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1. 发明申请

US20100294168A1 Transparent Coatings 审中-公开
标题翻译：透明涂料
公开(公告)号：US20100294168A1
公开(公告)日：2010-11-25
申请号：US12225282
申请日：2007-03-22
申请人： Qi Sun , Daniel Ray Fruge , Demetrius Michos
发明人： Qi Sun , Daniel Ray Fruge , Demetrius Michos
IPC分类号： C09D1/00
CPC分类号： C09D1/00 , C03C17/007 , C03C2217/213 , C03C2217/42 , C03C2218/114 , C03C2218/32 , C08F8/50 , C08K3/22 , C09D7/61 , C23C16/32 , C23C16/505 , C08F16/06
摘要： An inorganic oxide coating produced by preparing a coating composition comprising inorganic oxide particles and a polymer, applying the composition on a substrate to form a coating, and heating the substrate to remove the polymeric component, wherein the resulting coating is transparent.
摘要翻译：通过制备包含无机氧化物颗粒和聚合物的涂料组合物制备的无机氧化物涂层，将所述组合物施加在基材上以形成涂层，并加热所述基材以除去聚合物组分，其中所得涂层是透明的。

2. 发明申请

US20130189425A1 Transparent Coatings 审中-公开
标题翻译：透明涂料
公开(公告)号：US20130189425A1
公开(公告)日：2013-07-25
申请号：US13554400
申请日：2012-07-20
申请人： Demetrius Michos , Daniel Ray Fruge , Qi Sun
发明人： Demetrius Michos , Daniel Ray Fruge , Qi Sun
IPC分类号： B05D3/02
CPC分类号： B05D3/0254 , C08K3/36 , C09D5/00 , C09D7/61 , C09D9/00
摘要： An inorganic oxide coating produced by preparing a coating composition comprising inorganic oxide particles and a polymer, applying the composition on a substrate to form a coating, and heating the substrate to remove the polymeric component, wherein the resulting coating is transparent.
摘要翻译：通过制备包含无机氧化物颗粒和聚合物的涂料组合物制备的无机氧化物涂层，将所述组合物施加在基材上以形成涂层，并加热所述基材以除去聚合物组分，其中所得涂层是透明的。

3. 发明授权

US06896942B2 Coating composition comprising colloidal silica and glossy ink jet recording sheets prepared therefrom 失效
标题翻译：包含胶体二氧化硅和由其制备的光泽喷墨记录纸的涂料组合物
公开(公告)号：US06896942B2
公开(公告)日：2005-05-24
申请号：US10391270
申请日：2003-03-18
申请人： Daniel Ray Fruge , Demetrius Michos
发明人： Daniel Ray Fruge , Demetrius Michos
IPC分类号： B41J2/01 , B41M1/00 , B41M5/00 , B41M5/50 , B41M5/52 , C09D7/12 , B41M5/40
CPC分类号： B41M5/5218 , C08K3/36 , C08K9/04 , C09D7/62 , C09D7/67 , C09D7/68
摘要： A coating composition comprising cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and polydispersed cationic colloidal silica. The cationic colloidal silica preferably has an average particle size in the range of about 1 to about 300 nanometers. It has been discovered that if a cationic polydispersed colloidal silica is employed in a glossy coating formulation, the coating provides a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater, but also a coating having good to excellent printability characteristics.
摘要翻译：描述了由这样的涂层制备的包含阳离子胶体二氧化硅和喷墨记录片的涂料组合物。涂层包括粘合剂和多分散阳离子胶体二氧化硅。阳离子胶体二氧化硅的平均粒径优选在约1至约300纳米的范围内。已经发现，如果在光泽涂层制剂中使用阳离子多分散胶体二氧化硅，则涂层在60℃下提供至少30°的镜面光泽，即使在相对高的二氧化硅固体与粘合剂固体比为1:1的条件下以上，也可以是具有优异的印刷特性的涂层。

4. 发明授权

US09234104B2 Composite metal oxide particles and methods of making and using the same 有权
标题翻译：复合金属氧化物颗粒及其制造和使用方法
公开(公告)号：US09234104B2
公开(公告)日：2016-01-12
申请号：US13519748
申请日：2010-12-13
申请人： Demetrius Michos , Daniel Ray Fruge
发明人： Demetrius Michos , Daniel Ray Fruge
IPC分类号： C08K3/32 , B32B5/16 , C09D5/08 , C01B33/18 , C09C1/30 , C09C1/36 , C09D7/12 , C09C3/06 , C08K3/22 , C08K3/36 , C08K9/02
CPC分类号： C09C3/063 , C01B33/18 , C01P2004/61 , C01P2004/62 , C08K3/22 , C08K3/36 , C08K9/02 , C09C1/3045 , C09C1/3054 , C09C1/3653 , C09C3/06 , C09D5/084 , C09D7/62 , C09D7/67 , C09D7/68 , C09D7/69 , Y10T428/2991
摘要： Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.
摘要翻译：公开了含有二氧化硅颗粒的复合无机颗粒和组合物。还公开了制备二氧化硅颗粒的方法和使用复合无机颗粒的方法。

5. 发明授权

US06902780B2 Coating composition comprising colloidal silica and glossy ink jet recording sheets prepared therefrom 失效
标题翻译：包含胶体二氧化硅和由其制备的光泽喷墨记录纸的涂料组合物
公开(公告)号：US06902780B2
公开(公告)日：2005-06-07
申请号：US10391286
申请日：2003-03-18
申请人： Daniel Ray Fruge , Demetrius Michos
发明人： Daniel Ray Fruge , Demetrius Michos
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C01B33/14 , D21H19/14 , B41M5/40
CPC分类号： B41M5/5218 , B41M5/52
摘要： A coating composition comprising relatively low alkali cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and cationic colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(−0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
摘要翻译：描述了由这样的涂层制备的包含相对低的碱性阳离子胶体二氧化硅和喷墨记录片的涂料组合物。该涂层包括粘合剂和阳离子胶态二氧化硅，其平均粒径在约1至约300纳米范围内，其固体与碱金属之比至少为AW（-0.013SSA + 9），AW为存在于胶体二氧化硅中的碱金属的原子量和SSA为二氧化硅的比表面积。已经发现，如果碱性金属（例如钠）含量降低，则由这种胶态二氧化硅制备的涂料涂覆到传统的喷墨记录片材载体上，在60℃下提供至少30°的镜面光泽度，即使在相对高的二氧化硅固体与粘合剂固体比为1:1或更高的情况下。

6. 发明申请

US20120285349A1 Composite Metal Oxide Particles and Methods of Making and Using the Same 有权
标题翻译：复合金属氧化物颗粒及其制备和使用方法
公开(公告)号：US20120285349A1
公开(公告)日：2012-11-15
申请号：US13519748
申请日：2010-12-13
申请人： Demetrius Michos , Daniel Ray Fruge
发明人： Demetrius Michos , Daniel Ray Fruge
IPC分类号： C08K3/32 , B32B5/16
CPC分类号： C09C3/063 , C01B33/18 , C01P2004/61 , C01P2004/62 , C08K3/22 , C08K3/36 , C08K9/02 , C09C1/3045 , C09C1/3054 , C09C1/3653 , C09C3/06 , C09D5/084 , C09D7/62 , C09D7/67 , C09D7/68 , C09D7/69 , Y10T428/2991
摘要： Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.
摘要翻译：公开了含有二氧化硅颗粒的复合无机颗粒和组合物。还公开了制备二氧化硅颗粒的方法和使用复合无机颗粒的方法。

7. 发明授权

US07622170B2 Coating composition comprising colloidal silica and glossy ink jet recording sheets prepared therefrom 失效
标题翻译：包含胶体二氧化硅和由其制备的光泽喷墨记录纸的涂料组合物
公开(公告)号：US07622170B2
公开(公告)日：2009-11-24
申请号：US10391044
申请日：2003-03-18
申请人： Daniel Ray Fruge , Demetrius Michos
发明人： Daniel Ray Fruge , Demetrius Michos
IPC分类号： B41M5/40
CPC分类号： B41M5/5218 , C08K3/36 , C09D7/62 , C09D7/67 , C09D7/68
摘要： A coating composition comprising low sodium containing colloidal silicas and ink jet recording sheets prepared from such coatings are described. The coating comprises binder and colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(−0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
摘要翻译：描述了由这种涂层制备的包含低钠含胶体二氧化硅和喷墨记录片的涂料组合物。该涂层包括粘合剂和胶态二氧化硅，其平均粒度优选在约1至约300纳米范围内，并且其固体与碱金属之比至少为AW（-0.013SSA + 9），AW为存在于胶体二氧化硅中的碱金属的原子量和SSA是二氧化硅的比表面积。已经发现，如果碱性金属（例如钠）含量降低，则由这种胶态二氧化硅制备的涂料涂覆到传统的喷墨记录片材载体上，在60℃下提供至少30°的镜面光泽度，即使在相对高的二氧化硅固体与粘合剂固体比为1:1或更高的情况下。

8. 发明授权

US06893691B2 Coating composition comprising colloidal silica and glossy ink jet recording sheets prepared therefrom 失效
标题翻译：包含胶体二氧化硅和由其制备的光泽喷墨记录纸的涂料组合物
公开(公告)号：US06893691B2
公开(公告)日：2005-05-17
申请号：US10391287
申请日：2003-03-18
申请人： Daniel Ray Fruge , Demetrius Michos
发明人： Daniel Ray Fruge , Demetrius Michos
IPC分类号： B41M5/00 , B41M5/50 , B41M5/52 , C01B33/14 , C08K3/36 , C09D7/12 , C09D201/00 , D21H19/14 , B41M5/40
CPC分类号： B41M5/5218
摘要： A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.
摘要翻译：描述了包含相对低的含碱胶体二氧化硅和由这种涂层制备的光泽喷墨记录片的涂料组合物。该涂层包括粘合剂和胶态二氧化硅，例如其平均粒度在约1至约300纳米的范围内。本发明的低碱性胶体二氧化硅包括氨，多分散胶体二氧化硅或两者。具有粒度分布使得中值粒径在15至100纳米范围内的多分散二氧化硅，并且80％的颗粒跨越至少约30至约70纳米的范围是优选的。已经发现，由这种胶体二氧化硅制备的并且应用于常规喷墨记录片材载体的涂层在60℃下具有至少30°的镜面光泽度，并且在二氧化硅固体与粘合剂固体比率为1:1或更高时具有优异的可印刷性。

9. 发明申请

US20100314585A1 ANTICORROSION MATERIAL 审中-公开
标题翻译：防腐材料
公开(公告)号：US20100314585A1
公开(公告)日：2010-12-16
申请号：US12743719
申请日：2008-11-24
申请人： Daniel Ray Fruge , Yoshitaka Sugimoto , Qi Sun
发明人： Daniel Ray Fruge , Yoshitaka Sugimoto , Qi Sun
IPC分类号： C23F11/00
CPC分类号： C23F11/187 , C09D1/00 , C09D5/084 , C23C22/06
摘要： An anticorrosion material comprising colloidal particles and multivalent metal ions is disclosed. The particles are preferably silica. The metal ions may be Al, Ga, Ti, Zr, Hf, Zn, Mg, Ca, Nb, Ta, Fe, Cu, Sn, Co, W or Ce. The material can be added to a conversion coating liquid, mixed with a polymeric binder or used as such to form a coating.
摘要翻译：公开了一种包含胶体颗粒和多价金属离子的防腐材料。颗粒优选为二氧化硅。金属离子可以是Al，Ga，Ti，Zr，Hf，Zn，Mg，Ca，Nb，Ta，Fe，Cu，Sn，Co，W或Ce。可以将该材料加入到与聚合物粘合剂混合的转化涂料液体中，或者直接用于形成涂料。

10. 发明申请

US20120142845A1 METAL OXIDE DISPERSION 审中-公开
标题翻译：金属氧化物分散体
公开(公告)号：US20120142845A1
公开(公告)日：2012-06-07
申请号：US13148755
申请日：2009-09-11
申请人： Kris P. De Winter , Nicolas H.M. Leliveld , Horst Herrig , Daniel Ray Fruge
发明人： Kris P. De Winter , Nicolas H.M. Leliveld , Horst Herrig , Daniel Ray Fruge
IPC分类号： C08K3/36
CPC分类号： C09C1/3081 , C01P2004/61 , C08K3/22 , C08K3/36 , C09C1/028 , C09C1/3684 , C09C1/407 , C09C3/12 , C08L91/00
摘要： A metal oxide particulate dispersion comprising, oil and metal oxide particles having an average particle size of 35 microns or less, wherein the dispersion includes less than 10% by weight water and water-miscible solvent, based on the total weight of the dispersion.
摘要翻译：包含平均粒径为35微米或更小的油和金属氧化物颗粒的金属氧化物颗粒分散体，其中基于分散体的总重量，分散体包含小于10重量％的水和水混溶性溶剂。

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