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1. 发明申请

WO9839406A9 BLEACH COMPOSITIONS 审中-公开
标题翻译：漂白组合物
公开(公告)号：WO9839406A9
公开(公告)日：1999-09-16
申请号：PCT/IB9800300
申请日：1998-03-06
申请人： PROCTER & GAMBLE , UNIV KANSAS , BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY , LABEQUE REGINE , WILLIAMS BARBARA KAY , JOHNSTON JAMES PYOTT , KITKO DAVID JOHNATHAN , BURCKETT ST LAURENT JAMES CHAR , PERKINS CHRISTOPHER MARK
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY , LABEQUE REGINE , WILLIAMS BARBARA KAY , JOHNSTON JAMES PYOTT , KITKO DAVID JOHNATHAN , BURCKETT-ST LAURENT JAMES CHAR , PERKINS CHRISTOPHER MARK
IPC分类号： C11D20060101 , C11D3/16 , C11D3/39 , C11D3/395 , D06L20060101
CPC分类号： C11D3/3935 , C11D3/168 , C11D3/3932 , C11D3/3942 , C11D3/3945
摘要： Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9 %, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1 % of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
摘要翻译：洗衣或清洁组合物，其包含：（a）催化有效量，优选约1ppb至约99.9％的过渡金属漂白催化剂，其为过渡金属和交叉桥联的大多环配体的络合物; 和（b）至少约0.1％的一种或多种衣物或清洁辅助材料，优选包含氧漂白剂。优选的组合物是洗衣组合物和自动餐具洗涤剂，其通过使用这种催化剂提供增强的清洁/漂白益处。

2. 发明专利

ES2289202T3 CATALIZADORES Y METODOS PARA OXIDACION CATALITICA. 未知
公开(公告)号：ES2289202T3
公开(公告)日：2008-02-01
申请号：ES03008790
申请日：1998-03-06
申请人： PROCTER & GAMBLE
发明人： BUSCH DARLYE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY
IPC分类号： B01J31/18 , B01J31/22 , B01J31/16 , C07D471/18 , C07D471/22 , C07D487/08 , C07D487/18 , C07F13/00 , C07F19/00 , C11D3/39
摘要： Un sistema catalítico eficaz para oxidar materiales que comprende: (a) de 1 ppb a 500 ppm de un catalizador de oxidación con metal de transición, comprendiendo dicho catalizador un complejo de un metal de transición y un ligando macropolicíclico unido por puente cruzado, en donde: (1) dicho metal de transición se selecciona del grupo que consiste en Mn(II), Mn(III), Mn(IV), Mn(V), Fe(II), Fe(III), Fe(IV), Cr(II), Cr(III), Cr(IV), Cr(V), Cr(VI); y (2) dicho ligando macropolicíclico rígido está coordinado por al menos cuatro, preferiblemente cinco, átomos dadores al mismo metal de transición y comprende: (i) un anillo macrocíclico orgánico que contiene cuatro o más átomos dadores, preferiblemente al menos 3, más preferiblemente al menos 4, de estos átomos dadores son N, separados entre sí por enlaces covalentes de al menos uno, preferiblemente 2 ó 3, átomos no dadores, estando de dos a cinco, preferiblemente de tres a cuatro, más preferiblemente cuatro, de estos átomos dadores coordinados almismo metal de transición en el complejo; (ii) un resto de unión que es una cadena unida por puente cruzado, que conecta covalentemente al menos 2 átomos dadores no adyacentes del anillo macrocíclico orgánico, siendo dichos átomos dadores covalentemente conectados no adyacentes átomos dadores cabeza de puente que están coordinados al mismo metal de transición en el complejo, y en donde dicho resto de unión comprende de 2 a 10 átomos, en donde la cadena unida por puente cruzado preferida se selecciona de 2, 3 ó 4 átomos no dadores y 4-6 átomos no dadores con un átomo dador adicional; y (3) uno o más ligandos no macropolicíclicos, preferiblemente seleccionados del grupo que consiste en H2O, ROH, NR3, RCN, OH-, OOH-, RS-, RO-, RCOO-, OCN-, SCN-, N3-, CN-, F-, Cl-, Br-, I-, O2-, NO3-, NO2-, SO42-, SO32-, PO43-, fosfatos orgánicos, fosfonatos orgánicos, sulfatos orgánicos, sulfonatos orgánicos y dadores de N aromáticos tales como piridinas, piracinas, pirazoles, imidazoles, bencimidazoles, pirimidinas, triazoles y tiazoles en donde R es H, alquilo opcionalmente sustituido, arilo opcionalmente sustituido; y (b) el resto hasta 100% de uno o más materiales adyuvantes detergentes.

3. 发明专利

CA2283163C BLEACH COMPOSITIONS COMPRISING A TRANSITION METAL BLEACH CATALYST INCORPORATING A CROSS-BRIDGED MACROPOLYCYCLIC LIGAND AND AN OXYGEN BLEACH 未知
公开(公告)号：CA2283163C
公开(公告)日：2006-10-31
申请号：CA2283163
申请日：1998-03-06
申请人： PROCTER & GAMBLE , UNIV KANSAS
发明人： HUBIN TIMOTHY JAY , WILLIAMS BARBARA KAY , PERKINS CHRISTOPHER MARK , LABEQUE REGINE , COLLINSON SIMON ROBERT , BUSCH DARYLE HADLEY , JOHNSTON JAMES PYOTT , BURCKETT-ST LAURENT JAMES CHAR , KITKO DAVID JOHNATHAN
IPC分类号： C11D3/39 , C11D20060101 , C11D3/16 , C11D3/395 , D06L20060101
摘要： Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9 %, of transition-metal bleach catalyst which is a complex of a transition-metal an d a cross-bridged macropolycyclic ligand; and (b) at least about 0.1 % of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.

4. 发明专利

AU6226298A Bleach compositions 未知
公开(公告)号：AU6226298A
公开(公告)日：1998-09-22
申请号：AU6226298
申请日：1998-03-06
申请人： PROCTER & GAMBLE , UNIV KANSAS
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY , LABEQUE REGINE , WILLIAMS BARBARA KAY , JOHNSTON JAMES PYOTT , KITKO DAVID JOHNATHAN , LAURENT JAMES CHARLES THEOPHIL , PERKINS CHRISTOPHER MARK
IPC分类号： C11D20060101 , C11D3/16 , C11D3/39 , C11D3/395 , D06L20060101
摘要： A laundry or cleaning composition comprising: (a) 1ppb-49% of a transition metal bleach catalyst comprising a complex of a transition metal and a cross-bridged macropolycyclic ligand in which: (1) the metal is selected from Mn(II), Mn(IV), Mn(V), Fe(II), Fe(III), Fe(IV), Co(I), Co(II), Co(III), Ni(I), Ni(II), Ni(III), Cu(I), Cu(II), Cr(III), Cr(IV), Cr(V), Cr(VI), V(III), V(IV), V(V), Mo(IV), Mo(V), Mo(VI), W(IV), W(VI), Pd(II), Ru(II), RU(III) and Ru(IV); and (2) the macropolycyclic rigid ligand is selected from: (i) ligand of formula (I) having denticity of 4 or 5: (ii) ligand of formula (II) having denticity of 5 or 6: (iii) ligand of formula (III) having denticity of 6 or 7; (where E = moiety (CRn)a-X-(CRn)a'; X = O, S, NR or P, or a covalent bond (especially covalent bond); for each E the sum of a + a' = 1-5( especially 2 and 3; G = (CRn)b; R = H, alkyl, alkenyl, alkynyl, aryl, alkylaryl or heteroaryl or two or more are covalently bonded to form an aromatic or hetero aromatic, cycloalkyl or heterocycloalkyl ring; D = donor atom selected from N,O, S, or P, at least two D atoms are bridgehead donor atoms coordinated to the transition metal; b = C or D or cycloalkyl or heterocyclic ring; n = 1 or 2, completing the valence of C atoms to which R moieties are bonded; n' = 0 or 1 completing the valence of D donor atoms to which R moieties are bonded; n'' = 0,1 or 2 completing the valence of B atoms to which R moieties are bonded; a, a' = 0-5, preferably a + a' = 2 or 3, the sum of all a + sum of all a' in formula (I) being 7-12, the sum of all a + a' in formula (II) being 6 (especially 8) -12, the sum of all a + a' in formula (III) being 8 (especially 10)-15 and the sum of all a + a' in formula (IV) being 10 (especially 12)-18; b = 0-9 (especially 0-5) or one or more of the (CRn)b moieties covalently bonded from any D to the B atom is absent as long as at least two (CRn)b covalently bond two of the D donor atoms to the B atom and the sum of all b is 1-5; and (iv) optionally one or more non-macropolycyclic ligands, preferably selected from H2O, ROH, NR3, RCN, OH-, OOH-, RS-, RO-, OCN-, SCN-, N3-, CN-, F-, Cl-, Br-, I-, O2-, NO3-, NO2-, SO42-, SO32-, PO43-, organic phosphates, organic phosphonates, organic sulphates, organic sulphonates, and aromatic N-donors such as pyridines, pyrazines, pyrazoles, imidazoles, benzimidazoles, pyrimidines, triazoles, and thiazoles with R being H, optionally substituted alkyl or aryl; and (b) at least 0.1% adjunct ingredient(s), preferably oxygen bleaching agent. Preferably the donor atoms in the macropolycyclic ligand are N, S, O or P, especially N or O, more especially all are N. The ligand comprises 4 or 5 donor atoms all connected to the same transition metal. The ligand comprises an organic macrocycle ring having at least 12, especially 12-20 atoms. Al, a are 2 or 3, all X are covalent bonds, a' are 0 and B are 0.1 or 2. The mol ratio of transition metal to ligand is 1:1 and transition metal is Mn or Fe.

5. 发明专利

ZA981890B Bleach compositions 未知
公开(公告)号：ZA981890B
公开(公告)日：1998-09-01
申请号：ZA981890
申请日：1998-03-05
申请人： PROCTER & GAMBLE , UNIV KANSAS
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY , LABEQUE REGINE , WILLIAMS BARBARA KAY , JOHNSTON JAMES PYOTT , KITKO DAVID JOHNATHAN , PERKINS CHRISTOPHER MARK , LAURENT JAMES CHARLES THEOPHIL
IPC分类号： C11D20060101 , C11D3/39 , C11D3/395 , D06L20060101 , C11D , D06L

6. 发明专利

CZ301076B6 Prací nebo cisticí prípravek 未知
公开(公告)号：CZ301076B6
公开(公告)日：2009-10-29
申请号：CZ315399
申请日：1998-03-06
申请人： PROCTER & GAMBLE
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY , LABEQUE REGINE , WILLIAMS BARBARA KAY , JOHNSTON JAMES PYOTT , KITKO DAVID JONNATHAN , BURCKETT-ST LAURENT JAMES CHARLES THEOPHILE ROGER , PERKINS CHRISTOPHER MARK
IPC分类号： C11D3/16 , C11D20060101 , C11D3/39 , C11D3/395 , D06L20060101
摘要： Prací nebo cisticí prípravek obsahující 1.10.sup.-7.n. až 99,9 % hmotnostních katalyzátoru belidla na bázi prechodného kovu, což je komplex prechodného kovu a zesítovaného makropolycyklického ligandu, který má alespon ctyri donorové atomy, pricemž alespon dva z nich jsou koncové atomy mustku, zesítování oznacuje rozpulení makrocyklického kruhu, ve kterém jsou dva donorové atomy kovalentne spojeny spojující skupinou a ve kterém je alespon jeden donorový atom kruhu v každé cásti kruhu oddelen rozpulením a zbytek do 100 % hmotnostních jedné nebo více prísad do pracích nebo cisticích prípravku zahrnujících kyslíkaté belidlo.

7. 发明专利

HU225021B1 METAL COMPLEXES AND CATALYTIC SYSTEMS FOR OXIDATION OF MATERIALS 未知
公开(公告)号：HU225021B1
公开(公告)日：2006-05-29
申请号：HU0001906
申请日：1998-03-06
申请人： PROCTER & GAMBLE
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY
IPC分类号： B01J31/18 , B01J31/22 , B01J31/16 , C07D471/18 , C07D471/22 , C07D487/08 , C07D487/18 , C07F13/00 , C07F19/00 , C11D3/39
摘要： The present invention relates to catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.

8. 发明专利

TR199902673T2 未知
公开(公告)号：TR199902673T2
公开(公告)日：2000-04-21
申请号：TR9902673
申请日：1998-03-06
申请人： PROCTER & GAMBLE , UNIV KANSAS
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY , LABEQUE REGINE , WILLIAMS BARBARA KAY , JOHNSTON JAMES PYOTT , KITKO DAVID JOHNATHAN , LAURENT JAMES CHARLES THEOPHIL , PERKINS CHRISTOPHER MARK
IPC分类号： C11D20060101 , C11D3/16 , C11D3/39 , C11D3/395 , D06L20060101
摘要： A laundry or cleaning composition comprising: (a) 1ppb-49% of a transition metal bleach catalyst comprising a complex of a transition metal and a cross-bridged macropolycyclic ligand in which: (1) the metal is selected from Mn(II), Mn(IV), Mn(V), Fe(II), Fe(III), Fe(IV), Co(I), Co(II), Co(III), Ni(I), Ni(II), Ni(III), Cu(I), Cu(II), Cr(III), Cr(IV), Cr(V), Cr(VI), V(III), V(IV), V(V), Mo(IV), Mo(V), Mo(VI), W(IV), W(VI), Pd(II), Ru(II), RU(III) and Ru(IV); and (2) the macropolycyclic rigid ligand is selected from: (i) ligand of formula (I) having denticity of 4 or 5: (ii) ligand of formula (II) having denticity of 5 or 6: (iii) ligand of formula (III) having denticity of 6 or 7; (where E = moiety (CRn)a-X-(CRn)a'; X = O, S, NR or P, or a covalent bond (especially covalent bond); for each E the sum of a + a' = 1-5( especially 2 and 3; G = (CRn)b; R = H, alkyl, alkenyl, alkynyl, aryl, alkylaryl or heteroaryl or two or more are covalently bonded to form an aromatic or hetero aromatic, cycloalkyl or heterocycloalkyl ring; D = donor atom selected from N,O, S, or P, at least two D atoms are bridgehead donor atoms coordinated to the transition metal; b = C or D or cycloalkyl or heterocyclic ring; n = 1 or 2, completing the valence of C atoms to which R moieties are bonded; n' = 0 or 1 completing the valence of D donor atoms to which R moieties are bonded; n'' = 0,1 or 2 completing the valence of B atoms to which R moieties are bonded; a, a' = 0-5, preferably a + a' = 2 or 3, the sum of all a + sum of all a' in formula (I) being 7-12, the sum of all a + a' in formula (II) being 6 (especially 8) -12, the sum of all a + a' in formula (III) being 8 (especially 10)-15 and the sum of all a + a' in formula (IV) being 10 (especially 12)-18; b = 0-9 (especially 0-5) or one or more of the (CRn)b moieties covalently bonded from any D to the B atom is absent as long as at least two (CRn)b covalently bond two of the D donor atoms to the B atom and the sum of all b is 1-5; and (iv) optionally one or more non-macropolycyclic ligands, preferably selected from H2O, ROH, NR3, RCN, OH-, OOH-, RS-, RO-, OCN-, SCN-, N3-, CN-, F-, Cl-, Br-, I-, O2-, NO3-, NO2-, SO42-, SO32-, PO43-, organic phosphates, organic phosphonates, organic sulphates, organic sulphonates, and aromatic N-donors such as pyridines, pyrazines, pyrazoles, imidazoles, benzimidazoles, pyrimidines, triazoles, and thiazoles with R being H, optionally substituted alkyl or aryl; and (b) at least 0.1% adjunct ingredient(s), preferably oxygen bleaching agent. Preferably the donor atoms in the macropolycyclic ligand are N, S, O or P, especially N or O, more especially all are N. The ligand comprises 4 or 5 donor atoms all connected to the same transition metal. The ligand comprises an organic macrocycle ring having at least 12, especially 12-20 atoms. Al, a are 2 or 3, all X are covalent bonds, a' are 0 and B are 0.1 or 2. The mol ratio of transition metal to ligand is 1:1 and transition metal is Mn or Fe.

9. 发明专利

CZ302258B6 Katalytický systém obsahující komplex prechodového kovu a jeho použití 未知
公开(公告)号：CZ302258B6
公开(公告)日：2011-01-19
申请号：CZ313899
申请日：1998-03-06
申请人： PROCTER & GAMBLE
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY
IPC分类号： B01J31/18 , B01J31/22 , B01J31/16 , C07D471/18 , C07D471/22 , C07D487/08 , C07D487/18 , C07F13/00 , C07F19/00 , C11D3/39
摘要： Katalytický systém úcinný pri oxidaci látek obsahující a) katalyticky úcinné množství, výhodne 1.10.sup.-7.n.až 99,9 % hmotn., oxidacního katalyzátoru prechodného kovu, kde oxidacní katalyzátor prechodného kovu obsahuje komplex prechodného kovu vybraného ze skupiny obsahující Mn(II), Mn(III), Mn(IV), Mn(V), Fe(II), Fe(III), Fe(IV), Co(I), Co(II), Co(III), Ni(I), Ni(II), Ni(III), Cu(I), Cu(II), Cu(III), Cr(II), Cr(III), Cr(IV), Cr(V), Cr(VI), V(III), V(IV), V(V),Mo(IV), Mo(V), Mo(VI), W(IV), W(V), W(VI), Pd(II), Ru(II), Ru(III) a Ru(IV); koordinovaného s makropolycyklickým ligandem, a b) zbytek do 100 % hmotn, s výhodou alespon 0,1 % hmotn. jedné nebo více detergentních doplnkových látek. Zpusob oxidace látek za použití výše uvedeného katalytického systému, kde zpusobem jsou napr. syntetické organické oxidacní reakce, oxidace sloucenin schopných oxidace, napr. skvrn na površích, napr. vláken, nádobí, pultu, zubních protéz a jiných, oxidace sloucenin schopných oxidace v roztoku, inhibice odbarvování pri praní vláken; a krome toho belení buniciny a produktu z papíru.

10. 发明专利

ES2203928T3 未知
公开(公告)号：ES2203928T3
公开(公告)日：2004-04-16
申请号：ES98904334
申请日：1998-03-06
申请人： PROCTER & GAMBLE
发明人： BUSCH DARYLE HADLEY , COLLINSON SIMON ROBERT , HUBIN TIMOTHY JAY
IPC分类号： B01J31/22 , B01J31/16 , B01J31/18 , C07D471/18 , C07D471/22 , C07D487/08 , C07D487/18 , C07F13/00 , C07F19/00 , C11D3/39
摘要： The present invention relates to catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.

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