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1. 发明授权

US5077396A Azo compounds containing two 6-hydroxypyrid-2-one coupling component radicals the nitrogen atoms of which are linked by a biscationic radical 失效
标题翻译：含有两个6-羟基吡啶-2-酮偶联组分的AZO化合物可以通过双相辐射连接的氮原子
公开(公告)号：US5077396A
公开(公告)日：1991-12-31
申请号：US523161
申请日：1990-05-14
申请人： Helmut A. Moser , Roland Wald
发明人： Helmut A. Moser , Roland Wald
IPC分类号： C09B44/08 , C03C25/10 , C09B33/12 , C09B44/10 , D21H21/28
CPC分类号： C09B33/12 , C03C25/102 , C09B44/105 , D21H21/28 , Y10S534/02
摘要： Compounds of the formula ##STR1## wherein each A is independently linear or branched C.sub.2-6 alkylene or linear or branched C.sub.3-6 alkylene substituted by hydroxy,each D is independently the radical of a diazo component of the benzene, azobenzene or naphthalene series, E is a divalent radical attached to each --N.sup..sym. R.sub.3 R.sub.4 -- radical through an aliphatic carbon atom,each R.sub.1 is independently hydrogen, C.sub.1-4 alkyl, cyclohexyl, phenyl or phenyl(C.sub.1-2 alkyl),each R.sub.2 is independently hydrogen, cyano, --COOR.sub.5, --CONR.sub.6 R.sub.7 or ##STR2## wherein R.sub.5 is hydrogen, C.sub.1-4 alkyl or phenyl(C.sub.1-2 alkyl),each of R.sub.6 and R.sub.7 is independently hydrogen or C.sub.1-4 alkyl,each R.sub.8 is independently C.sub.1-4 alkyl, and r is 0, 1, 2 or 3,each R.sub.3 is independently C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl,each R.sub.4 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl,each An.sup..crclbar. is a non-chromophoric anion, and n is 0, 1, 2, 3, 4, 5 or 6,with the proviso that the negative charges of the An.sup..crclbar. 's balance the positive charge of each cationic group of the molecule not balanced by the negative charge of an anionic group of the molecule, compositions containing them and their use for dyeing and printing hydroxy group- or nitrogen-containing organic substances.
摘要翻译：其中每个A独立地是直链或支链C 2-6亚烷基或被羟基取代的直链或支链C 3-6亚烷基的化合物，每个D独立地是苯，偶氮苯或萘系的重氮组分的基团，E是每个R 1独立地是氢，C 1-4烷基，环己基，苯基或苯基（C 1-2烷基），每个R 2独立地是氢，氰基， COOR 5，-CONR 6 R 7或者其中R 5是氢，C 1-4烷基或苯基（C 1-2烷基），R 6和R 7各自独立地是氢或C 1-4烷基，R 8独立地是C 1-4烷基，r是0， 1,2或3，每个R 3独立地是C 1-4烷基或被卤素，氰基，羟基或苯基单取代的C 1-4烷基，每个R 4独立地是氢，C 1-4烷基或被卤素，氰基，羟基或苯基单取代的C 1-4烷基，每个An（ - ）是非发色阴离子，n是0,1,2,3,4,5或6，条件是阴性 An（ - ）的e电荷平衡了分子的每个阳离子基团的正电荷，不受分子的阴离子基团的负电荷，含有它们的组合物和它们用于染色和印刷羟基或氮的用途含有机物质。

2. 发明授权

US3852261A O-6-hydroxypyridone-2 dyes bearing a cationic group in the 3-position 失效
标题翻译：在3位置承载阳离子基团的O-6-羟基吡啶二酮
公开(公告)号：US3852261A
公开(公告)日：1974-12-03
申请号：US8760270
申请日：1970-11-06
申请人： SANDOZ AG
发明人： STEINEMANN W
IPC分类号： C09B29/42 , C09B44/08 , C09B44/10
CPC分类号： C09B44/105 , C09B29/3621 , C09B29/3626 , C09B44/08
摘要： Azo dyes of the formula WHEREIN D is carbocyclic or heterocyclic aryl, R is hydrogen or an organic radical, R1 is hydrogen, hydrocarbyl, heterocyclyl, amino or substituted amino, K is substituted ammonium or hydrazinium (including compounds wherein the nitrogen(s) is (are) part of a heterocyclic ring), and A is an anion. These azo dyes are useful for the dyeing and printing of fibers (and textiles thereof) of acrylonitrile polymers and copolymers as well as polyamides and polyesters containing acidic groups. They give level dyeings having good fastness to light and water.
摘要翻译：式WHEREIN D的偶氮染料是碳环或杂环芳基，R是氢或有机基团，R 1是氢，烃基，杂环基，氨基或取代的氨基，K +是取代的铵或腙（包括其中氮（ s）是杂环的（部分）），并且A 1 - 是阴离子。

3. 发明授权

US09458142B2 Substituted quinones or analogues as colouring agents 有权
标题翻译：取代的醌或类似物作为着色剂
公开(公告)号：US09458142B2
公开(公告)日：2016-10-04
申请号：US14651747
申请日：2013-11-14
申请人： MERCK PATENT GMBH
发明人： Thomas Rudolph , Rene Peter Scheurich
IPC分类号： A61Q5/10 , C07D405/12 , C07D213/69 , A61Q5/06 , C07D309/40 , A61K8/49 , C09B23/14 , C09B29/036 , C09B29/08 , C09B44/10 , C09B55/00 , C09B57/08 , C09B1/26 , A61Q5/12 , A61Q17/04
CPC分类号： C07D405/12 , A61K8/49 , A61K8/4926 , A61K8/498 , A61Q5/06 , A61Q5/10 , A61Q5/12 , A61Q17/04 , C07D213/69 , C07D309/40 , C09B1/26 , C09B23/145 , C09B23/148 , C09B29/0037 , C09B29/081 , C09B29/0811 , C09B44/103 , C09B44/105 , C09B55/003 , C09B57/08
摘要： The invention relates to protein-adhesive dyes, to the preparation thereof and to preparations comprising same, and to a method for coloring keratin-containing fibers, in particular for coloring human hair.
摘要翻译：本发明涉及蛋白质粘合剂染料，其制备方法和包含其的制剂，以及用于着色含角蛋白的纤维，特别是用于着色人发的方法。

4. 发明授权

US08523990B2 Ink composition, inkjet recording ink composition, ink set, ink cartridge, inkjet recording method and recorded matter 有权
标题翻译：油墨组合物，喷墨记录油墨组合物，油墨组，墨盒，喷墨记录方法和记录物
公开(公告)号：US08523990B2
公开(公告)日：2013-09-03
申请号：US12999233
申请日：2009-06-15
申请人： Shigeaki Tanaka , Keiichi Tateishi , Takashi Ozawa
发明人： Shigeaki Tanaka , Keiichi Tateishi , Takashi Ozawa
IPC分类号： C09D11/02
CPC分类号： C09B44/105 , C09B7/00 , C09B43/16 , C09B56/08 , C09B56/20 , C09B67/0041 , C09B67/0055 , C09D11/328 , Y10T428/24802
摘要： An ink composition having a suitably-adjusted hue and causing no decomposition of dyes during storage is provided. The ink composition contains a compound (a) represented by the following formula (1), an ingredient (c) and moisture-retentive agents, characterized by being from 0.1 mass % to lower than 7.0 mass % in content of the compound represented by the formula (1), 10.0 mass % or lower in content of a moisture-retentive agent having 3 or more hydroxyl groups (b) and lower than 30.0 in molar ratio of the moisture-retentive agent having 3 or more hydroxyl groups to the compound represented by the formula (1): wherein each of Ar1 and Ar2 preferably represents an aromatic heterocyclic group, each of A1 and A2 represents a hydrogen atom or a substituent, Y represents —OM or —NR1R2, M represents a hydrogen atom or a metal ion and each of R1 and R2 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group or the like. The ingredient (c) is at least one compound selected from C.I. Direct Yellow 59, id. 86, id. 132 or the like.
摘要翻译：提供了具有适当调节的色调并且在储存期间不会分解染料的油墨组合物。油墨组合物含有由下式（1）表示的化合物（a），成分（c）和保湿剂，其特征在于，由以下化合物表示的化合物的含量为0.1质量％以上且低于7.0质量％式（1），具有3个以上羟基（b）且低于30.0的具有3个以上羟基的保湿剂的保湿剂相对于所表示的化合物的保湿剂的含量为10.0质量％以下式（1）中，Ar 1和Ar 2优选表示芳香族杂环基，A 1和A 2分别表示氢原子或取代基，Y表示-OM或-NR 1 R 2，M表示氢原子或金属离子 R 1和R 2各自表示氢原子，烷基，芳基，杂环基等。成分（c）是选自C.I.的至少一种化合物。直接黄色59，id。 86，id。 132等。

5. 发明公开

EP2098573A3 Basic monoazo compounds 审中-公开
标题翻译：碱性单偶氮化合物
公开(公告)号：EP2098573A3
公开(公告)日：2009-10-07
申请号：EP09150723.6
申请日：2009-01-16
申请人： Clariant International Ltd.
发明人： Hasemann, Ludwig
IPC分类号： C09B29/01 , C09B44/06 , C09B44/08 , C09B29/36 , C09D11/02
CPC分类号： C09B44/08 , C09B44/105 , C09D11/328
摘要： The invention relates to basic bisazo compounds according to formula (I)

wherein all substituents are defined as in Claim 1, their production, their use as dyestuffs as well as material dyed with these dyestuffs.
摘要翻译：本发明涉及根据式（I）的碱性双偶氮化合物，其中所有取代基如权利要求1中所定义，它们的生产，它们作为染料的用途以及用这些染料染色的材料。

6. 发明授权

EP0482508B1 Biskationische Azofarbstoffe sowie deren Zwischenprodukte 失效
标题翻译：双阳离子偶氮染料及其中间体。
公开(公告)号：EP0482508B1
公开(公告)日：1995-07-12
申请号：EP91117713.7
申请日：1991-10-17
申请人： BASF Aktiengesellschaft
发明人： Ruske, Manfred , Mayer, Udo, Dr.
IPC分类号： C09B44/10 , C07D401/04 , C07D401/14
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C09B44/105

7. 发明申请

US20150315177A1 SUBSTITUTED QUINONES OR ANALOGUES AS COLOURING AGENTS 有权
标题翻译：替代品或作为着色剂的模拟物
公开(公告)号：US20150315177A1
公开(公告)日：2015-11-05
申请号：US14651747
申请日：2013-11-14
申请人： MERCK PATENT GMBH
发明人： Thomas RUDOLPH , Rene Peter SCHEURICH
IPC分类号： C07D405/12 , A61Q5/10 , A61K8/49 , C07D309/40 , C07D213/69
CPC分类号： C07D405/12 , A61K8/49 , A61K8/4926 , A61K8/498 , A61Q5/06 , A61Q5/10 , A61Q5/12 , A61Q17/04 , C07D213/69 , C07D309/40 , C09B1/26 , C09B23/145 , C09B23/148 , C09B29/0037 , C09B29/081 , C09B29/0811 , C09B44/103 , C09B44/105 , C09B55/003 , C09B57/08
摘要： The invention relates to protein-adhesive dyes, to the preparation thereof and to preparations comprising same, and to a method for colouring keratin-containing fibres, in particular for colouring human hair.
摘要翻译：本发明涉及蛋白质粘合染料，其制备方法和包含其的制剂，以及用于着色含角蛋白的纤维，特别是用于着色人发的方法。

8. 发明申请

US20110104458A1 INK COMPOSITION, INKJET RECORDING INK COMPOSITION, INK SET, INK CARTRIDGE, INKJET RECORDING METHOD AND RECORDED MATTER 有权
标题翻译：墨水组合物，喷墨记录墨水组合物，墨盒，墨盒，喷墨记录方法和记录事项
公开(公告)号：US20110104458A1
公开(公告)日：2011-05-05
申请号：US12999233
申请日：2009-06-15
申请人： Shigeaki Tanaka , Keiichi Tateishi , Takashi Ozawa
发明人： Shigeaki Tanaka , Keiichi Tateishi , Takashi Ozawa
IPC分类号： B32B3/10 , C09D11/02 , B05D5/00
CPC分类号： C09B44/105 , C09B7/00 , C09B43/16 , C09B56/08 , C09B56/20 , C09B67/0041 , C09B67/0055 , C09D11/328 , Y10T428/24802
摘要： An ink composition having a suitably-adjusted hue and causing no decomposition of dyes during storage is provided. The ink composition contains a compound (a) represented by the following formula (1), an ingredient (c) and moisture-retentive agents, characterized by being from 0.1 mass % to lower than 7.0 mass % in content of the compound represented by the formula (1), 10.0 mass % or lower in content of a moisture-retentive agent having 3 or more hydroxyl groups (b) and lower than 30.0 in molar ratio of the moisture-retentive agent having 3 or more hydroxyl groups to the compound represented by the formula (1): wherein each of Ar1 and Ar2 preferably represents an aromatic heterocyclic group, each of A1 and A2 represents a hydrogen atom or a substituent, Y represents —OM or —NR1R2, M represents a hydrogen atom or a metal ion and each of R1 and R2 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group or the like. The ingredient (c) is at least one compound selected from C.I. Direct Yellow 59, id. 86, id. 132 or the like.
摘要翻译：提供了具有适当调节的色调并且在储存期间不会分解染料的油墨组合物。油墨组合物含有由下式（1）表示的化合物（a），成分（c）和保湿剂，其特征在于，由以下化合物表示的化合物的含量为0.1质量％以上且低于7.0质量％式（1），具有3个以上羟基（b）且低于30.0的具有3个以上羟基的保湿剂的保湿剂相对于所表示的化合物的保湿剂的含量为10.0质量％以下式（1）中，Ar 1和Ar 2优选表示芳香族杂环基，A 1和A 2分别表示氢原子或取代基，Y表示-OM或-NR 1 R 2，M表示氢原子或金属离子 R 1和R 2各自表示氢原子，烷基，芳基，杂环基等。成分（c）是选自C.I.的至少一种化合物。直接黄色59，id。 86，id。 132等。

9. 发明授权

US5424404A Biscationic azo dyes and intermediates therefor 失效
标题翻译：无色偶氮染料及其中间体
公开(公告)号：US5424404A
公开(公告)日：1995-06-13
申请号：US75019
申请日：1993-06-11
申请人： Manfred Ruske , Udo Mayer
发明人： Manfred Ruske , Udo Mayer
IPC分类号： C09B44/16 , C07D521/00 , C09B44/10 , D06P1/08 , D21H21/28 , C09B35/031 , C09B44/08 , C09B57/00 , D06P1/41
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C09B44/105
摘要： Biscationic azo dyes useful for dyeing or printing polymeric material have the formula ##STR1## where R.sup.1 is hydrogen or unsubstituted or phenyl-substituted C.sub.1 -C.sub.5 -alkyl,R.sup.2 is hydrogen or C.sub.1 -C.sub.5 -alkyl,R.sup.3 and R.sup.4 are independently of each other hydrogen or methyl,D is the radical of a diazo component, unsubstituted or substituted phenylene or a radical of the formula ##STR2## where Z is a bridge member, Y is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.2 -C.sub.6 -alkylene, xylidene or phenylene,An.sup..crclbar. is one equivalent of an anion,m is 1 or 2, andn is 1 or 2,
摘要翻译：可用于染色或印刷聚合物材料的无色偶氮染料具有式“IMAGE”，其中R 1是氢或未取代的或苯基取代的C 1 -C 5 - 烷基，R 2是氢或C 1 -C 5 - 烷基，R 3和R 4彼此独立地氢或甲基，D是重氮组分的基团，未取代或取代的亚苯基或下式的基团，其中Z是桥连构件，Y是氢，C 1 -C 18烷基，C 2 -C 6亚烷基，亚
甲基或亚苯基，An（ - ）是1当量的阴离子，m为1或2，n为1或2，

10. 发明授权

US5919914A Clathrate of bis �6-hydroxy-4-methyl-5-(3-methyl-imidazolium-1-yl) -3-(phen-4-ylazo) pyridin-2-one! ethylene and an aromatic compound 失效
标题翻译：双[6-羟基-4-甲基-5-（3-甲基 - 咪唑鎓-1-基）-3-（苯基-4-基偶氮）吡啶-2-酮]乙烯和芳族化合物的包合物
公开(公告)号：US5919914A
公开(公告)日：1999-07-06
申请号：US42808
申请日：1998-03-17
申请人： Manfred Ruske , Peter Erk , Heidi Hengelsberg
发明人： Manfred Ruske , Peter Erk , Heidi Hengelsberg
IPC分类号： C07D521/00 , C09B44/10 , C09B44/16 , C09B67/00 , C09B67/32 , C09B67/54 , C09B29/42 , C09B29/09 , C09B29/22 , C09B29/36
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C09B44/105 , C09B44/16 , C09B67/0028 , C09B67/0075 , C09B67/0096
摘要： Clathrates of bis�6-hydroxy-4-methyl-5-(3-methyl-imidazolium-1-yl)-3-(phen-4-ylazo)pyridin-2-one!ethylene with aromatics of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -hydroxyalkyl, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -hydroxyalkoxy, C.sub.1 -C.sub.10 -alkyl which is interrupted by 1, 2 or 3 non-neighboring oxygen atoms and is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.10 -alkoxy which is interrupted by 1, 2 or 3 non-neighboring oxygen atoms and is unsubstituted or substituted by hydroxyl, or is C.sub.1 -C.sub.6 -alkanoyl, hydroxy, carboxyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, phenylcarbonyl or C.sub.1 -C.sub.6 -alkenyl andR.sup.2 is R.sup.1, hydrogen or phenoxy,a process for their preparation and their use for the preparation of formulations of the dye.
摘要翻译：双[6-羟基-4-甲基-5-（3-甲基 - 咪唑鎓-1-基）-3-（苯基-4-基偶氮）]吡啶-2-酮]乙烯与通式I的芳族化合物的包合物其中R 1是C 1 -C 5 - 烷基，C 1 -C 5 - 羟基烷基，C 1 -C 5 - 烷氧基，C 1 -C 5 - 羟基烷氧基，被1,2或3个不相邻氧原子间隔的C1-C10-烷基，并且是未取代的或被羟基取代，被1,2或3个不相邻氧原子间隔的未被取代或被羟基取代的C1-C10-烷氧基，或是C1-C6-烷酰基，羟基，羧基，C1-C6-烷氧基羰基，苯基羰基或C 1 -C 6 - 烯基，R 2为R 1，氢或苯氧基，其制备方法及其用于制备染料配方的用途。

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