17173863.6
申请日：2015-11-03
申请人： Dalian Rongke Power Co., Ltd.
发明人： ZHANG, Yu , ZHANG, Huamin , ZOU, Yi , LI, Ying , WANG, Xiaoli , HAN, Xi , HAN, Lecong , ZHANG, Tao , MA, Xiangkun , ZHAO, Honggui
IPC分类号： G01R31/36 , H01M8/18 , H01M8/20 , H01M8/04537 , H01M10/48
摘要： A method and system for monitoring a state of charge (SOC) of a flow battery system, flow battery based on a redundancy design of an SOC detection device, method and device for determining an actual capacity of the flow battery, and method and system for estimating an input-output characteristic of a flow battery alternating current side, the monitoring method comprising the following steps: determining SOCs of at least two pairs of different monitoring positions, any pair of monitoring positions being as followings: an inside of an anode electrolyte storage tank(2) and an inside of a cathode electrolyte storage tank(3), inside an anode electrolyte outlet pipeline(6) of a stack and inside a cathode electrolyte outlet pipeline(7) of the stack, or inside an anode electrolyte inlet pipeline(8) of the stack and inside a cathode electrolyte inlet pipeline(9) of the stack; and according to the SOCs respectively corresponding to each pair of monitoring positions, acquiring an SOC sum of a flow battery system. The method ensures acquiring an SOC monitoring result timely and accurately, thus facilitating an increase in a usage efficiency of a flow battery, extending the service life of the battery, and accurately managing a flow battery system.
摘要翻译：一种用于监测液流电池系统的充电状态（SOC）的方法和系统，基于SOC检测设备的冗余设计的液流电池，用于确定液流电池的实际容量的方法和设备以及用于估计液流电池交流侧的输入 - 输出特性，所述监测方法包括以下步骤：确定至少两对不同监测位置的SOC，任何一对监测位置如下：阳极电解质储存器（2）和阴极电解质储罐（3）的内部，在电池组的阳极电解液出口管线（6）内部和电池组的阴极电解液出口管线（7）内部，或在阳极电解液入口管线（8）并且在所述堆的阴极电解质入口管线（9）内; 根据分别对应每对监测位置的SOC，获取液流电池系统的SOCCsum。该方法可以及时准确地获取SOC监测结果，有利于提高液流电池的使用效率，延长电池的使用寿命，并且精确地管理液流电池系统。

10. 发明公开

EP2490279A4 AROMATIC POLYMER ION EXCHANGE MEMBRANE AND ITS COMPLEX MEMBRANE AND ITS APPLICATION FOR ACIDIC ELECTROLYTE FLOW ENERGY STORAGE BATTERY 有权
标题翻译：芳香聚合物离子交换膜的研制及生物复合膜和本国对电力的蓄电池酸电解液流应用
公开(公告)号：EP2490279A4
公开(公告)日：2014-04-30
申请号：EP10823010
申请日：2010-06-25
申请人： DALIAN CHEMICAL PHYSICS INST , DALIAN RONGKE POWER CO LTD
发明人： ZHANG HUAMIN , LI XIANFENG , DAI HUA , BI CHENG
IPC分类号： H01M8/10 , C08G73/18 , H01M8/18
CPC分类号： H01M8/103 , C08G73/18 , H01M8/1027 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/188 , Y02E60/521 , Y02E60/528

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