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    • 8. 发明申请
    • Sr-Ce-Yb-O CATALYSTS FOR OXIDATIVE COUPLING OF METHANE
    • 用于甲烷氧化偶联的Sr-Ce-Yb-O催化剂
    • WO2018085826A1
    • 2018-05-11
    • PCT/US2017/060371
    • 2017-11-07
    • SABIC GLOBAL TECHNOLOGIES, B.V.LIANG, WugengSARSANI, Vidya Sagar ReddyWEST, DavidPEREZ, HectorMAMEDOV, Aghaddin
    • LIANG, WugengSARSANI, Vidya Sagar ReddyWEST, DavidPEREZ, HectorMAMEDOV, Aghaddin
    • B01J23/02B01J23/10B01J37/00C07C2/84C07C11/04
    • An oxidative coupling of methane (OCM) catalyst composition characterized by the overall general formula Sr 1.0 Ce a Yb b O c , wherein a is from about 0.01 to about 2.0, wherein b is from about 0.01 to about 2.0, wherein the sum (a+b) is not 1.0, and wherein c balances the oxidation states. A method of making an oxidative coupling of methane (OCM) catalyst composition comprising (a) forming an oxide precursor mixture, wherein the oxide precursor mixture comprises one or more compounds comprising a Sr cation, one or more compounds comprising a Ce cation, and one or more compounds comprising a Yb cation, and wherein the oxide precursor mixture is characterized by a molar ratio of Sr:(Ce+Yb) that is not about 1:1, and (b) calcining at least a portion of the oxide precursor mixture to form the OCM catalyst composition, wherein the OCM catalyst composition comprises Sr Ce Yb O perovskite in an amount of less than about 75.0 wt.%.
    • 甲烷(OCM)催化剂组合物的氧化偶联特征在于总的通式Sr 1.0 Ce 0.6 Yb b 1 其中a为约0.01至约2.0,其中b为约0.01至约2.0,其中总和(a + b)不为1.0,并且其中c平衡氧化态 。 一种制备甲烷(OCM)催化剂组合物的氧化偶联方法,所述方法包括(a)形成氧化物前体混合物,其中所述氧化物前体混合物包含一种或多种包含Sr阳离子的化合物,一种或多种包含Ce阳离子的化合物和一种 或更多种包含Yb阳离子的化合物,并且其中所述氧化物前体混合物的特征在于Sr:(Ce + Yb)不为约1:1的摩尔比,和(b)煅烧至少一部分氧化物前体混合物 以形成OCM催化剂组合物,其中所述OCM催化剂组合物包含量小于约75.0重量%的Sr Ce Yb O钙钛矿。