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    • 5. 发明授权
    • Method for stabilizing phosphorus trichloride
    • 稳定三氯化磷的方法
    • US5147621A
    • 1992-09-15
    • US665512
    • 1991-03-06
    • Rudolf Schumann
    • Rudolf Schumann
    • C01B25/10
    • C01B25/10
    • The invention relates to a method for stabilizing phosphorus trichloride. In order to delay the formation of phosphorus oxychloride in phosphorus trichloride and to reduce it to a minimum value which no longer adversely affects further processing, one or more amines which have at least two aromatic hydrocarbon groups linked to one nitrogen atom, such as diphenylamine, phenothiazine, phenyl-4-methylphenylamine and triphenylamine, are added to the phosphorus trichloride. The amines can also be added in the form of their salts, including their quaternary ammonium compounds, or their reaction products with phosphorus halides. The amounts of amines, added fall within the range of 10.sup.-6 % to 10.sup.-1 %, based on the amount of phosphorus trichloride.
    • 本发明涉及一种稳定三氯化磷的方法。 为了延迟磷酰氯在三氯化磷中的形成,并将其降低至不再对进一步加工产生不利影响的最小值,一种或多种具有至少两个与一个氮原子连接的芳族烃基的胺如二苯胺, 吩噻嗪,苯基-4-甲基苯基胺和三苯胺,加入到三氯化磷中。 胺也可以以它们的盐的形式加入,包括它们的季铵化合物,或它们与卤化物的反应产物。 基于三氯化磷的量,添加的胺的量在10-6%至10-1%的范围内。
    • 7. 发明授权
    • Method for stabilizing phosphorus trichloride
    • 稳定三氯化磷的方法
    • US5147622A
    • 1992-09-15
    • US665511
    • 1991-03-06
    • Rudolf Schumann
    • Rudolf Schumann
    • C01B25/10
    • C01B25/10
    • The invention relates to a method for the stabilization of phosphorus trichloride, wherein one or more derivatives of dithiocarbamic acids are added to the phsophorus trichloride. As derivatives, salts, esters or thiuram sulfides of the dithiocarbamic acids, individually or as a mixture, are preferred. The amounts used generally fall within the range of 10.sup.-4 % to 10.sup.-2 %, based on the amount of phosphorus trichloride. Derivatives, which are only slightly soluble in phosphorus trichloride are advantageously used in amounts of more than 10.sup.-2 %. Due to the inventive addition of derivatives of dithiocarbamic acids, the formation of phosphorus oxychloride in the phosphorus trichloride is delayed significantly and reduced to a minimum value.
    • 本发明涉及一种稳定三氯化磷的方法,其中将二硫代氨基甲酸的一种或多种衍生物加到三氯化磷中。 作为二硫代氨基甲酸的衍生物,盐,酯或秋兰姆硫化物,单独或作为混合物是优选的。 基于三氯化磷的量,所用量通常在10-4%至10-2%的范围内。 只有微溶于三氯化磷的衍生物有利地以大于10-2%的量使用。 由于本发明添加了二硫代氨基甲酸的衍生物,三氯化磷中的三氯氧化磷的形成被显着地延迟并降低到最小值。