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1. 发明专利

JP5913364B2 ポリオキソメタレートおよびバナジウム(IV)化合物を含むカソード液を持つ再生可能な燃料電池有权
标题翻译：多金属氧酸盐和钒（IV），其具有包含化合物阴极电解液可再生燃料电池
公开(公告)号：JP5913364B2
公开(公告)日：2016-04-27
申请号：JP2013545494
申请日：2011-12-16
申请人：エーカル・エナジー・リミテッド , ACAL Energy Limited
发明人：ナッキー,キャスリン , カンガティ,ベルミ , ダウンズ,クレアー , ポッター,アンドリュー
IPC分类号： H01M8/18
CPC分类号： H01M8/20 , H01M4/9016 , H01M8/188 , H01M2008/1095 , Y02E60/528

2. 发明申请

WO2014001787A1 REDOX BATTERY USE FOR POLYOXOMETALLATE 审中-公开
标题翻译：用于聚硅氧烷的氧化还原电池
公开(公告)号：WO2014001787A1
公开(公告)日：2014-01-03
申请号：PCT/GB2013/051676
申请日：2013-06-25
申请人： ACAL ENERGY LIMITED
发明人： CREETH, Andrew, Martin , BAYNES, Nicholas de Brissac , DENNE, Joshua
IPC分类号： H01M8/18 , C01G41/02 , C11D3/39
CPC分类号： H01M4/5825 , C01B25/45 , C01G39/006 , C01G41/006 , H01M8/188 , H01M8/20 , Y02E60/528
摘要： The present invention provides a redox battery comprising a polyoxometallate as at least one redox couple. Preferably, the redox battery comprises two electrodes separated by an ion exchange membrane or other separator; means for supplying a first redox couple to the first electrode region of the cell; means for supplying a second redox couple to the second electrode region of the cell, the potential of the first redox couple being higher than that of the second redox couple, and at least the higher potential redox couple comprising polyoxometallate,
摘要翻译：本发明提供一种氧化还原电池，其包含作为至少一种氧化还原对的多金属氧酸盐。优选地，氧化还原电池包括由离子交换膜或其它分离器分离的两个电极; 用于将第一氧化还原对提供给所述电池的第一电极区域的装置; 用于将第二氧化还原对提供给所述电池的第二电极区的装置，所述第一氧化还原对的电位高于所述第二氧化还原对的电位，并且至少所述较高电位的氧化还原对包含多金属氧酸盐，

3. 发明申请

WO2012049494A1 ELECTROLYTIC CELL 审中-公开
标题翻译：电解槽
公开(公告)号：WO2012049494A1
公开(公告)日：2012-04-19
申请号：PCT/GB2011/051961
申请日：2011-10-11
申请人： ACAL ENERGY LIMITED , CREETH, Andrew Martin
发明人： CREETH, Andrew Martin
IPC分类号： C25B1/00 , C25B1/10 , C25B9/08 , C25B9/16
CPC分类号： C25B1/10 , C25B1/003 , C25B9/08 , C25B9/10 , C25B9/16 , Y02E60/366
摘要： An electrolytic cell comprising an anode in an anode region and a cathode in a cathode region, the anode region and the cathode regions separated by an ion selective polymer electrolyte membrane; an anolyte in flowing fluid communication with the anode, the anolyte comprising water and a redox mediator couple which is at least partially oxidised at the anode in operation of the cell and at least partially reduced by reaction with water after such oxidation at the anode.
摘要翻译：一种电解槽，包括在阳极区域中的阳极和阴极区域中的阴极，所述阳极区域和所述阴极区域被离子选择性聚合物电解质膜隔开; 与阳极流动连通的阳极电解液，所述阳极电解液包含水和氧化还原介体对，所述氧化还原介体对在所述电池的操作中在所述阳极处至少部分氧化，并且在所述阳极处经过氧化后至少部分地通过与水反应而被还原。

4. 发明申请

WO2009093081A1 FUEL CELLS 审中-公开
标题翻译：燃料电池
公开(公告)号：WO2009093081A1
公开(公告)日：2009-07-30
申请号：PCT/GB2009/050066
申请日：2009-01-23
申请人： ACAL ENERGY LIMITED , KNUCKEY, Kathryn , ROCHESTER, David
发明人： KNUCKEY, Kathryn , ROCHESTER, David
IPC分类号： H01M8/18 , H01M8/10
CPC分类号： H01M8/188 , H01M4/36 , H01M8/1016 , H01M8/20 , Y02E60/521 , Y02E60/528
摘要： A redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a catholyte solution comprising a modified ferrocene species comprising at least one bridging unit between the cyclopentadienyl rings, the modified ferrocene species being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode.
摘要翻译：一种氧化还原型燃料电池，包括由离子选择性聚合物电解质膜隔开的阳极和阴极; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 包含修饰的二茂铁物质的阴极电解液，所述二茂铁物质在所述环戊二烯基环之间包含至少一个桥连单元，所述修饰的二茂铁物质在所述电池的操作中在所述阴极处至少部分还原，并且至少部分地通过与所述氧化剂反应而再次产生在阴极这样的减少。

5. 发明申请

WO2014174295A1 APPARATUS FOR COOLING A FUEL CELL 审中-公开
标题翻译：用于冷却燃料电池的装置
公开(公告)号：WO2014174295A1
公开(公告)日：2014-10-30
申请号：PCT/GB2014/051274
申请日：2014-04-24
申请人： ACAL ENERGY LIMITED
发明人： LONGMAN, Robert J.
IPC分类号： H01M8/18 , H01M8/20 , H01M8/04
CPC分类号： H01M8/04029 , H01M8/04074 , H01M8/188 , H01M8/20 , H01M2250/20 , Y02E60/528 , Y02T90/32
摘要： Apparatus for cooling a liquid electrolyte fuel cell is disclosed. The apparatus comprises a liquid electrolyte transport arrangement for bringing liquid electrolyte from a fuel cell into thermal communication with a thermal energy transfer medium and for communicating liquid electrolyte from thermal communication with the energy transfer medium back to the fuel cell. A thermal energy transfer medium transport arrangement for communicating the thermal energy transfer medium to thermal communication with the liquid electrolyte from a heat sink and for communicating the thermal energy transfer medium from thermal communication with the liquid electrolyte to a heat sink is also provided. The electrical installation maybe by way of the thermal energy transfer medium being non-conducting, for example a water/ethylene glycol mix and/or by their being electrically insulating material between the energy transfer medium and liquid electrolyte.
摘要翻译：公开了用于冷却液体燃料电池的设备。该装置包括用于使来自燃料电池的液体电解质与热能传递介质热连通并且用于使液体电解质与能量传递介质热连通回传送到燃料电池的液体电解质输送装置。还提供了一种用于将热能传递介质与散热器与液体电解质热连通并将热能传递介质与液体电解质热连通传导到散热器的热能传递介质输送装置。电气装置可以通过不导电的热能传递介质，例如水/乙二醇混合物和/或通过它们在能量转移介质和液体电解质之间的电绝缘材料。

6. 发明申请

WO2012085542A1 REGENERATIVE FUEL CELL WITH CATHOLYTE COMPRISING A POLYOXOMETALATE AND A VANADIUM (IV) - COMPOUND 审中-公开
标题翻译：具有包含聚氧乙烯醚和四（V）化合物的催化剂的再生燃料电池
公开(公告)号：WO2012085542A1
公开(公告)日：2012-06-28
申请号：PCT/GB2011/052500
申请日：2011-12-16
申请人： ACAL ENERGY LIMITED , KNUCKEY, Kathryn , KANGATI, Belloumi , DOWNS, Clare , POTTER, Andrew
发明人： KNUCKEY, Kathryn , KANGATI, Belloumi , DOWNS, Clare , POTTER, Andrew
IPC分类号： H01M8/20 , H01M8/18 , H01M4/90 , H01M8/10
CPC分类号： H01M8/20 , H01M4/9016 , H01M8/188 , H01M2008/1095 , Y02E60/528
摘要： Redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile catholyte solution flowing fluid communication with the cathode, the catholyte solution comprising a polyoxometailate redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re -generated by reaction with the oxidant after such reduction at the cathode, the catholyte solution comprising at least about 0.075M of the said polyoxometailate, and additionally a vanadium (IV) compound.
摘要翻译：包含由离子选择性聚合物电解质膜分离的阳极和阴极的氧化还原型燃料电池; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 与阴极流体连通的非挥发性阴极电解液，包含多氧氧元素氧化还原对的阴极电解液在电解槽操作时在阴极处至少部分还原，并且在这种还原之后至少部分地与氧化剂反应而再生在阴极处，阴极电解液包含至少约0.075M的所述多氧氧基甲酸盐，另外还包含钒（IV）化合物。

7. 发明申请

WO2006097438A2 FUEL CELLS 审中-公开
标题翻译：燃料电池
公开(公告)号：WO2006097438A2
公开(公告)日：2006-09-21
申请号：PCT/EP2006/060640
申请日：2006-03-10
申请人： ACAL ENERGY LIMITED , CREETH, Andrew Martin
发明人： CREETH, Andrew Martin
IPC分类号： H01M4/86 , H01M4/96 , H01M8/10 , H01M8/18 , H01M8/20
CPC分类号： H01M8/1053 , H01M4/8652 , H01M4/96 , H01M8/1009 , H01M8/188 , H01M8/20 , Y02E60/528
摘要： This invention concerns a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte-membrane, preferably a bi-membrane, the cathode comprising a cathodic material and a proton-conducting polymeric material; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile redox couple in solution in flowing fluid communication with the cathode, the redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode.
摘要翻译：本发明涉及一种氧化还原燃料电池，其包括由离子选择性聚合物电解质膜隔离的阳极和阴极，优选双膜，所述阴极包括阴极材料和质子传导聚合材料; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 在与阴极流动的流体连通的溶液中的非挥发性氧化还原对，氧化还原对在电解槽的操作中在阴极处至少部分地还原，并且至少部分地通过与氧化剂反应而产生，阴极。

8. 发明申请

WO2013110950A1 IMPROVED FUEL CELL ELECTROLYTE REGENERATOR AND SEPARATOR 审中-公开
标题翻译：改进的燃料电池电解液再生器和分离器
公开(公告)号：WO2013110950A1
公开(公告)日：2013-08-01
申请号：PCT/GB2013/050173
申请日：2013-01-25
申请人： ACAL ENERGY LIMITED
发明人： WARD, David , LONGMAN, Robert
IPC分类号： B01D19/00 , H01M8/18
CPC分类号： H01M8/04276 , B01D19/0031 , B01D19/0042 , B01D19/0057 , B01D19/02 , H01M8/188 , H01M8/20 , H01M2250/20 , Y02E60/528
摘要： The invention concerns, in one aspect, a separator (100, 200, 300) for a liquid electrolyte regenerator of a fuel cell system and, in another aspect, a foam reducing apparatus. In the separator, a helical fluid channel (100, 200, 300) formed on a helix (150) is arranged to conduct liquid and gas of a gas-liquid mixture and separate the liquid from the gas-liquid mixture. The helical channel (100, 200, 300) may be an enclosed channel or pipe (210, 302) and the overall diameter (D Heiix ) of the helical channel may be around twice the pipe diameter. The helical channel can form part of a bulk gas-liquid separator (200), or a gas-liquid contactor and separator (300, 400, 500), or a condensing heat exchanger (300, 400, 500). The foam reduction apparatus (FIG.15 155, 157; FIG. 20; FIG. 16, 1600; FIG. 18, 1800), has a low surface energy material and is arranged to provide contact between foam and a surface of the low surface energy material. The separator and the foam reduction apparatus may be used independently or in combination to good effect so as to provide more efficient disruption of foam to provide separate gas and liquid phases.
摘要翻译：在一方面，本发明涉及一种用于燃料电池系统的液体电解质再生器的隔板（100,200,300），在另一方面，涉及一种减泡装置。在分离器中，形成在螺旋（150）上的螺旋流体通道（100,200,300）被布置成传导气液混合物的液体和气体，并将液体与气液混合物分离。螺旋通道（100,200,300）可以是封闭的通道或管道（210,302），并且螺旋通道的总直径（DHeiix）可以是管道直径的大约两倍。螺旋通道可以形成本体气液分离器（200）或气液接触器和分离器（300,400,500）或冷凝热交换器（300,400,500）的一部分。泡沫减少装置（图15,155,157;图20;图16,1600;图18,1800）具有低表面能材料并被布置成提供泡沫与低表面的表面之间的接触能源材料分离器和泡沫减少装置可以单独使用或组合使用以获得良好的效果，以便提供更有效的泡沫破裂以提供单独的气相和液相。

9. 发明申请

WO2011015875A1 FUEL CELLS 审中-公开
标题翻译：燃料电池
公开(公告)号：WO2011015875A1
公开(公告)日：2011-02-10
申请号：PCT/GB2010/051295
申请日：2010-08-05
申请人： ACAL ENERGY LIMITED , KNUCKEY, Kathryn , ROCHESTER, David , CREETH, Andrew Martin
发明人： KNUCKEY, Kathryn , ROCHESTER, David , CREETH, Andrew Martin
IPC分类号： H01M8/18
CPC分类号： H01M8/188 , Y02E60/528
摘要： The invention concerns the use as a redox a catalyst and/or mediator in a fuel cell catholyte solution of the compound of Formula (I) wherein: X is selected from hydrogen and from various functional groups; R 1-8 are independently selected from hydrogen and various functional groups; wherein R 1 and X and/or R 5 and X may together form an optionally substituted ring structure; wherein R 1 and R 2 and/or R 2 and R 3 and/or R 3 and R 4 and/or R 4 and R 8 and/or R 8 and R 7 and/or R 7 and R 6 and/or R 6 and R 5 may together form an optionally substituted ring structure; wherein (L) indicates the optional presence of a linking bond or group between the two neighbouring aromatic rings of the structure, and when present may form an optionally substituted ring structure with one or both of R 4 and R 8 ; and wherein at least one substituent group of the structure is a charge-modifying substituent.
摘要翻译：本发明涉及在式（I）化合物的燃料电池阴极液溶液中作为氧化还原催化剂和/或介体的用途，其中：X选自氢和各种官能团; R1-8独立地选自氢和各种官能团; 其中R1和X和/或R5和X可以一起形成任选取代的环结构; 其中R1和R2和/或R2和R3和/或R3和R4和/或R4和R8和/或R8和R7和/或R7和R6和/或R6和R5可以一起形成任选取代的环结构; 其中（L）表示在结构的两个相邻芳环之间任选存在连接键或基团，并且当存在时可以形成具有一个或两个R 4和R 8的任选取代的环结构; 并且其中所述结构的至少一个取代基是电荷改性取代基。

10. 发明申请

WO2010128333A1 FUEL CELLS 审中-公开
标题翻译：燃料电池
公开(公告)号：WO2010128333A1
公开(公告)日：2010-11-11
申请号：PCT/GB2010/050746
申请日：2010-05-07
申请人： ACAL ENERGY LIMITED , CREETH, Andrew Martin , WARD, David
发明人： CREETH, Andrew Martin , WARD, David
IPC分类号： H01M8/04 , H01M8/18 , H01M8/00
CPC分类号： H01M8/182 , H01M8/04276 , H01M2250/00 , H01M2250/405 , Y02B90/16 , Y02E60/528
摘要： A redox fuel cell comprising a catholyte solution comprising at least one non-volatile catholyte component, the catholyte solution comprising a redox mediator couple; and a regeneration zone separate from the membrane electrode assemblies of the fuel cell, the means for supplying an oxidant to the fuel cell being adapted to supply the oxidant to the regeneration zone, the volume of catholyte solution in the regeneration zone being from about 25 % to about 90 % of the total combined volume of catholyte solution in the regeneration zone and the cathode chambers of the fuel cell.
摘要翻译：一种氧化还原燃料电池，包括含有至少一种非挥发性阴极电解液组分的阴极电解液，所述阴极电解液包含氧化还原介体对; 以及与燃料电池的膜电极组件分开的再生区，用于向燃料电池供应氧化剂的装置适于将氧化剂供应到再生区，再生区中的阴极电解液的体积为约25％至燃料电池再生区和阴极室中阴极电解液总组合体积的约90％。

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