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1. 发明授权

US08354494B2 Polymerizable liquid crystal composition 有权
标题翻译：可聚合的液晶组合物
公开(公告)号：US08354494B2
公开(公告)日：2013-01-15
申请号：US12003368
申请日：2007-12-21
申请人： Kazumi Hagihara , Ryushi Shundo
发明人： Kazumi Hagihara , Ryushi Shundo
IPC分类号： C08G63/06 , C08G63/44
CPC分类号： C09K19/32 , C08F290/06 , C08F290/061 , C08G59/24 , C08G65/18 , C09K19/2007 , C09K19/322 , C09K19/3411 , C09K2019/0448 , C09K2019/3416 , Y10T428/105 , Y10T428/31504 , Y10T428/31507
摘要： A cholesteric polymerizable liquid crystal composition excellent in UV curing property and alignment property is provided. The polymerizable liquid crystal composition contains at least one liquid crystal compound selected from compounds represented by Formula (1-1) and Formula (1-2), at least one liquid crystal compound selected from compounds represented by Formula (2), and 5 to 15% by weight of at least one optically active compound selected from compounds represented by Formula (4) and may contain at least one liquid crystal compound selected from compounds represented by Formula (3). The meanings of the symbols in the Formulae are described in the specification.
摘要翻译：提供了UV固化性和取向性优异的胆甾型可聚合液晶组合物。可聚合液晶组合物含有至少一种选自式（1-1）和式（1-2）表示的化合物的液晶化合物，至少一种选自式（2）表示的化合物的液晶化合物和5至 15重量％的至少一种选自式（4）表示的化合物的光学活性化合物，并且可以含有至少一种选自式（3）表示的化合物的液晶化合物。公式中的符号的含义在说明书中描述。

2. 发明申请

US20100264367A1 Polymerizable liquid crystal compound, liquid crystal composition, and polymer 有权
标题翻译：可聚合液晶化合物，液晶组合物和聚合物
公开(公告)号：US20100264367A1
公开(公告)日：2010-10-21
申请号：US12662869
申请日：2010-05-07
申请人： Junichi Inagaki , Tomohiro Yano , Daisuke Ootsuki , Maiko Ito , Ryushi Shundo
发明人： Junichi Inagaki , Tomohiro Yano , Daisuke Ootsuki , Maiko Ito , Ryushi Shundo
IPC分类号： C09K19/32 , C07C69/76 , C09K19/34 , C08F120/00
CPC分类号： C09K19/32 , C09K2019/0448 , Y10T428/10
摘要： The compound of the present invention is represented by the formula (1). In the formula (1), R1 and R2 are hydrogen, fluorine, chlorine, methyl or ethyl; X1 and X2 are hydrogen, fluorine, methyl or trifluoromethyl; Z1 and Z2 are a single bond, —COO—, —OCO—, —CH═CH—COO—, —OCO—CH═CH—, —CH2CH2—COO—, —OCO—CH2CH2—, —CH2O—, —CONH—, —(CH2)4—, —CH2CH2— or —C≡C—; Z3 and Z4 are a single bond or —O—; A1 and A2 are 1,4-cyclohexylene, 1,4-phenylene, 1,3-phenylene, pyridin-2,5-diyl, pyrimidin-2,5-diyl, naphthalen-2,6-diyl or tetrahydronaphtlane-2,6-diyl; and Y1 and Y2 are alkylene having from 2 to 20 carbon atoms.
摘要翻译：本发明的化合物由式（1）表示。在式（1）中，R 1和R 2是氢，氟，氯，甲基或乙基; X 1和X 2是氢，氟，甲基或三氟甲基; Z1和Z2是单键，-COO-，-OCO-，-CH = CH-COO-，-OCO-CH = CH-，-CH2CH2-COO-，-OCO-CH2CH2-，-CH2O-，-CONH - ， - （CH 2）4 - ， - CH 2 CH 2 - 或-C≡C-; Z3和Z4是单键或-O-; A1和A2是1,4-亚环己基，1,4-亚苯基，1,3-亚苯基，吡啶-2,5-二基，嘧啶-2,5-二基，萘-2,6-二基或四氢萘并噻喃-2， 6-二基 Y1和Y2是具有2至20个碳原子的亚烷基。

3. 发明授权

US07560146B2 Polymerizable liquid crystal composition 有权
标题翻译：可聚合液晶组合物
公开(公告)号：US07560146B2
公开(公告)日：2009-07-14
申请号：US11882110
申请日：2007-07-30
申请人： Kazumi Hagihara , Seiki Mitani , Ryushi Shundo
发明人： Kazumi Hagihara , Seiki Mitani , Ryushi Shundo
IPC分类号： C09K19/20 , C09K19/34 , C09K19/32 , C09K19/12 , C09K19/38 , G02B5/30
CPC分类号： C09K19/582 , C09K19/3411 , C09K19/38 , C09K19/52 , C09K2019/0448 , C09K2019/323 , C09K2019/3416 , Y10T428/10
摘要： A polymerizable liquid crystal composition excellent in storage stability and UV curing property and a polymer thereof are provided. The polymerizable liquid crystal composition contains a compound represented by formula (1) as a component (A), an optically active compound represented by formula (2) as a component (B), and a mixture of a photopolymerization initiator and a photosensitizer as a component (C), and a ratio of the component (A) is from 77 to 98% by weight, a ratio of the component (B) is from 1 to 15% by weight, and a ratio of the component (C) is from 1 to 8% by weight, based on a total weight of the composition: wherein Z independently represents a single bond or alkylene having from 1 to 10 carbon atoms; Y1 independently represents a single bond or —O—; R1 represents methyl or ethyl; A1 and A2 each independently represents 1,4-phenylene or 4,4′-biphenylene; Y2 represents —COO— or —OCO—; Q represents a single bond or oxyalkylene having from 1 to 10 carbon atoms; and p represents 0 or 1.
摘要翻译：提供了保存稳定性和UV固化性优异的聚合性液晶组合物及其聚合物。可聚合液晶组合物含有作为组分（A）的由式（1）表示的化合物，作为组分（B）的由式（2）表示的光学活性化合物，以及光聚合引发剂和光敏剂作为成分（C），成分（A）的比例为77〜98重量％，成分（B）的比例为1〜15重量％，成分（C）的比例为 1至8重量％，基于组合物的总重量：其中Z独立地表示单键或具有1至10个碳原子的亚烷基; Y1独立地表示单键或-O-; R1代表甲基或乙基; A1和A2各自独立地表示1,4-亚苯基或4,4'-亚联苯; Y2表示-COO-或-OCO-; Q表示具有1至10个碳原子的单键或氧化烯; p表示0或1。

4. 发明授权

US07378135B2 Polymerizable liquid crystal composition and optically anisotropic thin film 有权
标题翻译：可聚合液晶组合物和光学各向异性薄膜
公开(公告)号：US07378135B2
公开(公告)日：2008-05-27
申请号：US11391194
申请日：2006-03-29
申请人： Kazuhiko Saigusa , Maiko Ito , Ryushi Shundo
发明人： Kazuhiko Saigusa , Maiko Ito , Ryushi Shundo
IPC分类号： C09K19/32 , C09K19/20 , C09K19/38
CPC分类号： C09K19/32 , C09K19/3861 , C09K2019/0448 , C09K2219/03 , G02B5/3016 , Y10T428/10 , Y10T428/1036 , Y10T428/1041
摘要： In order to obtain such a liquid crystal thin film having optical anisotropy that suffers less change in optical characteristics thereof under heating to 200° C., the following polymerizable liquid crystal composition is provided as a raw material therefor. The composition contains Compound (1) and at least one of Compound (2) and Compound (3), with a proportion of Compound (1) being from 50 to 99% by weight, a proportion of Compound (2) being from 0 to 50% by weight, and a proportion of Compound (3) being from 0 to 50% by weight: wherein R is alkyl; each of W1 and W2 is independently hydrogen, chlorine, fluorine or —CH3; each of W3 and W4 is independently hydrogen, chlorine, fluorine, —CH3 or —CF3; W5 is alkyl having, alkoxy, chlorine, fluorine, —CN or —OCF3; X is a single bond, —CH═CH— or —CH2CH2—; Z is a single bond, —COO—, —OCO— or —CH2CH2—; and q is an integer of from 1 to 20.
摘要翻译：为了得到这样的具有光学各向异性的液晶薄膜，在加热至200℃时光学特性变化较小，提供以下可聚合液晶组合物作为原料。组合物含有化合物（1）和化合物（2）和化合物（3）中的至少一种，化合物（1）的比例为50-99重量％，化合物（2）的比例为0〜 50重量％，化合物（3）的比例为0〜50重量％：其中R为烷基; W 1和W 2各自独立地是氢，氯，氟或-CH 3; W 3和W 4中的每一个独立地是氢，氯，氟，-CH 3或-CF 3 ; W 5是具有烷氧基，氯，氟，-CN或-OCF 3 N的烷基; X是单键，-CH-CH-或-CH 2 CH 2 - 。 Z是单键，-COO - ， - OCO-或-CH 2 CH 2 - 。 q为1〜20的整数。

5. 发明申请

US20060054859A1 Liquid-crystalline (METH) acrylate derivatives and composition containing them 有权
标题翻译：液晶（METH）丙烯酸酯衍生物和含有它们的组合物
公开(公告)号：US20060054859A1
公开(公告)日：2006-03-16
申请号：US11017809
申请日：2004-12-22
申请人： Ryushi Shundo , Tomohiro Eto
发明人： Ryushi Shundo , Tomohiro Eto
IPC分类号： C09K19/52 , C09K19/34 , C09K19/32 , C09K19/30 , C09K19/20 , C09K19/12 , C09K19/38
CPC分类号： C09K19/3861 , C09K19/14 , C09K19/32 , C09K19/322 , C09K19/3852 , C09K19/3857 , C09K2019/0448 , C09K2019/3408 , Y10T428/10
摘要： The compound of the invention is represented by Formula (1a) or Formula (1b) wherein R1 is a monovalent group; P1 and P2 are a monovalent group having an acrylic group and a hydroxyl group; A1, A2, and B1 are a divalent cyclic group; X1, X2, X3, X4, Y1 and Y2 are a bonding group.
摘要翻译：本发明的化合物由式（1a）或式（1b）表示，

6. 发明申请

US20100304148A1 Polymerizable liquid crystal compound, polymerizable liquid crystal composition, and polymer thereof 有权
标题翻译：聚合性液晶性化合物，聚合性液晶组合物及其聚合物
公开(公告)号：US20100304148A1
公开(公告)日：2010-12-02
申请号：US12659693
申请日：2010-03-17
申请人： Yoshiharu Hirai , Ryushi Shundo , Takashi Kato
发明人： Yoshiharu Hirai , Ryushi Shundo , Takashi Kato
IPC分类号： B32B17/10 , C09K19/32 , C09K19/34 , C07C69/92 , C07C69/54 , C08F120/26 , B32B27/00 , B32B27/36 , B32B17/08 , B32B27/38 , B32B27/06 , B32B27/34 , B32B27/30 , B32B27/32 , B32B23/04 , B32B9/04
CPC分类号： C09K19/32 , C09K2019/0448 , G02F1/133536 , G02F1/13363 , G02F1/133711 , G02F2001/133726 , G02F2201/343 , G02F2413/11 , G02F2413/15 , Y10T428/31504 , Y10T428/31507 , Y10T428/31515 , Y10T428/31518 , Y10T428/31533 , Y10T428/31616 , Y10T428/31623 , Y10T428/31634 , Y10T428/31645 , Y10T428/31649 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938 , Y10T428/31971
摘要： A compound represented by the formula (1) is provided. A polymerizable liquid crystal composition containing the compound can be controlled in birefringence and is excellent in stability of a liquid crystal phase. An anisotropic polymer excellent in uniformity of alignment is obtained by coating and polymerizing the composition on a supporting substrate. In the formula (1), at least one of Ra represents a polymerizable group, A represents a ring group, Y and Z each represent a single bond or alkylene; in which —CH2— in the alkylene may be replaced by another group, and m and n each represent an integer of from 0 to 5.
摘要翻译：提供由式（1）表示的化合物。含有该化合物的聚合性液晶组合物可以控制双折射，并且液晶相的稳定性优异。通过在支撑基材上涂布和聚合组合物，获得了取向均匀性优异的各向异性聚合物。在式（1）中，Ra中的至少一个表示可聚合基团，A表示环基，Y和Z各自表示单键或亚烷基; 其中亚烷基中的-CH 2可以被另一个基团取代，m和n各自表示0-5的整数。

7. 发明申请

US20080029734A1 Polymerizable liquid crystal composition 有权
标题翻译：可聚合液晶组合物
公开(公告)号：US20080029734A1
公开(公告)日：2008-02-07
申请号：US11882110
申请日：2007-07-30
申请人： Kazumi Hagihara , Seiki Mitani , Ryushi Shundo
发明人： Kazumi Hagihara , Seiki Mitani , Ryushi Shundo
IPC分类号： C09K19/52
CPC分类号： C09K19/582 , C09K19/3411 , C09K19/38 , C09K19/52 , C09K2019/0448 , C09K2019/323 , C09K2019/3416 , Y10T428/10
摘要： A polymerizable liquid crystal composition excellent in storage stability and UV curing property and a polymer thereof are provided. The polymerizable liquid crystal composition contains a compound represented by formula (1) as a component (A), an optically active compound represented by formula (2) as a component (B), and a mixture of a photopolymerization initiator and a photosensitizer as a component (C), and a ratio of the component (A) is from 77 to 98% by weight, a ratio of the component (B) is from 1 to 15% by weight, and a ratio of the component (C) is from 1 to 8% by weight, based on a total weight of the composition: wherein Z independently represents a single bond or alkylene having from 1 to 10 carbon atoms; Y1 independently represents a single bond or —O—; R1 represents methyl or ethyl; A1 and A2 each independently represents 1,4-phenylene or 4,4′-biphenylene; Y2 represents —COO— or —OCO—; Q represents a single bond or oxyalkylene having from 1 to 10 carbon atoms; and p represents 0 or 1.
摘要翻译：提供了保存稳定性和UV固化性优异的聚合性液晶组合物及其聚合物。可聚合液晶组合物含有作为组分（A）的由式（1）表示的化合物，作为组分（B）的由式（2）表示的光学活性化合物，以及光聚合引发剂和光敏剂作为成分（C），成分（A）的比例为77〜98重量％，成分（B）的比例为1〜15重量％，成分（C）的比例为 1至8重量％，基于组合物的总重量：其中Z独立地表示单键或具有1至10个碳原子的亚烷基; Y 1独立地表示单键或-O-; R 1表示甲基或乙基; A 1和A 2各自独立地表示1,4-亚苯基或4,4'-亚联苯; Y 2表示-COO-或-OCO-; Q表示具有1至10个碳原子的单键或氧化烯; p表示0或1。

8. 发明申请

US20050031801A1 Photo-curable fluorene derivative and composition containing the same 有权
标题翻译：光固化芴衍生物及其组合物
公开(公告)号：US20050031801A1
公开(公告)日：2005-02-10
申请号：US10901122
申请日：2004-07-29
申请人： Ryushi Shundo , Hiromichi Inoue , Tomohiro Etou
发明人： Ryushi Shundo , Hiromichi Inoue , Tomohiro Etou
IPC分类号： C09K19/32 , C09K19/34 , C09K19/38
CPC分类号： C09K19/32 , C09K19/3411 , C09K19/38 , C09K2019/3416 , Y10T428/10 , Y10T428/31511
摘要： The present invention provides a compound represented by formula (1) defined in the specification. The invention further provides a liquid crystal composition comprising at least two compounds, which at least one compound out of them is the above compound. The invention still further provides a polymer obtained by polymerizing the above composition, and uses of the polymer such as a molded article having an optical anisotropy, an optical compensation element, a wavelength functional plate, an optical element, and a liquid crystal display element comprising the polymer.
摘要翻译：本发明提供了由说明书中定义的式（1）表示的化合物。本发明还提供一种包含至少两种化合物的液晶组合物，其中至少一种化合物是上述化合物。本发明还提供了通过聚合上述组合物获得的聚合物，以及具有光学各向异性的成型制品的聚合物，光学补偿元件，波长功能板，光学元件和液晶显示元件的用途，所述聚合物包括聚合物。

9. 发明授权

US6045720A Pyridine compound and liquid crystalline composition 有权
标题翻译：吡啶化合物和液晶组合物
公开(公告)号：US6045720A
公开(公告)日：2000-04-04
申请号：US205613
申请日：1998-12-04
申请人： Ryushi Shundo , Shinichi Saito , Eiji Okabe , Hideo Saito
发明人： Ryushi Shundo , Shinichi Saito , Eiji Okabe , Hideo Saito
IPC分类号： G02F1/13 , C07D213/26 , C07D213/30 , C07D213/55 , C09K19/34 , C07D213/06
CPC分类号： C09K19/3444 , C07D213/55 , Y02P20/55
摘要： A compound expressed by the following formula (1) and a liquid crystalline composition with using it are provided: ##STR1## wherein, either one of rings A, B and C denotes ##STR2## remaining two of them denote each independently ##STR3## R denotes an alkyl group or an alkoxy group with 4-16 carbon atoms, R* denotes ##STR4## in which, R.sub.1 denotes CH.sub.3, CF.sub.3, CH.sub.2 F or CHF.sub.2, R.sub.2 denotes an alkyl group with 1-10 carbon atoms and m denotes 2-12.The said compound exhibits a ferroelectric liquid crystalline phase and an antiferroelectric liquid crystalline phase by itself.
摘要翻译：提供由下式（1）表示的化合物和使用该化合物的液晶组合物：其中，环A，B和C中的任一个表示其中两个独立地表示，R表示烷基或烷氧基， 4-16个碳原子，R *表示其中，R1表示CH 3，CF 3，CH 2 F或CHF 2，R 2表示具有1-10个碳原子的烷基，m表示2-12。所述化合物本身显示出铁电液晶相和反铁电液晶相。

10. 发明授权

US07985455B2 Polymerizable liquid crystal compound, liquid crystal composition, and polymer 有权
标题翻译：可聚合液晶化合物，液晶组合物和聚合物
公开(公告)号：US07985455B2
公开(公告)日：2011-07-26
申请号：US12662869
申请日：2010-05-07
申请人： Junichi Inagaki , Tomohiro Yano , Daisuke Ootsuki , Maiko Ito , Ryushi Shundo
发明人： Junichi Inagaki , Tomohiro Yano , Daisuke Ootsuki , Maiko Ito , Ryushi Shundo
IPC分类号： C09K19/32 , C09K19/38 , C09K19/20 , C07C69/76 , C07C69/78 , C07C69/96 , C08F20/10 , G02B5/30
CPC分类号： C09K19/32 , C09K2019/0448 , Y10T428/10
摘要： The compound of the present invention is represented by the formula (1). In the formula (1), R1 and R2 are hydrogen, fluorine, chlorine, methyl or ethyl; X1 and X2 are hydrogen, fluorine, methyl or trifluoromethyl; Z1 and Z2 are a single bond, —COO—, —OCO—, —CH═CH—COO—, —OCO—CH═CH—, —CH2CH2—COO—, —OCO—CH2CH2—, —CH2O—, —CONH—, —(CH2)4—, —CH2CH2— or —C≡C—; Z3 and Z4 are a single bond or —O—; A1 and A2 are 1,4-cyclohexylene, 1,4-phenylene, 1,3-phenylene, pyridin-2,5-diyl, pyrimidin-2,5-diyl, naphthalen-2,6-diyl or tetrahydronaphtlane-2,6-diyl; and Y1 and Y2 are alkylene having from 2 to 20 carbon atoms.
摘要翻译：本发明的化合物由式（1）表示。在式（1）中，R 1和R 2是氢，氟，氯，甲基或乙基; X 1和X 2是氢，氟，甲基或三氟甲基; Z1和Z2是单键，-COO-，-OCO-，-CH = CH-COO-，-OCO-CH = CH-，-CH2CH2-COO-，-OCO-CH2CH2-，-CH2O-，-CONH - ， - （CH 2）4 - ， - CH 2 CH 2 - 或-C≡C-; Z3和Z4是单键或-O-; A1和A2是1,4-亚环己基，1,4-亚苯基，1,3-亚苯基，吡啶-2,5-二基，嘧啶-2,5-二基，萘-2,6-二基或四氢萘并噻喃-2， 6-二基 Y1和Y2是具有2至20个碳原子的亚烷基。

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