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1. 发明专利

JP2002097476A METHOD FOR CATALYTIC HYDROGENATION TREATMENT OF SILICON- CONTAINING NAPHTHA 审中-公开
公开(公告)号：JP2002097476A
公开(公告)日：2002-04-02
申请号：JP2001279481
申请日：2001-09-14
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER , NIELSEN LARS PLETH , CHRISTENSEN STEFFEN VISSING , JACOBSEN JOACHIM
IPC分类号： C10G45/02 , C10G45/04 , C10G45/06 , C10G45/08 , C10G49/00
摘要： PROBLEM TO BE SOLVED: To provide a method for prolonging the operational time of a hydrogenation treatment reactor for treating a silicon-containing feed stock by improving the capacity of a hydrogenation treatment catalyst to tolerate silicon. SOLUTION: This method comprises a stage of wetting a hydrogenation treatment catalyst with 0.01-10 vol.% water to be added to the feed stock.

2. 发明专利

JP2001040370A COMBINED PROCESS FOR IMPROVED HYDROGEN TREATMENT OF DIESEL FUEL 失效
公开(公告)号：JP2001040370A
公开(公告)日：2001-02-13
申请号：JP2000166580
申请日：2000-06-02
申请人： TOPSOE HALDOR AS
发明人： WHITEHURST DARRELL DUAYNE , BRORSON MICHAEL , GROEN KNUDSEN KIM , ZEUTHEN PER , COOPER BARRY H
IPC分类号： B01J27/051 , C10G21/00 , C10G21/28 , C10G25/12 , C10G45/02 , C10G45/44 , C10G67/04 , C10G67/06
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a clean fuel for transportation means having a total sulfur content lower than 500 ppm. SOLUTION: In a combined process for improved hydrogen treatment of a diesel fuel, a feed to be subjected to the hydrogen treatment is treated with a selective adsorbent before a hydrogen treatment step, thus removing polar materials, especially nitrogen compounds. This selective adsorption process can be carried out by using a liquid adsorbent or a solid adsorbent and in a state selected from various states such as an agitation tank, a hydroclone, a moving bed, a fixed bed, an ebullient bed, and a fluidized bed. In an operation to move both the adsorbent and the diesel fuel in a reaction and adsorption zones, their flow may be in parallel current flow or countercurrent flow. After brought into contact with the fuel, the adsorbent containing undesired polar compounds is separated from the fuel, and the resultant fuel containing no inhibitor substance is treated with a generally used apparatus. The separated adsorbent is subjected to regeneration treatment and is returned to the adsorption zone to be recycled.

3. 发明专利

JP2001207177A METHOD FOR REDUCING CONTENT OF SULFUR COMPOUND AND POLYCYCLIC AROMATIC HYDROCARBON IN HYDROCARBON FEED 失效
公开(公告)号：JP2001207177A
公开(公告)日：2001-07-31
申请号：JP2001017170
申请日：2001-01-25
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER , COOPER BARRY H
IPC分类号： B01J23/88 , C10G45/02 , C10G45/50 , C10G65/04 , C10G65/08 , C10L1/00 , C10L1/08
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a low-sulfur and low nitrogen FCC feed having small content of a polycyclic aromatic hydrocarbon, and thereby for increasing an FCC yield and especially the quantity of production of an FCC gasoline. SOLUTION: This method for reducing the content of the sulfur compound and the polycyclic aromatic hydrocarbon in the feedstock of a hydrocarbon having 200-600 deg.C boiling point range is characterized by each step of (a) a step for bringing the feedstock into contact with hydrogen on a hydrogenation catalyst under a condition effective for the hydrogenation treatment to provide a hydrogenated outflow containing the hydrogenated feedstock, hydrogen sulfide and the hydrogen, (b) a step for cooling the outflow, and (c) a step for bringing the cooled outflow into contact with the hydrogenation catalyst under a condition effective for the hydrogenation of the polycyclic aromatic hydrocarbon.

4. 发明专利

ES2223692T3 PROCEDIMIENTO PARA EL HIDROTRATAMIENTO CATALITICO DE SILICIO QUE CONTIENE NAFTA. 未知
公开(公告)号：ES2223692T3
公开(公告)日：2005-03-01
申请号：ES01120960
申请日：2001-08-31
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER , NIELSEN LARS PLETH , CHRISTENSEN STEFFEN VISSING , JACOBSEN JOACHIM
IPC分类号： C10G45/02 , C10G45/04 , C10G45/06 , C10G45/08 , C10G49/00
摘要： Procedimiento para el hidrotratamiento catalítico de un material base de hidrocarburos que contiene compuestos de silicio, poniendo en contacto el material base en presencia de hidrógeno con un catalizador de hidrotratamiento en condiciones efectivas para el hidrotratamiento del material base, caracterizado porque el catalizador de hidrotratamiento se humedece con una cantidad de agua añadida al material base, estando la cantidad de agua entre 0, 01 y 10% en volumen.

5. 发明专利

DE69808542T2 未知
公开(公告)号：DE69808542T2
公开(公告)日：2003-02-13
申请号：DE69808542
申请日：1998-04-03
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER
IPC分类号： B01J23/63 , B01J23/652 , B01J23/83 , C10G45/60 , B01J23/36 , B01J23/85 , C10G45/62
摘要： Catalyst for ring opening of cyclic organic compounds comprising on a carrier of alumina, silica, zirconia and mixtures thereof; from 0.1 to 10 per cent by weight based on the total weight of the catalyst of a catalytic active metal selected from platinum, palladium, rhodium, rhenium, iridium, ruthenium, nickel, cobalt and mixtures or combinations thereof and from 0.01 to 20 per cent by weight based on the total weight of the catalyst of a metal modifier selected from tungsten, molybdenum lanthanum and rare earth metals and mixtures and combinations thereof.

6. 发明专利

NO20010419L 未知
公开(公告)号：NO20010419L
公开(公告)日：2001-07-26
申请号：NO20010419
申请日：2001-01-24
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER , COOPER BARRY H
IPC分类号： B01J23/88 , C10G45/02 , C10G45/50 , C10G65/04 , C10G65/08 , C10L1/00 , C10L1/08

7. 发明专利

NO20010419D0 未知
公开(公告)号：NO20010419D0
公开(公告)日：2001-01-24
申请号：NO20010419
申请日：2001-01-24
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER , COOPER BARRY H
IPC分类号： B01J23/88 , C10G45/02 , C10G45/50 , C10G65/04 , C10G65/08 , C10L1/00 , C10L1/08 , C10G

8. 发明专利

CA2332157A1 PROCESS FOR REDUCING CONTENT OF SULPHUR COMPOUNDS AND POLY-AROMATIC HYDROCARBONS IN A HYDROCARBON FEED 未知
公开(公告)号：CA2332157A1
公开(公告)日：2001-07-25
申请号：CA2332157
申请日：2001-01-24
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER , COOPER BARRY H
IPC分类号： B01J23/88 , C10G45/02 , C10G45/50 , C10G65/04 , C10G65/08 , C10L1/00 , C10L1/08
摘要： A process for reducing content of sulphur compounds and polyaromatic hydrocarbons in a hydrocarbon feed having a boiling range between 200.degree.C and 600.degree.C, which process com- prises in combination contacting the feed and hydrogen over a hydrotreating catalyst and hydrotreating feed at hydro- treating conditions, cooling the hydrotreated effluent and hydrogen-rich gas from the hydrotreating reactor contacting said effluent and hydrogen gas over a hydrotreating cata- lyst in a post-pretreatment reactor at a temperature suffi- cient to lower the polyaromatic hydrocarbon content.

9. 发明专利

AU3784000A A combined process for improved hydrotreating of diesel fuels 未知
公开(公告)号：AU3784000A
公开(公告)日：2000-12-07
申请号：AU3784000
申请日：2000-06-01
申请人： TOPSOE HALDOR AS
发明人： WHITEHURST DARRELL DUAYNE , BRORSON MICHAEL , KNUDSEN KIM GRON , ZEUTHEN PER , COOPER BARRY H
IPC分类号： B01J27/051 , C10G21/00 , C10G21/28 , C10G25/12 , C10G45/02 , C10G45/44 , C10G67/04 , C10G67/06 , C10G25/09 , B01J29/00
摘要： Described herein is a combined process for improved hydrotreating of diesel fuels, in which the feed to be hydrotreated is pretreated with a selective adsorbent prior to the hydrotreating step to remove polar materials, especially nitrogen containing compounds (N-compounds). By removing the N-compounds in this way, it is possible to achieve extremely high conversions of refractory sulphur compounds in the diesel fuel at moderate hydroprocessing conditions. If the diesel fuel is hydrotreated without prior removal of N-compounds, excessive amounts of hydrotreating catalysts must be used and high temperatures and pressures must be employed. This is particularly true when sulphur levels of below 500 ppm are desired. The selective adsorption process can employ either liquid or solid adsorbents, and may be operated in a variety of modes, including stirred tanks, hydroclones, moving beds, fixed beds, ebulated beds or fluidized beds. In operations, where the adsorbent and diesel fuel are both moving through the reaction adsorption zone, the flows can be either cocurrent or countercurrent. After contact of the adsorbent with the diesel fuel feed, the adsorbent containing undesired polar compounds is separated from the diesel fuel and the inhibitor free fuel is processed in conventional equipment. The separated adsorbent is then subjected to a two step procedure for regeneration. First any physically adsorbed inhibitor free fuel is recovered. For example, if a solid adsorbent is employed, the solid containing physically adsorbed diesel fuel is contacted with a stripper gas such as steam to strip off the inhibitor free fuel, while leaving the polar compounds strongly adsorbed on the solid adsorbent. The polar compounds may then be removed either by an oxygenative or hydrogenative process. A schematic representation of this combined process is shown in Fig. 1.

10. 发明专利

CA2310555A1 A COMBINED PROCESS FOR IMPROVED HYDROTREATING OF DIESEL FUELS 未知
公开(公告)号：CA2310555A1
公开(公告)日：2000-12-02
申请号：CA2310555
申请日：2000-06-01
申请人： TOPSOE HALDOR AS
发明人： ZEUTHEN PER , COOPER BARRY H , KNUDSEN KIM GRON , WHITEHURST DARRELL DUAYNE , BRORSON MICHAEL
IPC分类号： B01J27/051 , C10G21/00 , C10G21/28 , C10G25/12 , C10G45/02 , C10G45/44 , C10G67/04 , C10G67/06
摘要： Described herein is a combined process for improved hydrotreating of diesel fuels, in which the feed to be hydrotreated is pretreated with a selective adsorbent prior to the hydrotreating step to remove polar materials, especially nitrogen containing compounds (N-compounds). By removing the N-compounds in this way, it is possible to achieve extremely high conversions of refractory sulphur compounds in the diesel fuel at moderate hydroprocessing conditions. If the diesel fuel is hydrotreated without prior removal of N-compounds, excessive amounts of hydrotreating catalysts must be used and high temperatures and pressures must be employed. This is particularly true when sulphur levels of below 500 ppm are desired. The selective adsorption process can employ either liquid or solid adsorbents, and may be operated in a variety of modes, including stirred tanks, hydroclones, moving beds, fixed beds, ebulated beds or fluidized beds. In operations, where the adsorbent and diesel fuel are both moving through the reaction adsorption zone, the flows can be either cocurrent or countercurrent. After contact of the adsorbent with the diesel fuel feed, the adsorbent containing undesired polar compounds is separated from the diesel fuel and the inhibitor free fuel is processed in conventional equipment. The separated adsorbent is then subjected to a two step procedure for regeneration. First any physically adsorbed inhibitor free fuel is recovered. For example, if a solid adsorbent is employed, the solid containing physically adsorbed diesel fuel is contacted with a stripper gas such as steam to strip off the inhibitor free fuel, while leaving the polar compounds strongly adsorbed on the solid adsorbent. The polar compounds may then be removed either by a oxygenative or hydrogenative process.

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