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3. 发明申请

WO2021064458A1 BENZOXAZINE RESIN COMPOSITION, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL 审中-公开
公开(公告)号：WO2021064458A1
公开(公告)日：2021-04-08
申请号：PCT/IB2020/000785
申请日：2020-09-28
申请人： TORAY INDUSTRIES, INC.
发明人： RUTZ, Benjamin , KAMAE, Toshiya
IPC分类号： C08G14/073 , C08G59/24 , C08G59/40 , C08J5/24
摘要： A curable benzoxazine resin composition for a fiber-reinforced composite material is provided which contains at least a component [A], a component [B], and a component [C], The component [A] includes at least one multifunctional benzoxazine resin having a non-hydrocarbon linkage such as carbonyl, oxygen, sulfur, sulfone or sulfoxide between aromatic moieties. The component [B] includes at least one multifunctional benzoxazine resin having a direct bond or a hydrocarbon linkage between aromatic moieties. The component [C] includes at least one cycloaliphatic epoxy resin containing at least two epoxy groups which are part of cycloaliphatic rings. The curable benzoxazine resin composition is useful in the molding of fiber-reinforced composite materials. More particularly, the curable benzoxazine resin composition makes possible a fiber-reinforced composite material where the cured material obtained by heating has superior performance in extreme use environments, such as high temperature and high compressive load.

4. 发明申请

WO2018037283A1 EPOXY RESIN COMPOSITION, PREPREG, AND FIBER REINFORCED PLASTIC MATERIAL 审中-公开
标题翻译：环氧树脂组合物，预浸料和纤维增强塑料材料
公开(公告)号：WO2018037283A1
公开(公告)日：2018-03-01
申请号：PCT/IB2017/001172
申请日：2017-08-24
申请人： TORAY INDUSTRIES, INC.
发明人： TUN, Swezin, Than , HUGHES, Jonathan , ARAI, Noboyuki , LEHMAN, Benjamin
IPC分类号： C08G59/32 , C08J5/24 , C08L63/00
摘要： The embodiments herein relate to an epoxy resin composition comprising a specific type of amine-based epoxy resin containing four epoxy groups per molecule, a prepreg, and a fiber-reinforced composite material. More specifically, the embodiments herein relate to an epoxy resin composition containing a combination of particular types of epoxy resin and curatives that provides high flexural modulus that is suitable for preparing a fiber-reinforced composite material capable of withstanding extreme use environments such as low-temperature environments and high-temperature moisture- absorbing environments. In addition, the embodiments herein relate to epoxy resin systems capable of achieving a high degree of cure (e.g., 85% or more) within a relatively short period of time (e.g., less than two hours) at a relatively low temperature (e.g., 132°C).
摘要翻译：这里的实施方式涉及包含特定类型的每分子含有四个环氧基团的胺基环氧树脂，预浸料坯和纤维增强复合材料的环氧树脂组合物。更具体地说，本文的实施方案涉及含有特定类型的环氧树脂和固化剂的组合的环氧树脂组合物，其提供了高挠曲模量，该挠曲模量适合于制备能够经受极端使用环境的纤维增强复合材料，例如低温环境和高温吸湿环境。另外，本文的实施方案涉及能够在相对较低的温度（例如，在相对低的温度（例如，小于2小时））内实现高度固化（例如，85％或更高） 132℃下＆; C）

5. 发明申请

WO2017055920A1 PREPREG WITH VARIABLE CURE RATE RESIN COMPOSITIONS 审中-公开
标题翻译： PREPREG与可变固化速率树脂组合物
公开(公告)号：WO2017055920A1
公开(公告)日：2017-04-06
申请号：PCT/IB2016/001504
申请日：2016-09-27
申请人： TORAY INDUSTRIES, INC.
发明人： NGUYEN, Felix, N. , HARO, Alfred, P. , FENBERT, Bradley, R.
IPC分类号： C08J5/24 , B32B5/28 , B32B27/12
CPC分类号： B32B5/28 , B32B27/12 , C08J5/24 , C08J2363/00
摘要： A prepreg comprising a layer of impregnated reinforcing fibers comprising at least one layer of reinforcing fibers impregnated by a resin composition comprising at least a thermosetting resin, a curing agent and an accelerator, such that the accelerator has a gradient concentration which is more concentrated in the resin composition in the vicinity of the reinforcing fibers than further away. The resin composition comprising a first resin composition impregnates the reinforcing fibers to provide a layer of impregnated reinforcing fibers and a surface layer comprising a second resin composition is formed on the layer of impregnated reinforcing fibers, wherein the first resin composition has at least one peak exotherm occurring at a time earlier than and/or at a temperature lower than any peak exotherm of the second resin composition, The heat generation from the first resin composition is tailored to initiate or speed up the curing of the second resin composition, leading to a substantial reduction of cure cycle time of the prepreg. Excellent handling and processing abilities of the uncured prepreg and excellent physical, thermal and mechanical properties when cured are achieved.
摘要翻译：一种预浸料，其包括浸渍的增强纤维层，其包含至少一层增强纤维层，所述增强纤维层由至少包含热固性树脂，固化剂和促进剂的树脂组合物浸渍，使得促进剂具有更集中在树脂组合物在增强纤维附近比较远。包含第一树脂组合物的树脂组合物浸渍增强纤维以提供浸渍的增强纤维层，并且在浸渍的增强纤维层上形成包含第二树脂组合物的表面层，其中第一树脂组合物具有至少一个峰放热发生在比第二树脂组合物的任何峰值放热低的温度和/或低于第二树脂组合物的任何峰值放热的时间内。来自第一树脂组合物的发热被定制以引发或加速第二树脂组合物的固化，导致大量预浸料的固化周期时间的缩短。实现了未固化预浸料的优异处理和加工能力，并且在固化时具有优异的物理，热和机械性能。

6. 发明申请

WO2014069379A1 MULTI-LAYERED FILM 审中-公开
标题翻译：多层膜
公开(公告)号：WO2014069379A1
公开(公告)日：2014-05-08
申请号：PCT/JP2013/079051
申请日：2013-10-18
申请人： TORAY INDUSTRIES,INC. , BASF SE
发明人： YAMAMURA, Gouhei , HIROTA, Masayuki , SAKAMOTO, Jun , LOOS, Robert , AUFFERMANN, Jorg , YANG, Xin
IPC分类号： B32B27/36
CPC分类号： B32B27/36 , B32B7/02 , B32B27/08 , B32B27/18 , B32B27/285 , B32B27/365 , B32B2250/24 , B32B2250/40 , B32B2270/00 , B32B2307/31 , B32B2307/54 , B32B2307/5825 , B32B2307/7163 , B32B2439/46 , B32B2439/70 , B32B2439/80
摘要： This invention relates to a multi-layered film that has high flexibility, tear resistance, heat sealability, interlayer contact strength, and biodegradability. The multi-layered film comprising layer (X) and layer (Y) which meet requirement (A): layer (X) comprises (a) lactic acid based resin, (b) biodegradable resin except lactic acid based resin, and (c) block copolymer resin of polyether segment and polylactic acid segment wherein resin (a), (b), and (c) account for 20-85 parts, 10-50 parts, and 5-30 parts by mass, respectively (resin (a), (b), and (c) in total account for 100 parts by mass) and requirement (B): layer (Y) comprises (d) aliphatic-aromatic polyester and resin (e) as defined below wherein resin (d) and (e) account for 30-100 parts and 0-70 parts by mass, respectively (resin (d) and (e) in total account for 100 parts by mass) Resin (e): at least one resin selected from the group consisting of lactic acid based resin, aliphatic polyester, polypropylene carbonate, and polyhydroxy alkanoate.
摘要翻译：本发明涉及具有高柔韧性，抗撕裂性，热封性，层间接触强度和生物降解性的多层膜。（A）：层（X）的层（X）和层（Y）的多层膜包含（a）乳酸类树脂，（b）乳酸类树脂以外的生物降解性树脂，（c）其中树脂（a），（b）和（c）分别占20-85份，10-50份和5-30质量份的聚醚链段和聚乳酸链段的嵌段共聚物树脂（树脂（a），（b）和（c）总计为100质量份）和要求（B）：层（Y）包含（d）如下所定义的脂族 - 芳族聚酯和树脂（e），其中树脂（d）和（e）分别为30〜100份，0〜70质量份（树脂（d）和（e）总计为100质量份）树脂（e）：至少一种选自乳酸类树脂，脂肪族聚酯，聚碳酸丙烯酯和聚羟基链烷酸酯。

7. 发明申请

WO2014060815A1 HIGH MODULUS FIBER REINFORCED POLYMER COMPOSITE 审中-公开
标题翻译：高模量纤维增强聚合物复合材料
公开(公告)号：WO2014060815A1
公开(公告)日：2014-04-24
申请号：PCT/IB2013/002275
申请日：2013-10-10
申请人： TORAY INDUSTRIES, INC.
发明人： NGUYEN, Felix, N. , HARO, Alfred, P. , YOSHIOKA, Kenichi
IPC分类号： C08J5/24
CPC分类号： C08J5/24 , C08J5/042 , C08J5/10 , C08J2300/24 , C08J2363/00 , C08J2363/02 , C08J2363/04 , C08K7/06
摘要： A fiber reinforced polymer composition is provided comprising a fiber and an adhesive composition, wherein the adhesive composition comprises at least a thermosetting resin and a curing agent, the reinforcing fiber has a tensile modulus of at least 300 GPa and the cured adhesive has a resin modulus of at least 3.2 GPa, and the adhesive composition when cured makes good bonds to the reinforcing fiber. Additional embodiments include a prepreg comprising the fiber reinforced polymer composition and a method of manufacturing a composite article by curing the adhesive composition and a reinforcing fiber.
摘要翻译：提供一种纤维增强聚合物组合物，其包含纤维和粘合剂组合物，其中所述粘合剂组合物至少包含热固性树脂和固化剂，所述增强纤维的拉伸模量为至少300GPa，并且所述固化的粘合剂具有树脂模量至少3.2GPa，固化时的粘合剂组合物与增强纤维形成良好的结合。另外的实施方案包括包含纤维增强聚合物组合物的预浸料和通过固化粘合剂组合物和增强纤维来制造复合制品的方法。

8. 发明申请

WO2013096968A3 PREPREG, FIBER REINFORCED COMPOSITE MATERIAL, AND MANUFACTURING METHOD FOR FIBER REINFORCED COMPOSITE MATERIAL 审中-公开
公开(公告)号：WO2013096968A3
公开(公告)日：2013-06-27
申请号：PCT/US2012/071641
申请日：2012-12-26
申请人： TORAY INDUSTRIES, INC.
发明人： HUGHES, Jonathan C. , SATTERWHITE, Jeffrey A. , ARAI, Nobuyuki , HARO, Alfred P. , YOSHIOKA, Kenichi , ARAI, Atsuhito
IPC分类号： B29C70/44
摘要： Embodiments herein relate to a prepreg comprising a thermosetting resin, and reinforcing fibers in the thermosetting resin, wherein when the prepreg is cured in vacuum bag only conditions, and a method of making the same. The method also applies for autoclave processing. Embodiments also relate to a cured fiber reinforced composite material made by thermally curing the prepreg.

9. 发明申请

WO2012116261A1 REINFORCED INTERPHASE AND BONDED STRUCTURES THEREOF 审中-公开
标题翻译：增强地层及其结合结构
公开(公告)号：WO2012116261A1
公开(公告)日：2012-08-30
申请号：PCT/US2012/026463
申请日：2012-02-24
申请人： TORAY INDUSTRIES, INC. , NGUYEN, Felix N. , YOSHIOKA, Kenichi , HARO, Alfred P. , ARAI, Nobuyuki
发明人： NGUYEN, Felix N. , YOSHIOKA, Kenichi , HARO, Alfred P.
IPC分类号： B32B7/00
CPC分类号： B32B7/00 , B32B5/10 , B32B7/12 , B32B2262/02 , B32B2262/101 , B32B2262/106 , Y10T428/28 , Y10T428/2927 , Y10T428/2933
摘要： Embodiments disclosed herein include a structure comprising an adherend and an adhesive composition, wherein the adhesive composition comprises at least a thermosetting resin, a curing agent, and an interfacial material, wherein the adherend is suitable for concentrating the interfacial material in an interfacial region between the adherend and the adhesive composition upon curing of the adhesive composition; a method of manufacturing a composite article by curing the adhesive composition and a reinforcing fiber; and a method of manufacturing an adhesive bonded joint comprising applying the adhesive composition to a surface of one of the two or of different kinds the adherend, and curing the adhesive composition to form an adhesive bond between the adherends. The resulting interfacial region, viz., the reinforced interphase, is reinforced by one or more layers of the interfacial material such that substantial improvements in bond strength and fracture toughness are observed.
摘要翻译：本文公开的实施方案包括包含被粘物和粘合剂组合物的结构，其中所述粘合剂组合物至少包含热固性树脂，固化剂和界面材料，其中所述被粘物适于将所述界面材料浓缩在所述界面区域之间粘合剂组合物固化后的粘合剂组合物; 通过固化粘合剂组合物和增强纤维来制造复合制品的方法; 以及粘合剂接合方法的制造方法，其特征在于，将所述粘合剂组合物涂布在所述两种或不同种类的被粘物中的一种的表面上，使所述粘合剂组合物固化，从而在所述被粘物之间形成粘结剂。所得到的界面区域，即增强相间，由一层或多层界面材料增强，从而观察到粘合强度和断裂韧性的显着改善。

10. 发明申请

WO1998023290A1 ANTIPRURITIC AGENT 审中-公开
标题翻译：抗菌剂
公开(公告)号：WO1998023290A1
公开(公告)日：1998-06-04
申请号：PCT/JP1997004267
申请日：1997-11-21
申请人： TORAY INDUSTRIES, INC. , NAGASE, Hiroshi , UTSUMI, Jun , ENDOH, Takashi , TANAKA, Toshiaki , KAMEI, Junzo , KAWAMURA, Kuniaki
发明人： TORAY INDUSTRIES, INC.
IPC分类号： A61K45/00
CPC分类号： A61K31/541 , A61K31/40 , A61K31/4025 , A61K31/435 , A61K31/485 , A61K31/5377 , C07D489/00 , C07D489/08
摘要： An antipruritic agent comprising as the active ingredient an opioid kappa receptor agonist useful for the treatment of pruritus in various diseases accompanied by pruritus, and novel morphinane quaternary ammonium salt derivatives and morphinane N-oxide derivatives.
摘要翻译：包含作为活性成分的止痒剂，其可用于治疗伴有瘙痒症的各种疾病中的瘙痒症，以及新的吗啡烷季铵盐衍生物和吗啡烷N-氧化物衍生物。

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