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    • 2. 发明专利
    • HETEROPOLY ACID/POLYOXOMETHALATE CATALYST
    • JP2001104793A
    • 2001-04-17
    • JP2000247492
    • 2000-08-17
    • ROHM & HAASSUNOCO INC
    • ELLIS PAUL EDWARDKARMAKAR SWATILINK RICHARD DAVID IIILYONS JAMES EDWARDMCNEAL NNEKA NAMONOVOLPE ANTHONY FRANK JR
    • B01J27/19B01J23/16B01J27/188B01J27/199B01J31/06B01J37/08C07B61/00C07C5/42C07C11/02C07C51/215C07C57/05
    • PROBLEM TO BE SOLVED: To provide an improved catalyst for various chemical processes, containing a heteropoly acid carried on a polyoxomethalate salt. SOLUTION: This heteropoly acid/oplyoxomethalate catalyst comprises a catalyst composition containing a heteropoly acid carried on a polyoxomethalate carrier, wherein the carrier of the polyoxomethalate is subjected to heat treatment at 385-600 deg.C. The heteropoly acid has a structure represented by the formula I, H(e'-bz')Gb-(Xk'Mm'-x'M1x'M2n'Oy')-e' (wherein G is an element selected from group 1-16 elements, or its oxygen; X is an element selected from group 3-16 elements; M is molybdenum, tungsten, or their combination; M1 is vanadium; M2 is a transition metal different from M and M1; z' is a charge of G; (b) is an integer of 0-12; k' is an integer of 1-5; m' is an integer of 5-20; x' is an integer of 0-6; n' is an integer of 0-3; y' is an integer of 18-62; and e' is a charge of polyoxomethalate anino). The polyoxomethalate carrier has a structure represented by the formula II, CaH(e-az)(XkMm-xM1xM2nOy)-e (wherein C is a cation selected from potassium, rubidium, cesium, magnetisum, calcium, strontium, barium, transistion metal, an actinide metal, a lanthanide metal, a metal oxyion, ammonium, tetraalkylammonium, pyridinium, quinolinium, a protonated aromatic amine, and a protonated aliphatic amine or a mixture thereof; (x) is an element selected from group 3-16 elements; M is molybdenum, tungsten, or their combination; M1 is vanadium; M2 is a transition metal different from M and M1; (z) is a charge of C; (k) is an integer of 1-5; (m) is an integer of 5-20; (n) is an integer of 0-3; x is an integer of 0-6; (y) is an integer of 18-62; and (e) is a charge of a olyoxomethalate anion). The polyoxomethalate carrier is, for example, Cs3PMo12O40, and the heteropoly acid is, for example, H3PMo12O40.
    • 4. 发明申请
    • PROCESS FOR RECOVERY OF CUMENE HYDROPEROXIDE DECOMPOSITION PRODUCTS BY DISTILLATION
    • 通过蒸馏来回收碳氢化合物分解产物的方法
    • WO2007058962A1
    • 2007-05-24
    • PCT/US2006/043848
    • 2006-11-10
    • SUNOCO, INC. (R & M)KEENAN, Scott, R.HARACH, Amber, R.SKIPWORTH, James, G.
    • KEENAN, Scott, R.HARACH, Amber, R.SKIPWORTH, James, G.
    • C07C409/10C07C407/00
    • C07C45/53C07C37/08C07C37/72C07C37/74C07C37/82C07C45/80C07C45/82C07C39/04
    • Products from the decomposition of cuniene hydroperoxide (CHP) are recovered by distillation. The majority of the undesirable by-product acetol (hydroxyacetone) is removed from the phenol stream by distillation wherein the majority of the acetol is carried with an overheads stream comprising acetone, cumene and alphamethylstyrene (AMS). Acetol is subsequently separated from acetone by distillation wherein acetone is taken as an overheads stream and acetol remains with a bottoms stream comprising cumene, AMS and phenol. The acetol, along with residual phenol, is extracted from the cumene and AMS by counter-current washing with an aqueous alkali metal hydroxide. The phenol stream is then distilled to separate phenol from cumene, alphamethylstyrene and higher boiling compounds. The phenol, containing only a small amount of acetol, can then be treated to remove methylbenzofuran by treatment with an acidic resin or solid superacid catalyst without formation of significant amounts of additional methylbenzofuran.
    • 通过蒸馏回收氢过氧化氢(CHP)分解产物。 通过蒸馏从苯酚流中除去大部分不合需要的副产物丙酮醇(羟基丙酮),其中大部分丙酮醇与包含丙酮,枯烯和α-甲基苯乙烯(AMS)的塔顶馏出物携带。 Acetol随后通过蒸馏与丙酮分离,其中将丙酮作为塔顶馏出物流,并且丙酮醇残留有包含枯烯,AMS和苯酚的塔底物流。 通过用碱金属氢氧化物水溶液逆流洗涤,从异丙苯和AMS中提取丙酮醇和残留的苯酚。 然后将苯酚流蒸馏以将苯酚与枯烯,α-甲基苯乙烯和较高沸点化合物分离。 然后可以用酸性树脂或固体超强酸催化剂处理除苯甲呋喃,只含少量丙酮醇,除去甲基苯并呋喃,不形成显着量的甲基苯并呋喃。
    • 5. 发明申请
    • HIGH MELT FLOW RATE THERMOPLASTIC POLYOLEFINS PRODUCED IN-REACTOR
    • 高熔体流动速率热塑性聚烯烃生产反应器
    • WO2005105914A1
    • 2005-11-10
    • PCT/US2005/009053
    • 2005-03-17
    • SUNOCO, INC. (R & M)
    • KIM, SehzunSCHNITGEN, Andrew, L.MIGONE, Ruben, A.SALEK, Jeffrey, S.
    • C08L23/14
    • C08L23/12C08L23/142C08L23/16C08L2666/06
    • A thermoplastic polyolefin having a melt flow rate of 20 dg/min or higher at 230 ° C is produced in reactor without visbreaking. By controlling ratio of the weight average molecular weight of the xylene soluble fraction to the weight average molecular weight of the xylene insoluble fraction, a high melt flow thermoplastic polyolefin can be produced having a good balance of impact and stiffness, tensile elongation at break and gloss properties. Optionally, the ratio of the melt flow rate of the homopolymer phase to the melt flow rate of the total thermoplastic polyolefin can also be controlled. By compounding thermoplastic polyolefins according to the current invention with one or more modifiers, additional compositions can be produced having improved resistance to solvents.
    • 在230℃下熔体流动速率为20dg / min或更高的热塑性聚烯烃在不进行减粘裂化的反应器中生产。 通过控制二甲苯可溶部分的重均分子量与二甲苯不溶部分的重均分子量的比例,可以制得具有良好的冲击和刚度,断裂拉伸伸长率和光泽度的良好平衡的高熔体流动的热塑性聚烯烃 属性。 任选地,也可以控制均聚物相的熔体流动速率与总热塑性聚烯烃的熔体流动速率的比率。 通过将根据本发明的热塑性聚烯烃与一种或多种改性剂混合,可以生产具有改进的耐溶剂性的另外的组合物。