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    • 1. 发明申请
    • WATER ABSORBING AGENT, WATER ABSORBING ARTICLE AND METHOD FOR PRODUCTION OF WATER ABSORBING AGENT
    • 吸水剂,吸水剂及其吸水剂的生产方法
    • WO2006088115A1
    • 2006-08-24
    • PCT/JP2006/302782
    • 2006-02-10
    • NIPPON SHOKUBAI CO., LTD.KIMURA, KazukiFUJINO, Shin-ichiWADA, KatsuyukiISHIZAKI, Kunihiko
    • KIMURA, KazukiFUJINO, Shin-ichiWADA, KatsuyukiISHIZAKI, Kunihiko
    • C08J3/12
    • A61L15/60B01J20/26B01J20/264B01J20/267B01J20/28004B01J20/2803B01J20/28047B01J20/30B01J20/3028B01J2220/68C08J3/245C08J2300/14Y10T428/2982Y10T428/2991Y10T428/2998
    • An object of the present invention is to provide a water absorbing agent having a low amount of residual monomer, small variance of the amount of residual monomer among ranges of particle size distribution and favorable absorption properties, and being sanitary; an absorbing article; and a method for the production of a water absorbing agent. The water absorbing agent of the present invention has the amount of residual monomer of not higher than 500 ppm, and a residual monomer index of not greater than 0.30.The method for the production includes a first step of obtaining a hydrogel polymer by polymerizing an aqueous solution of a monomer including an unsaturated carboxylic acid and/or a salt thereof in the presence of a crosslinking agent;a second step of obtaining a water absorbent resin precursor which is in powder form and includes particles having a particle size of 300 to 850 µm and particles having a particle size of smaller than 300 µm as main components by drying said hydrogel polymer followed by pulverization and classification to adjust the particle size distribution,a third step of obtaining a water absorbent resin by heating a mixture of said water absorbent resin precursor and a surface crosslinking agent, which can form an ester bond around the surface of said water absorbent resin precursor,a fourth step of adding by spraying an aqueous solution that includes a sulfur-containing reducing agent to said water absorbent resin, and a fifth step of subjecting the mixture of the water absorbent resin and said aqueous solution to a heat treatment under an airflow of not lower than 40°C but not higher than 120°C.
    • 本发明的目的是提供一种具有少量残留单体的吸水剂,在粒度分布范围和吸收性能良好之间的残留单体量的变化小,并且是卫生的; 吸收物品 和吸水剂的制造方法。 本发明的吸水剂的残留单体的量不高于500ppm,残留单体指数不大于0.30。制备方法包括通过聚合水性聚合物获得水凝胶聚合物的第一步骤 包含不饱和羧酸和/或其盐的单体在交联剂存在下的溶液;第二步,获得粉末形式的吸水性树脂前体,并且包括粒度为300至850μm的颗粒 粒径小于300μm的颗粒作为主要组分,通过干燥所述水凝胶聚合物,然后粉碎和分级以调节粒度分布;第三步骤,通过加热所述吸水性树脂前体的混合物获得吸水性树脂 以及可在所述吸水性树脂前体的表面周围形成酯键的表面交联剂,第四步骤 通过将包含含硫还原剂的水溶液喷雾到所述吸水性树脂中而添加,第五步是在吸水性树脂和所述水溶液的混合物在不低于40°的气流下进行热处理 但不高于120℃。
    • 3. 发明申请
    • WATER-ABSORBENT AGENT COMPOSITION AND METHOD FOR MANUFACTURING SAME
    • 吸水剂组合物及其制造方法
    • WO2007037522A1
    • 2007-04-05
    • PCT/JP2006/319923
    • 2006-09-28
    • NIPPON SHOKUBAI Co., Ltd.KIMURA, KazukiIKEUCHI, Hiroyuki
    • KIMURA, KazukiIKEUCHI, Hiroyuki
    • C08L33/02C08K3/36C08K5/00
    • C08J3/245C08J2300/14C08J2333/02C08K3/36C08L33/02C08L2312/00C08L2666/02
    • A subject invention provides a water-absorbent agent composition superior in both liquid permeability and liquid updrawing property, which are conventionally incompatible. Moreover, the water-absorbent agent composition according to the present invention causes less decrease in liquid updrawing property. The water-absorbent agent composition according to the present invention contains as a main component a polycarboxylic acid water-absorbent agent having a crosslinking structure which is produced by polymerizing an acid-group-containing unsaturated monomer, the water-absorbent agent composition containing water-insoluble organic or inorganic fine particles, the water-absorbent agent composition satisfying the following set of conditions (a) through (e): (a) decreasing rate of a liquid distribution velocity (LDV) is not more than 30%; (b) saline flow conductivity (SFC) is not less than 60 (Unit: 10 -7 cm 3 s/g); (c) mass average particle diameter (D50) is 200 to 420 m; (d) logarithm standard deviation (σζ ) of particle size distribution is 0.25 to 0.40; and (e) percentage of particles less than 150 μm in diameter is not more than 3 mass % with respect to the whole particle amount.
    • 本发明提供了一种传统上不相容的液体渗透性和液体上翘性均优异的吸水剂组合物。 此外,根据本发明的吸水剂组合物引起液体上翘性能的降低较少。 本发明的吸水剂组合物含有具有交联结构的聚羧酸类吸水剂作为主要组分,所述聚羧酸类吸水剂通过聚合含酸基的不饱和单体而制得,所述吸水剂组合物包含水溶性聚合物, (a)至(e)的条件组成的吸水剂组合物:(a)液体分布速度(LDV)的降低率不大于30%; (b)盐水导流率(SFC)不小于60(单位:10 -7 cm 3 s / g); (c)质量平均粒径(D50)为200〜420μm, (d)粒度分布的对数标准偏差(σζ)为0.25至0.40; 和(e)相对于全部颗粒量,直径小于150μm的颗粒的百分比不大于3质量%。