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    • 2. 发明申请
    • HIGH TEMPERATURE STABLE WATER SWELLABLE RUBBER COMPOSITION
    • 高温稳定水可膨胀橡胶组合物
    • WO2013158487A1
    • 2013-10-24
    • PCT/US2013/036345
    • 2013-04-12
    • ZEON CHEMICALS L.P.
    • CHOI, SoobumJUSTICE, Lawrence, J.
    • E21B33/12
    • C08L9/02C08L15/005C08L23/16C08L33/02C08L33/10C08L33/18C08L63/00C08L71/02C08L2205/03E21B33/1208C08L21/00
    • A water swellable rubber composition comprising (a) a non-water swellable base rubber, (b) an ethylene oxide based hydrophilic elastomer having from zero up to and including 20 mole % of a crosslinkable curable functional group, and (c) a water swellable non-elastomeric material. The composition has excellent water swell characteristics under prolonged exposure to high temperature and various electrolyte solutions (strongly saline as well as acid conditions) and is particularly suitable for oil field applications. When the ethylene oxide based hydrophilic elastomer (b) has from zero to less than 5 mole % of crosslinkable functional group, the amount of (b) is between about 30 parts and 300 parts by weight based on 100 parts by weight of the base rubber (a) and the amount of (c) is between about 20 parts and 200 parts by weight based on 100 parts by weight of the base rubber (a), the composition is characterized by good shape retention after undergoing constrained swell, as well as a high degree of constrained swell at elevated temperatures in different saline concentrations.
    • 一种水溶胀性橡胶组合物,其包含(a)非水可溶胀基础橡胶,(b)具有至多且包含20摩尔%交联性可固化官能团的环氧乙烷基亲水性弹性体,和(c)水可溶胀 非弹性材料。 该组合物在长时间暴露于高温和各种电解质溶液(强盐水以及酸性条件)下具有优异的水溶胀特性,特别适用于油田应用。 当环氧乙烷基亲水弹性体(b)的交联性官能团为零至小于5摩尔%时,相对于100重量份的基础橡胶,(b)的量为约30重量份〜300重量份 (a)和(c)的量基于100重量份的基础橡胶(a)为约20重量份至200重量份,该组合物的特征在于经受约束膨胀之后具有良好的形状保持性,以及 在不同盐水浓度的高温下高度受限的膨胀。
    • 10. 发明授权
    • Process for producing coalesced rubber microparticles and their blends with epoxy resins
    • 制备聚合橡胶微粒及其与环氧树脂的共混物的方法
    • US09096733B2
    • 2015-08-04
    • US14085383
    • 2013-11-20
    • ZEON CHEMICALS L.P.
    • Soobum ChoiLawrence JusticeJames Eckler
    • C08C1/15C08J3/12C08J3/00
    • C08C1/15C08J3/16C08J3/226C08J2309/04C08J2363/00C08J2363/02C08J2409/04
    • Coalesced rubber particles having an average particle size of 5-50 microns are produced by: (1) adding simultaneously to a latex of pre-crosslinked rubber particles a solvent and an electrolyte solution to form swollen rubber aggregation particles, wherein the solvent has a lower boiling point than water and a capacity of swelling the rubber by at least 10 wt %, and the electrolyte is a solution of at least one metal salt; (2) removing the solvent under atmospheric pressure or low vacuum and at temperature greater than 80° C. to coalesce the rubber into particles having an average particle size of 5-50 50 microns; (3) filtering and washing with methanol; and (4) filtering the washed particles to remove methanol. An epoxy resin is blended with the particles and residual methanol removed, to obtain a blend containing coalesced rubber particles having an average particle size of 5-50 microns in the blended state.
    • 平均粒度为5-50微米的聚结橡胶颗粒通过以下方法制备:(1)同时将预交联的橡胶颗粒的胶乳与溶剂和电解质溶液一起加入以形成溶胀的橡胶聚集颗粒,其中溶剂具有较低的 沸点比水和橡胶膨胀至少10重量%的能力,并且电解质是至少一种金属盐的溶液; (2)在常压或低真空和大于80℃的温度下除去溶剂,以将橡胶聚结成平均粒径为5-50微米的颗粒; (3)用甲醇过滤洗涤; 和(4)过滤洗涤的颗粒以除去甲醇。 将环氧树脂与除去的颗粒和残余甲醇混合,得到在共混状态下含有平均粒度为5-50微米的聚结的橡胶颗粒的共混物。