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    • 3. 发明授权
    • Random copolymers made by anionic polymerization, toners incorporating
these copolymers and method for the manufacture thereof
    • 通过阴离子聚合制备的无规共聚物,掺入这些共聚物的调色剂及其制造方法
    • US5532327A
    • 1996-07-02
    • US394580
    • 1995-02-27
    • Robert D. BayleyThomas R. HoffendTimothy J. FullerSuresh K. Ahuja
    • Robert D. BayleyThomas R. HoffendTimothy J. FullerSuresh K. Ahuja
    • C08F236/10C08F4/48
    • C08F236/10
    • A solution polymerization process for producing an organic polymer from styrene and at least one other polymerizable monomer comprising providing a liquid reaction medium suitable for conducting said polymerization, wherein the reaction medium contains styrene and a polymerizable monomer other than styrene; and, anionically polymerizing styrene and monomer, thereby forming random copolymer chains, wherein the total quantity of said styrene used in said polymerization is at least 50% by weight based on the total weight of styrene and other polymerizable monomers used in the polymerization. A second embodiment comprises a copolymer made by the above-described method.A third embodiment comprises a process for forming a toner, wherein the process comprises providing a liquid reaction medium suitable for conducting a solution polymerization, the reaction medium containing at least two polymerizable monomers; anionically polymerizing the monomers, thereby forming random and nearly random copolymer chains; finely dividing the copolymer into particles; and, incorporating said particles into a composition for use as a toner. A fourth embodiment comprises a toner made by extrusion with pigment or colorant and change control additive to form small particles.A fifth embodiment comprises a solution polymerization process for producing an organic polymer wherein a difunctional initiator is used to initiate said polymerization.
    • 一种从苯乙烯和至少一种其它可聚合单体制备有机聚合物的溶液聚合方法,包括提供适于进行所述聚合的液体反应介质,其中反应介质含有苯乙烯和除苯乙烯之外的可聚合单体; 并且阴离子聚合苯乙烯和单体,从而形成无规共聚物链,其中所述聚合中使用的所述苯乙烯的总量基于聚合中使用的苯乙烯和其它可聚合单体的总重量为至少50重量%。 第二实施方案包括通过上述方法制备的共聚物。 第三实施方案包括形成调色剂的方法,其中所述方法包括提供适于进行溶液聚合的液体反应介质,所述反应介质含有至少两种可聚合单体; 使单体阴离子聚合,从而形成无规和几乎无规的共聚物链; 将共聚物细分成颗粒; 并将所述颗粒结合到用作调色剂的组合物中。 第四实施方案包括通过与颜料或着色剂一起挤出而制成的调色剂和改变控制添加剂以形成小颗粒。 第五实施方案包括用于制备有机聚合物的溶液聚合方法,其中使用双官能引发剂引发所述聚合。
    • 5. 发明授权
    • Unsaturated polyesters
    • 不饱和聚酯
    • US5407772A
    • 1995-04-18
    • US159176
    • 1993-11-30
    • Robert D. BayleyCarol A. FoxThomas R. HoffendHadi K. MahabadiEnno E. AgurGuerino SacripanteMichael S. Hawkins
    • Robert D. BayleyCarol A. FoxThomas R. HoffendHadi K. MahabadiEnno E. AgurGuerino SacripanteMichael S. Hawkins
    • C08G63/547G03G9/087G03G9/00
    • C08G63/547G03G9/08755G03G9/08791G03G9/08793G03G9/08797
    • Unsaturated linear polymers have repeating units of a reaction product of a first monomer, a second monomer, a third monomer and optionally a fourth monomer. The linear polymers have a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C. The first monomer should have a weight average molecular weight less than 200. The second monomer may be a dicarboxylic acid or diester which is different than the third monomer. A concentration of second residues of the polymer, derived from the second monomer, ranges from about 3 wt. % to about 15 wt. %, based on the total weight of the polymer. The third monomer is an aromatic dicarboxylic acid or an ester thereof. In the polymer, a concentration of third residues, derived from the third monomer, ranges from about 40 wt. % to about 55 wt. %, based on the total weight of the polymer. The fourth monomer is a diol having a higher molecular weight than the first monomer. In a process for preparing the inventive polymer, the first, second, third monomer (and optionally a fourth monomer) and/or a catalyst undergo transesterification to form the unsaturated, linear polymer.
    • 不饱和线性聚合物具有第一单体,第二单体,第三单体和任选的第四单体的反应产物的重复单元。 线性聚合物的玻璃化转变温度为约52℃至约61℃。第一单体应具有小于200的重均分子量。第二单体可以是二羧酸或二酯,其不同于 第三单体。 衍生自第二单体的聚合物的第二残余物的浓度范围为约3wt。 %至约15wt。 %,基于聚合物的总重量。 第三单体是芳族二羧酸或其酯。 在聚合物中,衍生自第三单体的第三残基的浓度范围为约40wt。 %至约55wt。 %,基于聚合物的总重量。 第四单体是分子量高于第一单体的二醇。 在制备本发明聚合物的方法中,第一,第二,第三单体(和任选的第四单体)和/或催化剂进行酯交换以形成不饱和的线性聚合物。