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    • 1. 发明专利
    • BRPI0412538A
    • 2006-09-19
    • BRPI0412538
    • 2004-06-17
    • HEADWATERS NANOKINETIX INC
    • ZHOU BINGRUETER MICHAELPARASHER SUKESH
    • B01J21/18B01J23/38B01J23/40B01J23/44C01B15/01
    • Supported reactive catalysts having a controlled coordination structure and methods for their production are disclosed. The supported catalyst comprises catalyst particles having top or outer layer of atoms in which at least a portion of the atoms exhibit a controlled coordination number of 2. Such catalysts may be manufactured from intermediate precursor compositions that include a control agent in which a preponderance of the molecules are straight-chained rather than branched. The supported catalysts of the present invention are useful for the preparation of hydrogen peroxide with high selectivity in addition to other chemical conversion reactions. The catalyst and methods may be used for the concurrent in situ and ex situ conversion of organic compounds. In addition, a process is provided for catalytically producing hydrogen peroxide from hydrogen and oxygen feeds by contacting them with the catalysts of the invention and a suitable organic liquid solvent having a Solvent Selection Parameter (SSP) between 0.14 x 10 -4 and 5.0 x 10 -4 .
    • 6. 发明申请
    • MULTICOMPONENT NANOPARTICLES FORMED USING A DISPERSING AGENT
    • 用分散剂形成多组分纳米粒子
    • WO2007001418A2
    • 2007-01-04
    • PCT/US2005037545
    • 2005-10-19
    • HEADWATERS NANOKINETIX INCZHOU BINGPARASHER SUKESHRUETER MICHAEL
    • ZHOU BINGPARASHER SUKESHRUETER MICHAEL
    • B01J23/00
    • B01J35/0013B01J21/18B01J23/8906B01J23/8933B01J23/8946B01J35/006B01J37/0203B01J37/18B82Y30/00B82Y40/00
    • Nanoparticles include a plurality of two or more dissimilar components selected from the group of noble metals, base transition metals, alkali earth metals, and rare earth metals and/or different groups of the periodic table of elements. The two or more dissimilar components are dispersed using a dispersing agent such that the nanoparticles have a substantially uniform distribution of the two or more dissimilar components. The dispersing agents can be poly functional small organic molecules, polymers, or oligomers, or salts of these. The molecules of the dispersing agent bind to the particle atoms to overcome same-component attractions, thereby allowing dissimilar components to form heterogeneous manoparticles. Dissimular components such as iron and platinum can be complexed using the dispersing agent to form sbstantially uniform heterogeneous nanoparticles. The nanoparticles can be used alone or applied to a support. At least a portion of the dispersing agent can be removed by reduction and/or oxidation.
    • 纳米颗粒包括多种选自贵金属,碱过渡金属,碱土金属和稀土金属和/或元素周期表的不同基团的两种或更多种不同组分。 使用分散剂分散两种或更多种不同组分,使得纳米粒子具有两种或更多种不同组分的基本均匀分布。 分散剂可以是多官能小有机分子,聚合物或低聚物或这些的盐。 分散剂的分子与粒子原子结合以克服相同成分的吸引力,由此允许不相似的组分形成不均匀的人造粒子。 可以使用分散剂使异物组分如铁和铂复合以形成基本均匀的非均相纳米粒子。 纳米颗粒可以单独使用或应用于支持物。 至少一部分分散剂可以通过还原和/或氧化除去。