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1. 发明申请

WO2015028682A1 PROCESS FOR PREPARING A CATALYST, CATALYST OBTAINED BY SUCH PROCESS, AND USE OF SUCH CATALYST 审中-公开
标题翻译：制备催化剂，通过这种方法获得的催化剂的方法，以及这些催化剂的使用
公开(公告)号：WO2015028682A1
公开(公告)日：2015-03-05
申请号：PCT/EP2014/068580
申请日：2014-09-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： ESPINOSA ALONSO, Leticia , FRANSSEN, Nicole Maria Gerarda , GEYER, Reinhard , RIGUTTO, Marcello Stefano , SCHAVERIEN, Colin John
IPC分类号： B01J23/755 , B01J37/02 , C10G1/00 , C10G3/00
CPC分类号： B01J23/755 , B01J37/02 , C10G3/44 , C10G3/50 , C10G2300/1011 , Y02P30/20
摘要： A process for converting a biomass-derived pyrolysis oil comprising contacting a feed containing the biomass-derived pyrolysis oil with hydrogen at a temperature in the range from 50°C to 350°C in the presence of a catalyst, wherein the catalyst comprises - equal to or more than 5wt% of one or more Group VIII metals, calculated on an elemental metal basis, based on the total weight of the catalyst; - one or more Group V elements; and - a refractory oxide selected from the Group consisting of titania, zirconia, silica and mixtures thereof.
摘要翻译：一种用于转化生物质衍生的热解油的方法，包括在催化剂存在下，将含有生物质衍生的热解油的进料与氢气在50℃至350℃的温度下接触，其中催化剂包括 - 相等至少5重量％的一种或多种基于元素金属计算的第VIII族金属，基于催化剂的总重量; - 一个或多个V组元素; 和 - 选自二氧化钛，氧化锆，二氧化硅及其混合物的耐火氧化物。

2. 发明申请

WO2015028681A1 PROCESS FOR PREPARING A CATALYST, CATALYST OBTAINED BY SUCH PROCESS, AND USE OF SUCH CATALYST 审中-公开
标题翻译：制备催化剂，通过这种方法获得的催化剂的方法，以及这些催化剂的使用
公开(公告)号：WO2015028681A1
公开(公告)日：2015-03-05
申请号：PCT/EP2014/068577
申请日：2014-09-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： AZGHAY, Ali , ESPINOSA ALONSO, Leticia , FRANSSEN, Nicole Maria Gerarda , RIGUTTO, Marcello Stefano , SCHAVERIEN, Colin John
IPC分类号： B01J23/755 , B01J37/02 , C10G1/00 , C10G3/00
CPC分类号： B01J23/755 , B01J23/40 , B01J23/70 , B01J37/0201 , B01J37/0213 , C10G3/44 , C10G3/50 , C10G2300/1011 , Y02P30/20
摘要： A process for converting a biomass-derived pyrolysis oil comprising the following steps: i) preparing a catalyst, preferably containing one or more Group VIII metals in an amount of equal to or more than 5 wt%, based on the total weight of the catalyst, by a method including preparing a basic metal-containing aqueous solution with a pH of equal to or more than 7.0, by mixing one or more Group VIII metal components and a water-soluble base in an aqueous solvent; and impregnating a refractory oxide, selected from the group consisting of titania, zirconia, silica and mixtures thereof, with the basic metal-containing aqueous solution; and ii) contacting a feed containing the biomass-derived pyrolysis oil with hydrogen at a temperature in the range from 50°C to 350°C in the presence of the catalyst.
摘要翻译：一种用于转化生物质衍生的热解油的方法，包括以下步骤：i）基于催化剂的总重量制备催化剂，优选含有等于或大于5重量％的一种或多种第VIII族金属通过在水性溶剂中混合一种以上的第VIII族金属成分和水溶性碱，通过包括制备pH为7.0以上的含碱性金属的水溶液的方法，并将含有碱金属的水溶液浸渍选自二氧化钛，氧化锆，二氧化硅及其混合物的难熔氧化物; 和ii）在催化剂存在下，将含有生物质衍生的热解油的进料与氢气在50℃至350℃的温度下接触。

3. 发明申请

WO2014041152A1 PROCESS FOR THE PREPARATION OF A HYDROCRACKING CATALYST 审中-公开
标题翻译：制备水解催化剂的方法
公开(公告)号：WO2014041152A1
公开(公告)日：2014-03-20
申请号：PCT/EP2013/069113
申请日：2013-09-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： JONGKIND, Hermanus , KIJLSTRA, Wiebe Sjoerd , PELGRIM, Bart , RIGUTTO, Marcello Stefano , WINTER, Ferry
IPC分类号： B01J37/02 , B01J37/04 , B01J23/888 , C10G47/20 , B01J29/16 , B01J29/14 , B01J35/00 , B01J37/20
CPC分类号： B01J29/166 , B01J21/04 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J29/146 , B01J31/06 , B01J35/0006 , B01J37/0203 , B01J37/0205 , B01J37/0213 , B01J37/04 , B01J37/08 , B01J37/20 , B01J2229/16 , B01J2229/186 , B01J2229/42 , C10G47/20
摘要： The invention relates to a process for the preparation of a hydrocracking catalyst, which comprises the steps of: (a) mixing a zeolite Y having a unit cell size in the range of from 24.42 to 24.52 Å, a bulk silica to alumina molar ratio (SAR) in the range of from 10 to 15, and a surface area of from 910 to 1020 m 2 /g with an alumina binder component and two or more catalytically active metal components which metal components are contained in one or more solutions, wherein the zeolite Y is present in an amount of 40 wt.% or greater, based on the total weight of the zeolite Y and the alumina binder component; (b) extruding the mixture as obtained in step (a); (c) drying the extruded mixture as obtained in step (b); (d) calcining the dried and extruded mixture as obtained in step (c); and (e) mixing the calcined product as obtained in step (d) with two or more catalytically active metal components which metal components are contained in one or more solutions. The invention further provides a process for hydrocracking a hydrocarbonaceous feedstock, which process comprises contacting the feedstock at elevated temperature with a hydrocracking catalyst as prepared by the present process. A process for the preparation of a hydrocracking catalyst, which comprises the steps of: (a) mixing a zeolite Y having a unit cell size in the range of from 24.42 to 24.52 A, a bulk silica to alumina molar ratio (SAR) in the range of from 10 to 15, and a surface area of from 910 to 1020 m 2 /g with an alumina binder component and a first metals-containing solution), wherein the zeolite Y is present in an amount of 40 wt.% or greater, based on the total weight of the zeolite Y and the alumina binder component; (b) extruding the mixture as obtained in step (a); (c) drying the extruded mixture as obtained in step (b); (d) calcining the dried and extruded mixture as obtained in step (c); and (e) impregnating the calcined product as obtained in step (d) with a second metals-containing solution.
摘要翻译：本发明涉及一种制备加氢裂化催化剂的方法，其包括以下步骤：（a）将具有24.42至24.52埃的单位晶胞尺寸的沸石Y，本体二氧化硅与氧化铝的摩尔比（ SAR）为10〜15，表面积为910〜1020m2 / g，具有氧化铝粘合剂成分和2种以上催化活性金属成分，该金属成分含在一种或多种溶液中，其中沸石基于沸石Y和氧化铝粘结剂组分的总重量，Y以40重量％或更大的量存在; （b）挤出步骤（a）中获得的混合物; （c）干燥步骤（b）中获得的挤出混合物; （d）煅烧步骤（c）中获得的干燥和挤出的混合物; 和（e）将步骤（d）中获得的煅烧产物与两种或更多种催化活性金属组分混合，所述金属组分在一种或多种溶液中包含。本发明还提供了一种烃类原料的加氢裂化方法，该方法包括使原料在升高的温度下与本方法制备的加氢裂化催化剂接触。一种制备加氢裂化催化剂的方法，其包括以下步骤：（a）将具有24.42至24.52A范围内的晶胞尺寸的沸石Y与本体二氧化硅与氧化铝的摩尔比（SAR）混合在一起范围为10至15，表面积为910至1020m2 / g，氧化铝粘合剂组分和第一含金属溶液），其中沸石Y的存在量为40重量％以上，基于沸石Y和氧化铝粘结剂组分的总重量; （b）挤出步骤（a）中获得的混合物; （c）干燥步骤（b）中获得的挤出混合物; （d）煅烧步骤（c）中获得的干燥和挤出的混合物; 和（e）用第二含金属溶液浸渍在步骤（d）中获得的煅烧产物。

4. 发明申请

WO2022101327A1 A METHOD OF PREPARING A HYDROCRACKING CATALYST 审中-公开
公开(公告)号：WO2022101327A1
公开(公告)日：2022-05-19
申请号：PCT/EP2021/081350
申请日：2021-11-11
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： DEN BREEJEN, Johan Peter , OUWEHAND, Cornelis , RIGUTTO, Marcello Stefano
IPC分类号： B01J29/12 , B01J35/10 , C10G47/18
摘要： The present invention provides a method of preparing a supported catalyst, preferably a hydrocracking catalyst, the method at least comprising the steps of:a) providing a zeolite Y having a bulk silica to alumina molar ratio (SAR) of at least 10; b) contacting the zeolite Y provided in step a) with a base and a surfactant, thereby obtaining a zeolite Y with increased mesoporosity; c) shaping the zeolite Y with increased mesoporosity as obtained in step b) thereby obtaining a shaped10catalyst carrier; d) calcining the shaped catalyst carrier as obtained in step c) in the presence of the surfactant of step b), thereby obtaining a calcined catalyst carrier; e) impregnating the catalyst carrier calcined in step d) with a noble metal component thereby obtaining a supported catalyst.

5. 发明申请

WO2013127592A1 A TITANIA-BOUND ZEOLITE EU-2 CATALYST COMPOSITION AND METHOD OF MAKING AND USING SUCH COMPOSITION 审中-公开
标题翻译： TITANIA-BOUND ZEOLITE EU-2催化剂组合物及其制备和使用这种组合物的方法
公开(公告)号：WO2013127592A1
公开(公告)日：2013-09-06
申请号：PCT/EP2013/051914
申请日：2013-01-31
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： GEERINCK, Peter , JONGKIND, Hermanus , PELGRIM, Bart , RIGUTTO, Marcello Stefano
IPC分类号： B01J29/70 , B01J29/74 , C07C5/27 , C10G45/64
CPC分类号： B01J29/7461 , B01J21/063 , B01J29/703 , B01J29/74 , B01J2229/16 , B01J2229/186 , B01J2229/32 , B01J2229/37 , B01J2229/42 , C10G45/62 , C10G45/64 , C10G73/02
摘要： Catalyst composition useful in the catalytic dewaxing of a waxy hydrocarbon feedstock which catalyst composition includes a mixture of zeolite EU-2 and titania and may further include a noble metal. The zeolite EU-2 has a molar bulk ratio of silica-to-alumina (SAR) of greater than 100:1. The zeolite or mixture may have been dealuminated such as by acid leaching using a fluorosilicate salt or by steam treating.
摘要翻译：可用于蜡质烃原料的催化脱蜡的催化剂组合物，该催化剂组合物包括沸石EU-2和二氧化钛的混合物，并且还可包含贵金属。沸石EU-2的二氧化硅 - 氧化铝（SAR）的摩尔体积比大于100:1。沸石或混合物可以已经脱铝，例如通过使用氟硅酸盐的酸浸或通过蒸汽处理。

6. 发明申请

WO2012071137A1 PROCESS FOR HYDROCRACKING BUTANE OR NAPHTHA IN THE PRESENCE OF A COMBINATION OF TWO ZEOLITES 审中-公开
标题翻译：在两种沸石组合存在下水解棕榈酸或萘甲酸的方法
公开(公告)号：WO2012071137A1
公开(公告)日：2012-05-31
申请号：PCT/US2011/058599
申请日：2011-10-31
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BAKKER, Geert Marten , BHAVAN, Saravana , KAYGAY, Bruce , KHANDAVILLI, Muralikrishna Venkatacharyulu , KOORNNEEF, Malgorzata Anna , NARASIMHAN, Chilkoor Soundararajan Laxmi , RIGUTTO, Marcello Stefano , VAN VEGCHEL, Ingrid Maria , WINTER, Ferry
发明人： BAKKER, Geert Marten , BHAVAN, Saravana , KAYGAY, Bruce , KHANDAVILLI, Muralikrishna Venkatacharyulu , KOORNNEEF, Malgorzata Anna , NARASIMHAN, Chilkoor Soundararajan Laxmi , RIGUTTO, Marcello Stefano , VAN VEGCHEL, Ingrid Maria , WINTER, Ferry
IPC分类号： C07C4/04 , C07C9/00 , C07C9/10 , C07C11/04 , C07C11/06
CPC分类号： C07C4/06 , B01J29/44 , B01J29/7484 , B01J29/80 , B01J2229/18 , C07C2529/44 , C07C2529/74 , C10G47/18 , C10G47/20 , C10G2300/1044 , C10G2300/202 , C10G2400/20 , Y02P20/52 , C07C11/04 , C07C11/06
摘要： The present invention provides a process for preparing a gas cracker feedstock, comprising contacting a feed containing one or more paraffins comprising 4 to 12 carbon atoms with a catalyst comprising at least one zeolite having 10-membered ring channels and at least one group VIb, VIIb and/or VIII metal, in the presence of hydrogen at elevated temperatures and elevated pressures and converting at least 40wt% of the paraffins comprising 4 to 12 carbon atoms based on the total weight of paraffins comprising 4 to 12 carbon atoms in the feed to ethane and/or propane to obtain a hydrocracked gas cracker feedstock comprising ethane and/or propane. In a further aspect the invention also relates to a process for producing olefins.
摘要翻译：本发明提供一种制备气体裂化器原料的方法，包括使含有一种或多种包含4-12个碳原子的链烷烃的进料与包含至少一种具有10元环通道的沸石和至少一种VIb，VIIb 和/或VIII金属，在氢气存在下，在升高的温度和升高的压力下，并将至少40重量％的包含4-12个碳原子的链烷烃基于在乙烷的进料中含有4至12个碳原子的链烷烃的总重量和/或丙烷，以获得包含乙烷和/或丙烷的加氢裂化气体裂化器原料。在另一方面，本发明还涉及一种生产烯烃的方法。

7. 发明申请

WO2012038413A1 PROCESS FOR REDUCING THE HALOGEN CONTENT OF A HYDROCARBON PRODUCT STREAM BY MIXING WITH AN AQEOUS CAUSTIC SOLUTION IN THE PRESENCE OF A PHASE TRANSFER CATALYST 审中-公开
标题翻译：在相转移催化剂存在下通过混合原料溶液来降低烃类产物流的含量的方法
公开(公告)号：WO2012038413A1
公开(公告)日：2012-03-29
申请号：PCT/EP2011/066301
申请日：2011-09-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , RIGUTTO, Marcello Stefano , KLUSENER, Peter Anton August , SCHOON, Lodewijk
发明人： RIGUTTO, Marcello Stefano , KLUSENER, Peter Anton August , SCHOON, Lodewijk
IPC分类号： C10G19/02 , C10G19/04 , C07C7/148
CPC分类号： C10G19/02 , C07C7/10 , C10G19/04 , C10G2300/201 , C10G2300/4081 , C07C9/15
摘要： The present invention provides a process for reducing the halogen content of a hydrocarbon product stream which is obtained by a hydrocarbon conversion process in which use is made is made of a halogen- containing acidic ionic liquid catalyst, which process comprises the steps of: (a) mixing the hydrocarbon product stream with an aqueous caustic solution in the presence of a phase transfer catalyst; (b) separating from the mixture obtained in step (a) a hydrocarbon-rich phase and a caustic-rich phase; and (c) recovering the hydrocarbon-rich phase having a halogen content which is smaller than the halogen content of the hydrocarbon product stream.
摘要翻译：本发明提供一种降低烃产物流的卤素含量的方法，其通过烃转化方法获得，其中使用含卤素的酸性离子液体催化剂，该方法包括以下步骤：（a ）在相转移催化剂存在下将烃产物流与苛性碱水溶液混合; （b）从步骤（a）获得的混合物中分离富烃相和苛性碱相; 和（c）回收卤素含量小于烃产物流的卤素含量的富烃相。

8. 发明申请

WO2021255145A1 PROCESS TO PREPARE FISCHER-TROPSCH DERIVED MIDDLE DISTILLATES AND BASE OILS 审中-公开
公开(公告)号：WO2021255145A1
公开(公告)日：2021-12-23
申请号：PCT/EP2021/066351
申请日：2021-06-17
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： CREYGHTON, Edward Julius , SAMMELIUS, Olav , RIGUTTO, Marcello Stefano , JANSSEN, Andries Hendrik
IPC分类号： C10G2/00 , C10G45/64 , C10G45/62 , C10L1/00 , C10M171/02 , C10L1/08 , C10L1/02 , C10G2/30 , C10G2300/1022 , C10G2400/02 , C10G2400/06 , C10G2400/10 , C10L1/026 , C10M107/02 , C10M2205/173 , C10N2020/01 , C10N2020/011 , C10N2020/02
摘要： The present invention provides a process to prepare middle distillates and base oils from a Fischer-Tropsch product, by (a) subjecting the Fischer-Tropsch product to a hydroprocessing step in the presence of a catalyst comprising a molecular sieve with a pore size between 5 and 7 angstrom and a SiO2/AlO3 ratio of at least 25, preferably from 50 to 180 and a group VIII metal to obtain a mixture comprising one or more middle distillate fractions and a first residual fraction and a naphtha fraction; (b) separating the mixture as obtained in step (a) by means of atmospheric distillation into one or more middle distillate fractions, a first residual fraction and a naphtha fraction;(c) separating the first residual fraction by means of vacuum distillation into at least a distillate base oil fraction and a second residual fraction.

9. 发明申请

WO2015104320A1 PROCESS FOR CONVERTING A BIOMASS-DERIVED PYROLYSIS OIL, METHOD FOR PREPARING A CATALYST, AND A CATALYST 审中-公开
标题翻译：用于转化生物质衍生的热解油的方法，制备催化剂的方法和催化剂
公开(公告)号：WO2015104320A1
公开(公告)日：2015-07-16
申请号：PCT/EP2015/050235
申请日：2015-01-08
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： FRANSSEN, Nicole Maria Gerarda , RIGUTTO, Marcello Stefano
IPC分类号： B01J37/04 , B01J23/72 , B01J23/755 , C10G3/00
CPC分类号： C10G3/45 , B01J23/72 , B01J23/755 , B01J37/04 , B01J37/08 , C10G3/48 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , C10G2300/70 , Y02P30/20
摘要： A process for converting a biomass-derived pyrolysis oil in which the pyrolysis oil is contacted with hydrogen in the presence of a catalyst, comprising the following steps: i) preparing a catalyst containing at least one or more Group VIII metals, preferably in an amount of equal to or more than 2wt%, more preferably equal to or more than 16wt%, even more preferably equal to or more than 18wt%, most preferably equal to or more than 20wt%, to equal to or less than 80wt%, more preferably to equal to or less than 65wt% based on the total weight of the catalyst, by a method comprising - (a) comulling (1) a refractory oxide, (2) a small amount of liquid, chosen such that the Loss On Ignition (LOI) at 485°C of the mixture is from equal to or more than 20wt% to equal to or less than 70wt% based on the total weight of the catalyst composition,and (3) at least one or more metal component(s), which is/are at least partially insoluble in the amount of liquid used, to form a mixture, wherein the metal component(s) is/are at least one or more Group VIII metal component, preferably nickel or a nickel component; - (b) optionally shaping, and drying of the mixture thus obtained; and - (c) calcination of the composition thus obtained to provide a calcined catalyst; and ii) contacting a feed containing the biomass-derived pyrolysis oil with hydrogen at a temperature in the range from 50°C to 350°C in the presence of the catalyst prepared in step i).
摘要翻译：一种转化生物质衍生的热解油的方法，其中所述热解油在催化剂存在下与氢接触，所述方法包括以下步骤：i）制备含有至少一种或多种第Ⅷ族金属的催化剂，优选量为等于或大于2重量％，更优选等于或大于16重量％，甚至更优选等于或大于18重量％，最优选等于或大于20重量％，等于或小于80重量％优选等于或小于65重量％，通过包括以下的方法：（a）将（1）难熔氧化物，（2）少量液体，选择为使得点火损失混合物的485℃下的（LOI）为基于催化剂组合物的总重量等于或大于20重量％至等于或小于70重量％，和（3）至少一种或多种金属组分），其至少部分不溶于所用液体的量，以形成混合物，其中金属组分为至少一种或多种第VIII族金属组分，优选镍或镍组分; - （b）任选地成型和干燥由此获得的混合物; 和（c）煅烧由此获得的组合物以提供煅烧催化剂; 和ii）在步骤i）中制备的催化剂的存在下，将含有生物质衍生的热解油的进料与氢气在50℃至350℃的温度下接触。

10. 发明申请

WO2015067585A1 PROCESS FOR PREPARING A HYDROTREATING CATALYST 审中-公开
标题翻译：制备氢化催化剂的方法
公开(公告)号：WO2015067585A1
公开(公告)日：2015-05-14
申请号：PCT/EP2014/073639
申请日：2014-11-04
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： WINTER, Ferry , VAN WELSENES, Jan Arend , RIGUTTO, Marcello Stefano , GILTAY, Patricia Johanna Anne Maria , VAN VLAANDEREN, Johannes Jacobus Maria , AZGHAY, Ali
IPC分类号： B01J37/20 , B01J37/00 , B01J37/02 , B01J27/19 , C10G45/08 , B01J23/883 , B01J37/28 , B01J35/10 , B01J35/00 , B01J31/04
CPC分类号： B01J27/19 , B01J21/04 , B01J23/883 , B01J31/0202 , B01J31/04 , B01J35/0006 , B01J35/0026 , B01J35/026 , B01J35/1019 , B01J35/1061 , B01J37/0018 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/0215 , B01J37/0236 , B01J37/024 , B01J37/08 , B01J37/086 , B01J37/088 , B01J37/20 , B01J37/28 , B01J2523/00 , C10G45/08 , B01J2523/31 , B01J2523/51 , B01J2523/68 , B01J2523/845 , B01J2523/847
摘要： Process for preparing a hydrotreating catalyst comprising of from 5 wt% to 50 wt% of molybdenum, of from 0.5 wt% to 20 wt% of nickel and of from 0 to 5 wt% of phosphorus, all based on total dry weight of catalyst, which process comprises (a) treating alumina carrier with molybdenum and nickel and of from 1 to 60 %wt of gluconic acid, based on weight of carrier, and optionally phosphorus, (b) optionally drying the treated carrier at a temperature of from 40 to 200 °C, and (c) calcining the treated and optionally dried carrier at a temperature of from 200 to 650 °C to obtain the calcined treated carrier.
摘要翻译：制备加氢处理催化剂的方法，其包含5重量％至50重量％的钼，0.5重量％至20重量％的镍和0至5重量％的磷，均基于催化剂的总干重，该方法包括（a）基于载体的重量和任选的磷，用钼和镍处理氧化铝载体和1至60重量％的葡萄糖酸，（b）任选地将处理过的载体在40〜 200℃，和（c）在200至650℃的温度下煅烧经处理和任选干燥的载体，以获得经煅烧处理的载体。

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