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1. 发明授权

US07112621B2 Coating compositions for modifying surfaces 有权
公开(公告)号：US07112621B2
公开(公告)日：2006-09-26
申请号：US10060708
申请日：2002-01-30
申请人： Robert Henry Rohrbaugh , Glenn Thomas Jordan, IV , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink , Heather Anne Liddle
发明人： Robert Henry Rohrbaugh , Glenn Thomas Jordan, IV , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink , Heather Anne Liddle
IPC分类号： C08K9/04 , C08K3/10 , C08K3/20 , B05D3/00
CPC分类号： C09D5/00 , B41M3/006 , B41M5/0047 , B41M5/0058 , B41M5/0064 , B41M5/007 , B41M5/0076 , C09D1/00 , C11D3/001 , C11D3/1213 , C11D3/1253 , C11D3/128 , C11D11/0017 , C11D11/007 , C11D17/0043 , D06M10/00 , D06M10/06 , D06M11/44 , D06M11/45 , D06M11/46 , D06M11/77 , D06M11/78 , D06M11/79 , D06M23/08 , D06P5/02 , D06P5/20 , Y10T428/24802 , Y10T428/24851 , Y10T428/24876 , Y10T428/24884 , Y10T428/24893 , Y10T428/24901 , Y10T428/25 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/263 , Y10T428/2982 , Y10T442/20 , Y10T442/273
摘要： Coating compositions, methods and articles of manufacture comprising a nanoparticle system employing same to impart surface modifying benefits for all types of soft surfaces, and in some cases, hard surfaces, are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of coating compositions, methods and articles of manufacture that create multi-use benefits to the modified surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that, in some embodiments, may include at least one of the following improved surface properties: cleaning, wettability, liquid strike-through, comfort, stain resistance, soil removal, malodor control, modification of surface friction, reduced damage to abrasion and color enhancement, relative to the surfaces unmodified with such nanoparticle systems.

2. 发明授权

US07066998B2 Coatings for modifying hard surfaces and processes for applying the same 失效
公开(公告)号：US07066998B2
公开(公告)日：2006-06-27
申请号：US10020064
申请日：2001-12-13
申请人： Robert Henry Rohrbaugh , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink , Chanchal Kumar Ghosh , Helen Frances O'Connor , Heather Anne Liddle , Marc Francois Evers , Morgan Thomas Leahy , Alan Scott Goldstein , Brian Joseph Loughnane
发明人： Robert Henry Rohrbaugh , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink , Chanchal Kumar Ghosh , Helen Frances O'Connor , Heather Anne Liddle , Marc Francois Evers , Morgan Thomas Leahy , Alan Scott Goldstein , Brian Joseph Loughnane
IPC分类号： C09K3/00 , C09D1/00 , C09C1/42 , C09C3/00
CPC分类号： C11D17/0013 , B01J39/05 , B05D1/04 , B05D3/02 , B05D7/14 , B05D7/532 , B05D2601/20 , B08B3/026 , C02F1/42 , C02F2001/422 , C02F2001/425 , C08K3/22 , C08K3/346 , C09D1/00 , C09D7/61 , C09D7/67 , C09D7/68 , C11D3/1213 , C11D3/1253 , C11D3/1266 , C11D3/14 , C11D3/3776 , C11D11/0023 , C11D11/0058 , C11D11/0064 , Y10T428/25 , B01J41/07
摘要： Materials for coating, coating compositions, methods and articles of manufacture comprising a nanoparticle system or employing the same to impart surface modifying benefits for all types of hard surfaces are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of coating compositions, methods and articles of manufacture that create multi-use benefits to modified hard surfaces. In some embodiments, actively curing the coating composition on the hard surfaces, including, but not limited to by radiative heating the air surrounding the hard surface with the coating thereon can be used to increase the durability of the hard surface coating.

3. 发明授权

US07087662B2 Rinse aid surface coating compositions for modifying dishware surfaces 有权
公开(公告)号：US07087662B2
公开(公告)日：2006-08-08
申请号：US10641184
申请日：2003-08-14
申请人： Chanchal Kumar Ghosh , William Michael Scheper , Robert Henry Rohrbaugh , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink
发明人： Chanchal Kumar Ghosh , William Michael Scheper , Robert Henry Rohrbaugh , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink
IPC分类号： C08K3/34
CPC分类号： C11D17/0013 , B01J39/05 , B08B3/026 , C02F1/42 , C02F2001/422 , C02F2001/425 , C08K3/346 , C09D1/00 , C09D7/61 , C09D7/67 , C09D7/70 , C11D3/1213 , C11D3/1253 , C11D3/1266 , C11D3/14 , C11D11/0023 , C11D11/0058 , B01J41/07
摘要： Rinse aid materials for coating, coating compositions, methods and articles of manufacture for use in automatic dishwashing appliances comprising a nanoparticle system or employing the same to impart surface modifying benefits for all types of dishware surfaces are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of rinse aid surface coating compositions, methods and articles of manufacture that create multi-use benefits to modified dishware surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that include at least one of the following improved surface properties: wetting and sheeting, uniform drying, anti-spotting, anti-staining, anti-filming, self cleaning, and durability benefits, relative to dishware surfaces unmodified with such nanoparticle systems. In some embodiments, actively curing the rinse aid surface coating composition on the dishware surfaces, including, but not limited to by radiative heating the air surrounding the dishware surface with the coating thereon can be used to increase the durability of the dishware surface coating.

4. 发明授权

US06693071B2 Rinse aid surface coating compositions for modifying dishware surfaces 有权
标题翻译：用于改变餐具表面的漂洗助剂表面涂料组合物
公开(公告)号：US06693071B2
公开(公告)日：2004-02-17
申请号：US10022976
申请日：2001-12-13
申请人： Chanchal Kumar Ghosh , William Michael Scheper , Robert Henry Rohrbaugh , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink
发明人： Chanchal Kumar Ghosh , William Michael Scheper , Robert Henry Rohrbaugh , Michael Ray McDonald , John David Carter , Eugene Paul Gosselink
IPC分类号： C08G104
CPC分类号： C11D17/0013 , B01J39/05 , B08B3/026 , C02F1/42 , C02F2001/422 , C02F2001/425 , C08K3/346 , C09D1/00 , C09D7/61 , C09D7/67 , C09D7/70 , C11D3/1213 , C11D3/1253 , C11D3/1266 , C11D3/14 , C11D11/0023 , C11D11/0058 , B01J41/07
摘要： Rinse aid materials for coating, coating compositions, methods and articles of manufacture for use in automatic dishwashing appliances comprising a nanoparticle system or employing the same to impart surface modifying benefits for all types of dishware surfaces are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of rinse aid surface coating compositions, methods and articles of manufacture that create multi-use benefits to modified dishware surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that include at least one of the following improved surface properties: wetting and sheeting, uniform drying, anti-spotting, anti-staining, anti-filming, self cleaning, and durability benefits, relative to dishware surfaces unmodified with such nanoparticle systems. In some embodiments, actively curing the rinse aid surface coating composition on the dishware surfaces, including, but not limited to by radiative heating the air surrounding the dishware surface with the coating thereon can be used to increase the durability of the dishware surface coating.
摘要翻译：公开了用于涂覆的辅助材料，涂料组合物，方法和制品，用于包括纳米颗粒体系的自动洗碗设备中，或者使用该辅助材料来赋予所有类型的餐具表面的表面改性效果。在一些实施方案中，纳米颗粒在合适的载体介质中的分散允许产生漂洗助剂表面涂料组合物，方法和制品，从而为修改的餐具表面产生多用途益处。这些表面改性可以产生长期或半永久的多用途益处，其包括以下改进的表面性质中的至少一种：润湿和片材，均匀干燥，抗斑点，抗污染，抗成膜，自清洁和相对于未用这种纳米颗粒系统改性的餐具表面，耐久性有益。在一些实施方案中，主动地固化餐具表面上的漂洗助剂表面涂料组合物，包括但不限于通过辐射加热餐具表面周围的空气与其上的涂层，以增加餐具表面涂层的耐久性。

5. 发明授权

US06933269B2 Polyaspartate derivatives for use in detergent compositions 失效
标题翻译：用于洗涤剂组合物的聚天冬氨酸衍生物
公开(公告)号：US06933269B2
公开(公告)日：2005-08-23
申请号：US10210376
申请日：2002-07-31
申请人： Glenn Thomas Jordan, IV , Eugene Paul Gosselink
发明人： Glenn Thomas Jordan, IV , Eugene Paul Gosselink
IPC分类号： D06L1/12 , C08G69/10 , C08G73/10 , C11D3/37 , C11D3/20 , C11D3/26
CPC分类号： C08G73/1092 , C11D3/3719
摘要： Polyaspartate derivatives, especially hydrophobically modified and/or hydrophilically modified polyaspartate derivatives, most especially polyaspartate derivatives that are both hydrophilically and hydrophobically modified, for use in detergent compositions, specifically laundry detergent compositions for providing cleaning, dispersancy, especially soil dispersion, builder properties and/or improved whitening of fabrics contacted by such detergent compositions; and methods for making such polyaspartate derivatives, and methods and articles employing such detergent compositions, are provided.
摘要翻译：聚天冬氨酸衍生物，特别是疏水改性和/或亲水改性的聚天冬氨酸盐衍生物，最特别是亲水和疏水改性的聚天冬氨酸盐衍生物，用于洗涤剂组合物，特别是用于提供清洁，分散，特别是土壤分散体，助洗剂性质和/ 或改善由这种洗涤剂组合物接触的织物的美白; 以及制备这种聚天冬氨酸衍生物的方法，以及使用这种洗涤剂组合物的方法和制品。

6. 发明授权

US5728671A Soil release polymers with fluorescent whitening properties 失效
公开(公告)号：US5728671A
公开(公告)日：1998-03-17
申请号：US576243
申请日：1995-12-21
申请人： Robert Henry Rohrbaugh , Eugene Paul Gosselink
发明人： Robert Henry Rohrbaugh , Eugene Paul Gosselink
IPC分类号： C07D307/80 , C07C309/10 , C07C309/42 , C07C309/58 , C08G18/65 , C08G18/71 , C08G63/18 , C08G63/668 , C08G63/672 , C08G63/685 , C08G63/688 , C08G63/91 , C08G69/44 , C08K13/02 , C08L67/02 , C08L75/04 , C11D3/00 , C11D3/37 , C11D3/42
CPC分类号： C11D3/3715 , C08G63/668 , C08G63/6854 , C08G63/6884 , C11D3/0036 , C11D3/3719 , C11D3/42
摘要： Oligomeric or polymeric substituted or unsubstituted ethylene terephthalate esters comprising fluorescent whitening groups useful as soil release agents in laundry detergent compositions are described. The soil release agents of the present invention are especially suitable for use with polyester and polyester-blended fabric.

7. 发明授权

US06812198B2 Laundry detergent compositions comprising hydrophobically modified polyamines 失效
标题翻译：包含疏水改性多胺的洗衣洗涤剂组合物
公开(公告)号：US06812198B2
公开(公告)日：2004-11-02
申请号：US10233196
申请日：2002-08-30
申请人： Jeffrey Scott Dupont , Eugene Paul Gosselink , Kenneth Nathan Price , Robert Henry Rohrbaugh
发明人： Jeffrey Scott Dupont , Eugene Paul Gosselink , Kenneth Nathan Price , Robert Henry Rohrbaugh
IPC分类号： C11D183
CPC分类号： C07C217/50 , C08G65/2621 , C11D1/62 , C11D3/3723
摘要： The present invention relates to hydrophobically modified polyamines and laundry detergent compositions which comprise said polyamines, said compositions comprising: A) from about 0.01%, preferably from about 0.1%, more preferably from about 1%, most preferably from about 3% to about 50%, preferably to about 20%, more preferably to about 10%, most preferably to about 7% by weight, of a hydrophobically modified polyamine having the formula: wherein R is C6-C20 linear or branched alkylene, and mixtures thereof; R1 is an alkyleneoxy unit having the formula: —(R2O)x—R3 wherein R2 is C2-C4 linear or branched alkylene, and mixtures thereof; R3 is hydrogen, C1-C22 alkyl, C7-C22 alkylenearyl, and mixtures thereof; x is from about 15 to about 30; at least one Q moiety is a hydrophobic quaternizing unit selected from the group consisting of C8-C30 substituted or unsubstituted linear or branched alkyl, C6-C30 substituted or unsubstituted cycloalkyl, C7-C30 substituted or unsubstituted alkylenearyl, and mixtures thereof, and the remaining Q moieties are selected from the group consisting of lone pairs of electrons on the unreacted nitrogens, hydrogen, C1-C30 substituted or unsubstituted linear or branched alkyl, C3-C30 substituted or unsubstituted cycloalkyl, C7-C30 substituted or unsubstituted alkylenearyl, and mixtures thereof; X is an anion present in sufficient amount to provide electronic neutrality; n is from 0 to 3; B) from about 0.01% by weight, of a surfactant system comprising one or more surfactants selected from: i) from 0% to 100% by weight, of one or more anionic surfactants; ii) from 0% to 100% by weight, of one or more nonionic surfactants; iii) optionally from 0.1% to about 80% by weight, of one or more cationic surfactants; iv) optionally from 0.1% to about 80% by weight, of one or more zwitterionic surfactants; v) optionally from 0.1% to about 80% by weight, of one or more ampholytic surfactants; or vi) mixtures thereof; C) the balance carriers and adjunct ingredients.

8. 发明授权

US6075000A Bleach compatible alkoxylated polyalkyleneimines 失效
标题翻译：漂白相容的烷氧基化聚亚烷基亚胺
公开(公告)号：US6075000A
公开(公告)日：2000-06-13
申请号：US103135
申请日：1998-06-23
申请人： Robert Henry Rohrbaugh , James Albert Cleary , Shulin Zhang , Eugene Paul Gosselink
发明人： Robert Henry Rohrbaugh , James Albert Cleary , Shulin Zhang , Eugene Paul Gosselink
IPC分类号： C11D3/37 , C11D3/39 , C11D3/00 , C11D3/30 , C11D3/395 , D06L3/00
CPC分类号： C11D3/3942 , C11D3/3723 , C11D3/3917 , C11D3/3945
摘要： The present invention relates to laundry detergent compositions which comprise bleach compatible hydrophobic soil dispersants. The dispersants are polyalkyleneimines having a backbone molecular weight of from about 2000 to about 5000 daltons and having most of the N--H unit hydrogens, preferably all N--H unit hydrogens substituted with from about 20 to about 50, alkyleneoxy units.
摘要翻译：本发明涉及包含漂白剂的疏水性土壤分散剂的衣物洗涤剂组合物。分散剂是主链分子量为约2000-约5000道尔顿的聚亚烷基亚胺，并且具有大部分N-H单元氢，优选全部由约20至约50个亚烷氧基单元取代的N-H单元氢。

9. 发明授权

US5834412A Soil release polymers with fluorescent whitening properties 失效
标题翻译：具有荧光增白性能的土壤释放聚合物
公开(公告)号：US5834412A
公开(公告)日：1998-11-10
申请号：US868785
申请日：1997-06-04
申请人： Robert Henry Rohrbaugh , Eugene Paul Gosselink
发明人： Robert Henry Rohrbaugh , Eugene Paul Gosselink
IPC分类号： C07D307/80 , C07C309/10 , C07C309/42 , C07C309/58 , C08G18/65 , C08G18/71 , C08G63/18 , C08G63/668 , C08G63/672 , C08G63/685 , C08G63/688 , C08G63/91 , C08G69/44 , C08K13/02 , C08L67/02 , C08L75/04 , C11D3/00 , C11D3/37 , C11D3/42
CPC分类号： C11D3/3715 , C08G63/668 , C08G63/6854 , C08G63/6884 , C11D3/0036 , C11D3/3719 , C11D3/42
摘要： Oligomeric or polymeric substituted or unsubstituted ethylene terephthalate esters comprising fluorescent whitening groups useful as soil release agents in laundry detergent compositions are described. The soil release agents of the present invention are especially suitable for use with polyester and polyester-blended fabric.
摘要翻译：描述了包含用作洗衣洗涤剂组合物中的污垢释放剂的荧光增白基团的低聚或取代或未取代的对苯二甲酸乙二醇酯酯。本发明的脱模剂特别适用于聚酯和聚酯混纺织物。

10. 发明授权

US5691298A Ester oligomers suitable as soil release agents in detergent compositions 失效
标题翻译：适合作为洗涤剂组合物中的去污剂的酯低聚物
公开(公告)号：US5691298A
公开(公告)日：1997-11-25
申请号：US545351
申请日：1995-11-22
申请人： Eugene Paul Gosselink , James Albert Cleary , Robert Henry Rohrbaugh , Margaret Robinson Tallmadge , Shulin Zhang
发明人： Eugene Paul Gosselink , James Albert Cleary , Robert Henry Rohrbaugh , Margaret Robinson Tallmadge , Shulin Zhang
IPC分类号： C08G63/688 , C11D3/37 , C11D1/28
CPC分类号： C08G63/6884 , C11D3/3715
摘要： Soil release agents which comprise: an ester backbone comprising (1) units selected from dihydroxy or polyhydroxy sulfonate (e.g., a sulfoethyl ether of glycerin), a unit which is at least trifunctional whereby ester linkages are formed resulting in a branched oligomer backbone (e.g., glycerol), or mixtures thereof, (2) terephthaloyl unit, and (3) oxyalkyleneoxy unit; and one or more capping units (preferably anionic).
摘要翻译：土壤脱模剂，其包含：（1）选自二羟基或多羟基磺酸酯的单元（例如，甘油的磺基乙基醚）的酯主链，其是至少三官能的单元，由此形成酯键，得到支链低聚物主链（例如，甘油）或其混合物，（2）对苯二甲酰单元，和（3）氧亚烷基氧基单元; 和一个或多个封端单元（优选阴离子）。

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