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1. 发明授权

US08445609B2 Method for producing olefin polymer 有权
标题翻译：烯烃聚合物的制备方法
公开(公告)号：US08445609B2
公开(公告)日：2013-05-21
申请号：US13265122
申请日：2010-04-21
申请人： Yasushi Tohi , Ken Yoshitsugu , Naoya Akiyama , Toshio Fujita , Masatoshi Chinaka
发明人： Yasushi Tohi , Ken Yoshitsugu , Naoya Akiyama , Toshio Fujita , Masatoshi Chinaka
IPC分类号： C08F4/642 , C08F4/649 , C08F4/6592 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F210/16 , C08F2410/02 , C08F4/65922 , C08F4/65912 , C08F210/14 , C08F4/6495 , C08F2/005
摘要： An object of the present invention is to provide a method for producing an olefin polymer, with which an olefin polymer having good particle properties can be produced in high activity, fouling inside the polymerization vessel, such as a vessel wall or an impeller, can be effectively prevented, and a long-term stable operation is achieved.A method for producing an olefin polymer according to the present invention is characterized by including (co)polymerizing at least one olefin selected from the group consisting of ethylene and α-olefins having 3 to 20 carbon atoms in a polymerization vessel in the presence of (A) a solid catalyst component for olefin polymerization, (B) an aliphatic amide, and (C) an organoaluminum compound.
摘要翻译：本发明的目的是提供一种生产烯烃聚合物的方法，通过该方法可以高活性地制备具有良好的颗粒性能的烯烃聚合物，聚合容器如容器壁或叶轮内的结垢可以是有效防范，长期稳定运行。本发明的烯烃聚合物的制造方法的特征在于，在（聚）容器中，在（（共）聚合容器中存在（（共））聚合至少一种选自乙烯和碳原子数3〜20的α-烯烃的烯烃， A）用于烯烃聚合的固体催化剂组分，（B）脂族酰胺和（C）有机铝化合物。

2. 发明申请

US20120041162A1 METHOD FOR PRODUCING OLEFIN POLYMER 有权
标题翻译：生产烯烃聚合物的方法
公开(公告)号：US20120041162A1
公开(公告)日：2012-02-16
申请号：US13265122
申请日：2010-04-21
申请人： Yasushi Tohi , Ken Yoshitsugu , Naoya Akiyama , Toshio Fujita , Masatoshi Chinaka
发明人： Yasushi Tohi , Ken Yoshitsugu , Naoya Akiyama , Toshio Fujita , Masatoshi Chinaka
IPC分类号： C08F2/00 , C08F2/18 , C08F2/04 , C08F2/34
CPC分类号： C08F10/00 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F210/16 , C08F2410/02 , C08F4/65922 , C08F4/65912 , C08F210/14 , C08F4/6495 , C08F2/005
摘要： [Object] An object of the present invention is to provide a method for producing an olefin polymer, with which an olefin polymer having good particle properties can be produced in high activity, contamination inside the polymerization vessel, such as a vessel wall or an impeller, can be effectively prevented, and a long-term stable operation is achieved.[Means for Achieving the Object] A method for producing an olefin polymer according to the present invention is characterized by including (co)polymerizing at least one olefin selected from the group consisting of ethylene and α-olefins having 3 to 20 carbon atoms in a polymerization vessel in the presence of (A) a solid catalyst component for olefin polymerization, (B) an aliphatic amide, and (C) an organoaluminum compound.
摘要翻译：本发明的目的是提供一种制备烯烃聚合物的方法，通过该方法可以高活性地产生具有良好颗粒性能的烯烃聚合物，聚合容器内诸如容器壁或叶轮之间的污染，可以有效地防止长期稳定的运转。实现目的的手段本发明的烯烃聚合物的制造方法的特征在于，在（a）中，使（a）在（a）中含有选自乙烯和碳原子数3〜20的α-烯烃中的至少一种烯烃（A）用于烯烃聚合的固体催化剂组分，（B）脂族酰胺和（C）有机铝化合物存在下的聚合容器。

3. 发明申请

US20120095167A1 METHOD FOR PREVENTING FOULING IN CHEMICAL EQUIPMENT AND ANTIFOULING AGENT 失效
标题翻译：防止化学设备和反应剂发生化学反应的方法
公开(公告)号：US20120095167A1
公开(公告)日：2012-04-19
申请号：US13258554
申请日：2010-03-31
申请人： Naoshi Nagai , Shiro Nakatsuka , Kazuoki Nakai , Kenji Sugimura , Yasushi Tohi , Ken Yoshitsugu , Hideki Bando , Yasuyuki Harada
发明人： Naoshi Nagai , Shiro Nakatsuka , Kazuoki Nakai , Kenji Sugimura , Yasushi Tohi , Ken Yoshitsugu , Hideki Bando , Yasuyuki Harada
IPC分类号： C08L53/00 , C08F4/00 , C08F293/00
CPC分类号： C08G65/329 , C08F210/16 , C08G2261/126 , C08L71/02 , C08L2205/05 , C10G75/04 , C10G2300/1088 , C10G2300/4075 , C10G2400/22 , C08F2/005 , C08F210/14 , C08F2500/17 , C08F2500/12 , C08F2500/18 , C08F210/08 , C08L23/00
摘要： The invention provides a method for preventing fouling in chemical equipment, comprising adding an antifouling agent which comprises a polyoxyalkylene polymer having Mn of 30,000 or less to a component in the chemical equipment.
摘要翻译：本发明提供一种防止化学设备中结垢的方法，包括向化学设备中的组分添加包含Mn为30,000以下的聚氧化烯聚合物的防污剂。

4. 发明授权

US08604140B2 Method for preventing fouling in chemical equipment and antifouling agent 失效
标题翻译：防止化学设备和防污剂污染的方法
公开(公告)号：US08604140B2
公开(公告)日：2013-12-10
申请号：US13258554
申请日：2010-03-31
申请人： Naoshi Nagai , Shiro Nakatsuka , Kazuoki Nakai , Kenji Sugimura , Yasushi Tohi , Ken Yoshitsugu , Hideki Bando , Yasuyuki Harada
发明人： Naoshi Nagai , Shiro Nakatsuka , Kazuoki Nakai , Kenji Sugimura , Yasushi Tohi , Ken Yoshitsugu , Hideki Bando , Yasuyuki Harada
IPC分类号： C08F210/16 , C08G65/329 , C08L71/02 , C10G75/04
CPC分类号： C08G65/329 , C08F210/16 , C08G2261/126 , C08L71/02 , C08L2205/05 , C10G75/04 , C10G2300/1088 , C10G2300/4075 , C10G2400/22 , C08F2/005 , C08F210/14 , C08F2500/17 , C08F2500/12 , C08F2500/18 , C08F210/08 , C08L23/00
摘要： The invention provides a method for preventing fouling in chemical equipment, comprising adding an antifouling agent which comprises a polyoxyalkylene polymer having Mn of 30,000 or less to a component in the chemical equipment.
摘要翻译：本发明提供一种防止化学设备中结垢的方法，包括向化学设备中的组分添加包含Mn为30,000以下的聚氧化烯聚合物的防污剂。

5. 发明申请

US20100069588A1 PROCESS FOR PRODUCTION OF SYNDIOTACTIC PROPYLENE POLYMER 有权
标题翻译：生产聚丙烯聚合物的方法
公开(公告)号：US20100069588A1
公开(公告)日：2010-03-18
申请号：US12312483
申请日：2007-11-16
申请人： Tomohiro Yamaguchi , Junpei Tanaka , Shiro Otsuzuki , Yasushi Tohi , Kouji Nagahashi , Nobukazu Yamahira , Shigenobu Ikenaga , Sunil Krzysztof Moorthi , Kazunori Kamio
发明人： Tomohiro Yamaguchi , Junpei Tanaka , Shiro Otsuzuki , Yasushi Tohi , Kouji Nagahashi , Nobukazu Yamahira , Shigenobu Ikenaga , Sunil Krzysztof Moorthi , Kazunori Kamio
IPC分类号： C08F4/52 , C08F4/76
CPC分类号： C08F10/06 , C08F4/65912 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2/06 , C08F2500/16 , C08F2500/17 , C08F2500/12 , C08F2500/26
摘要： It is an object of the present invention to provide a process for producing a syndiotactic propylene polymer with high polymerization activity and high efficiency by a solution polymerization method without deposition of polymers (excluding a white state), and a production process capable of conducting the above production continuously, provided that these processes could not be attained conventionally.The present invention is: a process for producing a syndiotactic propylene polymer having a syndiotactic pentad fraction (rrrr fraction), as measured by 13C-NMR, of at least 85%, a melting point (Tm), as measured by DSC, of from 145° C. to 170° C., and an intrinsic viscosity [η] of 0.1 to 10 dl/g, which process comprises a step (P1) of solution polymerizing propylene singly or propylene and at least one monomer selected from ethylene and an α-olefin having 4 to 10 carbon atoms at a polymerization temperature (TR) of from 30° C. to 250° C. in an inert hydrocarbon solvent in the presence of an olefin polymerization catalyst which comprises; (A) a bridged metallocene compound represented by the following formula (I), and (B) at least one compound selected from (b-1) an organoaluminum oxy compound, (b-2) a compound capable of forming an ion pair by reacting with the metallocene compound (A), and (b-3) an organoaluminum compound. in which M is a titanium atom or the like, Q is a halogen atom or the like, j is an integer of 1 to 4, Ra and Rb may be identically or differently a single nuclear or polynuclear hydrocarbon residue capable of forming a sandwich structure together with M, Y is a carbon atom or a silicon atom, and Rc and Rd may be the same or different from each other, is selected from hydrogen, a hydrocarbon group and a silicon atom-containing group and further may be bonded each other to form a ring.
摘要翻译：本发明的目的是提供一种通过不沉积聚合物（不包括白色状态）的溶液聚合法制备具有高聚合活性和高效率的间同立构丙烯聚合物的方法，以及能够进行上述只要这些方法不能常规地实现即可。本发明是通过13 C-NMR测定的具有间同立构五单元组分（rrrr分数）的间同立构丙烯聚合物的方法，其通过DSC测定为至少85％，熔点（Tm） 145℃至170℃，特性粘度[η]为0.1至10dl / g，该方法包括使丙烯单独或丙烯和至少一种选自乙烯和/或丙烯的单体的溶液聚合的步骤（P1）在烯烃聚合催化剂存在下，在惰性烃溶剂中，在30℃至250℃的聚合温度（TR）下具有4至10个碳原子的α-烯烃，其包含：（A）由下式（I）表示的桥连金属茂化合物和（B）至少一种选自（b-1）有机铝氧化合物的化合物，（b-2）能够形成离子对的化合物与茂金属化合物（A）和（b-3）有机铝化合物反应。其中M为钛原子等，Q为卤素原子等，j为1〜4的整数，Ra和Rb可以相同或不同，能形成夹层结构的单核或多核烃残基与M一起，Y是碳原子或硅原子，并且R c和R d可以相同或不同，选自氢，烃基和含硅原子的基团，并且可以彼此键合形成一个戒指。

6. 发明申请

US20050228155A1 Metallocene compound, process for preparing metallocene compund, olefin polymerization catalyst, process for preparing polyolefin, and polyolefin 有权
标题翻译：茂金属化合物，金属茂化合物的制备方法，烯烃聚合催化剂，制备聚烯烃的方法和聚烯烃
公开(公告)号：US20050228155A1
公开(公告)日：2005-10-13
申请号：US11054597
申请日：2005-02-10
申请人： Koji Kawai , Masahiro Yamashita , Yasushi Tohi , Nobuo Kawahara , Kenji Michiue , Hiromu Kaneyoshi , Ryoji Mori
发明人： Koji Kawai , Masahiro Yamashita , Yasushi Tohi , Nobuo Kawahara , Kenji Michiue , Hiromu Kaneyoshi , Ryoji Mori
IPC分类号： C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F4/72
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/15 , C08F210/16 , C08F210/08 , C08F2500/17
摘要： The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method. The process for preparing a polyolefin according to the invention is intended to prepare a polyolefin having excellent impact resistance and transparency, and this process comprises homopolymerizing an α-olefin of 3 to 8 carbon-atoms or copolymerizing an olefin of 3 to 8 carbon atoms and another α-olefin in the presence of an olefin polymerization catalyst containing the above-mentioned metallocene compound.
摘要翻译：根据本发明的茂金属化合物和含有该化合物的烯烃聚合催化剂旨在制备能够制备具有高聚合活性的全同立构聚合物的催化剂。茂金属化合物含有取代的环戊二烯基和（取代的）芴基，并且具有这些基团被烃基等桥接的结构。根据本发明的制备茂金属化合物的方法是为了选择性地制备特定的茂金属化合物以便不产生异构体，并且在该方法中通过具体方法合成中间产物。根据本发明的制备聚烯烃的方法旨在制备具有优异的耐冲击性和透明性的聚烯烃，该方法包括使3至8个碳原子的α-烯烃均聚或将3至8个碳原子的烯烃共聚，和在含有上述茂金属化合物的烯烃聚合催化剂存在下，制备另一种α-烯烃。

7. 发明授权

US06313243B1 Catalyst for olefin polymerization and method of polymerizing olefin 失效
标题翻译：用于烯烃聚合的催化剂和烯烃聚合方法
公开(公告)号：US06313243B1
公开(公告)日：2001-11-06
申请号：US09485637
申请日：2000-02-15
申请人： Yasushi Tohi , Shigekazu Matsui , Terunori Fujita
发明人： Yasushi Tohi , Shigekazu Matsui , Terunori Fujita
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F10/02 , C08F4/7047 , C08F4/704
摘要： The present invention is intended to provide an olefin polymerization catalyst exhibiting excellent olefin polymerization activity and capable of producing polyolefins of excellent properties and to provide a process for olefin polymerization using this catalyst. The olefin polymerization catalyst comprises a transition metal imine compound (A) represented by the following formula (I) and at least one compound (B) selected from an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and a compound (B-3) which reacts with the transition metal imine compound (A) to form an ion pair; wherein M is a transition metal atom of Group 8 to Group 11 of the periodic table; R1 to R4 are each a hydrogen atom, a hydrocarbon group or the like; R5 and R6 are each a hydrocarbon group or the like; R1 and R5, R2 and R6, R1 and R3, and R2 and R4 may be each bonded to form a ring; R3 and R4 may be bonded to form a ring; n is a number satisfying a valence of M; X is a halogen atom or the like; and Y is an atom of Group 16 of the periodic table.
摘要翻译：本发明旨在提供一种表现出优异的烯烃聚合活性且能够生产出优异性能的聚烯烃并提供使用该催化剂的烯烃聚合方法的烯烃聚合催化剂。烯烃聚合催化剂包含由下式（I）表示的过渡金属亚胺化合物（A）和至少一种选自有机金属化合物（B-1），有机铝氧化合物（B-2）和与过渡金属亚胺化合物（A）反应形成离子对的化合物（B-3）;其中M是周期表第8族至第11族的过渡金属原子; R 1〜R 4各自为氢原子，烃基等; R5和R6各自为烃基等; R1和R5，R2和R6，R1和R3，以及R2和R4各自键合形成环; R3和R4可以键合形成环; n是满足M价的数; X是卤素原子等; Y是元素周期表第16族的原子。

8. 发明授权

US06309997B1 Olefin polymerization catalysts, transition metal compounds, processes for olefin polymerization, and &agr;-olefin/conjugated diene copolymers 失效
标题翻译：烯烃聚合催化剂，过渡金属化合物，烯烃聚合方法和α-烯烃/共轭二烯共聚物
公开(公告)号：US06309997B1
公开(公告)日：2001-10-30
申请号：US09065593
申请日：1998-04-24
申请人： Terunori Fujita , Yasushi Tohi , Makoto Mitani , Shigekazu Matsui , Junji Saito , Masatoshi Nitabaru , Kiyoaki Sugi , Haruyuki Makio , Toshiyuki Tsutsui
发明人： Terunori Fujita , Yasushi Tohi , Makoto Mitani , Shigekazu Matsui , Junji Saito , Masatoshi Nitabaru , Kiyoaki Sugi , Haruyuki Makio , Toshiyuki Tsutsui
IPC分类号： B01J2106
CPC分类号： C08F210/02 , C07F7/003 , C07F7/0803 , C07F9/005 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/17 , C08F2500/01 , C08F2500/03 , C08F236/06 , C08F210/06 , C08F4/64189 , C08F4/64048 , C08F4/7022 , C08F4/6812
摘要： The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
摘要翻译：本发明提供了表现出优异聚合活性的烯烃聚合催化剂，使用该催化剂的烯烃聚合方法，用于催化剂的新型过渡金属化合物和具有特定性能的α-烯烃/共轭二烯共聚物。本发明的烯烃聚合催化剂包含（A）式（I）或（II）的过渡金属化合物和（B）有机金属化合物，或者是含有氧化铝的氧化合物或离子化离子化合物。本发明的新型过渡金属化合物是式（I）的化合物，其中M是周期表第3或4族的过渡膳食原子; m为1〜3的整数。 R1是烃基等; R2至R5各自为H，卤素，烃基等; R6是卤素，烃基等; n是满足M价的数; X为卤素，烃基等

9. 发明授权

US06297333B1 Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer 失效
标题翻译：烯烃聚合催化剂，制备烯烃聚合物的方法和烯烃聚合物
公开(公告)号：US06297333B1
公开(公告)日：2001-10-02
申请号：US09315268
申请日：1999-05-20
申请人： Junichi Imuta , Masayasu Yoshida , Yasushi Tohi
发明人： Junichi Imuta , Masayasu Yoshida , Yasushi Tohi
IPC分类号： C08F442
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F2500/17 , C08F2500/03 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： The olefin polymerization catalyst of the invention is formed from a Group IVB transition metal compound represented by the following formula (I) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair. In the olefin polymerization process of the invention using this catalyst or a catalyst formed from a Group IVB transition metal compound represented by the following formula (II) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair, an olefin (co)polymer having a high molecular weight can be obtained with high polymerization activities, and besides an olefin copolymer having a high comonomer content can be obtained even if a comonomer is used in a small amount, wherein, M is a transition metal of Group IVB, at least one of R1 is an aryl group and the remainder is hydrogen or the like, R2 is hydrogen, an alkyl group or the like, R3 and R4 are each hydrogen, an alkyl group or the like, R6 is hydrogen, an alkyl group or the like, R7 is hydrogen, an alkyl group or the like, any one of R8 and R9 is an alkyl group, and X1 and X2 are each halogen, a hydrocarbon group or the like.
摘要翻译：本发明的烯烃聚合催化剂由下式（I）表示的ⅣB族过渡金属化合物和有机铝氧化合物或与过渡金属化合物反应形成离子对的化合物形成。在使用该催化剂的本发明的烯烃聚合方法或由下式（II）表示的IVB族过渡金属化合物和有机铝氧化合物或与过渡金属化合物反应形成离子的化合物形成的催化剂可以获得高聚合活性的具有高分子量的烯烃（共）聚合物，并且即使使用少量共聚单体，也可以获得具有高共聚单体含量的烯烃共聚物，其中M为 IVB族的过渡金属，R 1中的至少一个是芳基，其余是氢等，R 2是氢，烷基等，R 3和R 4各自是氢，烷基等，R 6 是氢，烷基等，R 7是氢，烷基等，R 8和R 9中的任一个是烷基，X 1和X 2各自是卤素，烃基等。

10. 发明授权

US07847040B2 α-olefin-based polymer composition, molded product formed from the composition, and novel polymer 有权
标题翻译：基于α-烯烃的聚合物组合物，由该组合物形成的模塑产品和新型聚合物
公开(公告)号：US07847040B2
公开(公告)日：2010-12-07
申请号：US11578972
申请日：2005-04-08
申请人： Ryoji Mori , Takashi Nakagawa , Shigenobu Ikenaga , Hiromasa Marubayashi , Masahiko Okamoto , Yasushi Tohi , Kouji Nagahashi
发明人： Ryoji Mori , Takashi Nakagawa , Shigenobu Ikenaga , Hiromasa Marubayashi , Masahiko Okamoto , Yasushi Tohi , Kouji Nagahashi
IPC分类号： C08F4/48
CPC分类号： C08F210/06 , C08L23/10 , C08L23/142 , C08L2666/06
摘要： A composition having excellent transparency, flexibility, rubber elasticity, thermal resistance, impact resistance, abrasion resistance and the like, a composition having excellent rigidity and impact resistance as well as excellently balanced in whitening resistance, abrasion resistance and heat sealability, and a composition having excellent rubbery properties, thermal resistance, abrasion resistance and flexibility are provided.A composition comprising a specific propylene•α-olefin copolymer for which, in a signal chart measured by 13C-NMR and predetermined such that the peak present at the highest magnetic field among the signals originating from CH (methine) of the constituent unit derived from an α-olefin having 4 to 20 carbon atoms is to be at 34.4 ppm, an absorption intensity A at about 22.0 to 20.9 ppm and an absorption intensity B at about 19.0 to 20.6 ppm satisfy the following relational expressions (i) and (ii) with respect to an absorption intensity C at about 19.0 to 22.0 ppm, which is assignable to propylene methyl: (A/C)×100≦8 (i), and (B/C)×100≧60 (ii), a molded product thereof, and the α-olefin-based copolymer are provided.
摘要翻译：具有优异的透明性，柔软性，橡胶弹性，耐热性，耐冲击性，耐磨性等的组合物，具有优异的刚性和耐冲击性以及优异的耐白度，耐磨性和热封性均衡的组合物和具有提供优异的橡胶性能，耐热性，耐磨性和柔韧性。一种包含特定丙烯-α-烯烃共聚物的组合物，其以13 C-NMR测量的信号图表示，并且预先确定来自源自该构成单元的CH（次甲基）的CH（次甲基）的信号中的最高磁场存在的峰具有4至20个碳原子的α-烯烃应为34.4ppm，约22.0至20.9ppm的吸收强度A和约19.0至20.6ppm的吸收强度B满足以下关系式（i）和（ii）（A / C）×100＆nlE; 8（i）和（B / C）×100≥60（ii））中的约19.0〜22.0ppm的吸收强度C，其产物和α-烯烃基共聚物。

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