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1. 发明专利

CA2043034A1 PD-ADDED AUSTENITIC STAINLESS STEEL FOR USE FOR HIGH TEMPERATURE CONCENTRATED SULFURIC ACID 未知
公开(公告)号：CA2043034A1
公开(公告)日：1991-11-24
申请号：CA2043034
申请日：1991-05-22
申请人： MITSUBISHI HEAVY IND LTD
发明人： EBARA RYUICHIRO , NAKAMOTO HIDEO , UKAWA NAOHIKO , YAMADA TAMOTSU , NISHIMURA YASUO
IPC分类号： C22C38/00 , C22C30/00 , C22C38/40 , C22C38/58
摘要： An austenitic stainless steel for use for high temperature concentrated sulfuric acid which comprises, on weight basis, 0.04 % or less of C, 5 - 7 % of Si, 2 % or less of Mn, 15 - 25 % of Cr, 4 - 24 % of Ni, 0.01 - 1.07 % of Pd and the rest consisting of Fe and unavoidable contaminant materials. By the incorporation of small amount of palladium in a basal austenitic stainless steel containing the essential three elements of Cr, Ni and Si, a superior corrosion resistance against highly concentrated high temperature sulfuric acid is attained.

2. 发明专利

DE69108604T2 未知
公开(公告)号：DE69108604T2
公开(公告)日：1995-09-28
申请号：DE69108604
申请日：1991-05-21
申请人： MITSUBISHI HEAVY IND LTD
发明人： EBARA RYUICHIRO , NAKAMOTO HIDEO , UKAWA NAOHIKO , YAMADA TAMOTSU , NISHIMURA YASUO
IPC分类号： C22C38/00 , C22C30/00 , C22C38/40 , C22C38/58
摘要： An austenitic stainless steel for use for high temperature concentrated sulfuric acid which comprises, on weight basis 0.04% or less of C, 5 - 7% of Si, 2% or less of Mn, 15 - 25% of Cr, 4 - 24% of Ni, 0.01 - 1.07% of Pd and the rest consisting of Fe and unavoidable contaminant materials.

3. 发明专利

DE69108604D1 未知
公开(公告)号：DE69108604D1
公开(公告)日：1995-05-11
申请号：DE69108604
申请日：1991-05-21
申请人： MITSUBISHI HEAVY IND LTD
发明人： EBARA RYUICHIRO , NAKAMOTO HIDEO , UKAWA NAOHIKO , YAMADA TAMOTSU , NISHIMURA YASUO
IPC分类号： C22C38/00 , C22C30/00 , C22C38/40 , C22C38/58
摘要： An austenitic stainless steel for use for high temperature concentrated sulfuric acid which comprises, on weight basis 0.04% or less of C, 5 - 7% of Si, 2% or less of Mn, 15 - 25% of Cr, 4 - 24% of Ni, 0.01 - 1.07% of Pd and the rest consisting of Fe and unavoidable contaminant materials.

4. 发明专利

CA2494439A1 FUEL CELL MEMBRANE ELECTRODE AND FUEL CELL 未知
公开(公告)号：CA2494439A1
公开(公告)日：2005-07-30
申请号：CA2494439
申请日：2005-01-26
申请人： MITSUBISHI HEAVY IND LTD
发明人： YOSHIDA HIROHISA , TSURUMAKI SHIGERU , SATO AKIO , WATANABE SATORU , MORIGA TAKUYA , YAMADA TAMOTSU , ITO HIDEKI , NOJIMA SHIGERU , YAMADA AKIHIKO
IPC分类号： H01M4/86 , H01M4/90 , H01M8/02 , H01M8/10
摘要： A fuel cell membrane electrode having a cathode catalyst layer on one surface of a polymer electrolyte membrane, and an anode catalyst layer on the other surface of the membrane, the cathode catalyst layer being supplied with an oxygen-containing gas, and the anode catalyst layer being supplied with a hydrogen-containing gas, and wherein an active oxygen removing layer containing an active oxygen removing material is provided on at least one of interfaces between the membrane and the catalyst layers coated on both surfaces of the membrane, and the active oxygen removing material is Co3O4, Sb2O4, activated carbon, or a solid acid catalyst; and a fuel cell using the membrane electrode.

5. 发明专利

CA2444757A1 STACKED FUEL CELL AND METHOD FOR ITS MAINTENANCE 未知
公开(公告)号：CA2444757A1
公开(公告)日：2004-07-08
申请号：CA2444757
申请日：2003-10-14
申请人： MITSUBISHI HEAVY IND LTD
发明人： MORIGA TAKUYA , KAJIWARA TOMOYUKI , ITO HIDEKI , KOBAYASHI TOSHIRO , YAMADA TAMOTSU
IPC分类号： H01M8/00 , H01M8/02 , H01M8/04 , H01M8/10 , H01M8/24
摘要： A stacked fuel cell comprises a plurality of cell films (11) and a plurality of separators (12) stacked alternately. The cell films (11) each comprise a solid polymer electrolyte film sandwiched between electrode films made of graphite, while the separators (12) are electrically conductive graphite separators each having a fuel gas channel formed in one surface thereof, and an oxidant gas channel formed in the other surface thereof. In the stacked fuel cell, a plurality of partition plates (18) are interposed with predetermined spacing in the direction of stacking. The partition plates (18) each have an electrically conductive graphite terminal board (16) having a groove (16a) formed as a piercing portion, through which a band-shaped fastener (19) made of resin (for example, polypropylene) is passed in a direction perpendicular to the direction of stacking, and an electrically conductive graphite end separator (17) having a gas channel formed in a surface thereof in contact with the cell film (11). 27

6. 发明专利

CA2043034C PD-ADDED AUSTENITIC STAINLESS STEEL FOR USE FOR HIGH TEMPERATURE CONCENTRATED SULFURIC ACID 未知
公开(公告)号：CA2043034C
公开(公告)日：1996-04-09
申请号：CA2043034
申请日：1991-05-22
申请人： MITSUBISHI HEAVY IND LTD
发明人： EBARA RYUICHIRO , NAKAMOTO HIDEO , UKAWA NAOHIKO , YAMADA TAMOTSU , NISHIMURA YASUO
IPC分类号： C22C38/00 , C22C30/00 , C22C38/40 , C22C38/58
摘要： An austenitic stainless steel for use for high temperature concentrated sulfuric acid which comprises, on weight basis, 0.04 % or less of C, 5 - 7 % of Si, 2 % or less of Mn, 15 - 25 % of Cr, 4 - 24 % of Ni, 0.01 - 1.07 % of Pd and the rest consisting of Fe and unavoidable contaminant materials. By the incorporation of small amount of palladium in a basal austenitic stainless steel containing the essential three elements of Cr, Ni and Si, a superior corrosion resistance against highly concentrated high temperature sulfuric acid is attained.

7. 发明专利

JP2007193951A Fuel cell and its operation method 有权
标题翻译：燃料电池及其操作方法
公开(公告)号：JP2007193951A
公开(公告)日：2007-08-02
申请号：JP2006008227
申请日：2006-01-17
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： MORIGA TAKUYA , ITO EIKI , YAMADA AKIHIKO , YAMADA TAMOTSU , BABA TAKANORI
IPC分类号： H01M8/04 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a circulation type fuel cell capable of preventing drop in voltage in generated electric power caused by enrichment of an electrode catalyst poisoning substance, and keeping utilization factor of fuel gas or oxidant gas (efficiency of the fuel cell) in a high level, and to provide the operation method of the fuel cell. SOLUTION: For example, only when average cell voltage V1 of a stack is dropped than reference cell voltage V3, drop in voltage of the stack is judged that it is caused by enrichment of the electrode catalyst poisoning substance, exhaust amounts of hydrogen gas and oxygen gas are increased with a hydrogen gas exhaust amount control valve and an oxygen gas exhaust amount control valve so that a hydrogen gas utilization factor η1 and an oxygen gas utilization factor η2 reach a target hydrogen gas utilization factor η1a and a target oxygen gas utilization factor η2a, and by decreasing the exhaust amounts of the fuel gas and the oxidant gas with the hydrogen gas exhaust amount control valve and the oxygen gas exhaust amount control valve after voltage of the generated electric power is recovered, the hydrogen gas utilization factor η1 and the oxygen gas utilization factor η2 are returned to initial values. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种循环型燃料电池，其能够防止由电极催化剂中毒物质的富集引起的发电电压下降，并且保持燃料气体或氧化剂气体的利用率（燃料的效率电池），并且提供燃料电池的操作方法。
解决方案：例如，仅当堆叠的平均电池电压V1比参考电池电压V3下降时，判断堆叠电压的下降是由电极催化剂中毒物质的富集引起的，氢的排出量通过氢气排出量控制阀和氧气排出量控制阀增加气体和氧气，使得氢气利用系数η1和氧气利用系数η2达到目标氢气利用系数η1a，目标氧气利用系数η2a，并且在恢复生成电力的电压之后，通过利用氢气排出量控制阀和氧气排出量控制阀减少燃料气体和氧化剂气体的排出量，氢气利用系数η1 氧气利用系数η2返回到初始值。版权所有（C）2007，JPO＆INPIT

8. 发明专利

JP2005327611A Solid polymer fuel cell 有权
标题翻译：固体聚合物燃料电池
公开(公告)号：JP2005327611A
公开(公告)日：2005-11-24
申请号：JP2004144992
申请日：2004-05-14
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： ITO EIKI , YOSHIDA HIROHISA , TSURUMAKI SHIGERU , MORIGA TAKUYA , YAMADA TAMOTSU , YAMADA AKIHIKO , KOBAYASHI TOSHIRO
IPC分类号： H01M8/24 , H01M8/04 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer fuel cell 1 preventing unstable action of a downstream unit 5 which is caused by condensed water produced in an intermediate flange 7.
SOLUTION: In this solid polymer fuel cell 1, a plurality of laminates 3, 5 formed by laminating a plurality of unit cells in each of which a fuel electrode and an oxidizer electrode are each disposed on both sides of a solid polymer electrolyte and separators 9 are disposed on the outside of these electrodes are disposed through the intermediate flange 7, a fuel gas passage 20 for a fuel gas to flow is provided in the intermediate flange 7, and the fuel gas flows in the units 3, 5 one by one by passing through the fuel gas passage 20. In this intermediate flange 7, the fuel gas passage 20 is inclined so as to remove condensed water condensed from the gas flowing in the fuel gas passage 20.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决方案：提供固体聚合物燃料电池1，防止由中间法兰7中产生的冷凝水引起的下游单元5的不稳定作用。解决方案：在该固体聚合物燃料电池1中，在这些电极的外侧设置多个层压体3,5，其通过层叠多个单元电池而形成，所述多个单元电池分别设置在固体聚合物电解质的两面和隔板9的两侧，通过中间凸缘7，在中间凸缘7中设置用于燃料气体流动的燃料气体通道20，并且燃料气体通过燃料气体通道20一个接一个地流入单元3,5中。在此中间凸缘7，燃料气体通道20倾斜，以便去除在燃料气体通道20中流动的气体冷凝的冷凝水。（C）2006年，JPO＆NCIPI

9. 发明专利

JP2005216701A Membrane electrode for fuel cell and fuel cell 有权
标题翻译：用于燃料电池和燃料电池的膜电极
公开(公告)号：JP2005216701A
公开(公告)日：2005-08-11
申请号：JP2004022763
申请日：2004-01-30
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： WATANABE SATORU , TSURUMAKI SHIGERU , ITO EIKI , MORIGA TAKUYA , YOSHIDA HIROHISA , SATO AKIO , NOJIMA SHIGERU , YAMADA TAMOTSU , YAMADA AKIHIKO
IPC分类号： H01M4/86 , H01M4/90 , H01M8/02 , H01M8/10
CPC分类号： H01M8/1004 , H01M4/86 , H01M4/90 , H01M2300/0082
摘要： PROBLEM TO BE SOLVED: To provide a membrane electrode that is never deteriorated even in a long-term operation in a low humidification condition in a solid polymer type fuel cell. SOLUTION: This membrane electrode for a fuel cell is provided with a cathode catalyst layer to be supplied with an oxygen-containing gas on one surface of a polymer electrolyte membrane, and an anode catalyst layer to be supplied with a hydrogen-containing gas on the other surface thereof. The membrane electrode for a fuel cell is characterized by that an active oxygen removal layer containing an active oxygen removal material is formed on at least either of the interfacial surfaces between the membrane and the catalyst layers applied to both its surfaces; and the active oxygen removal material is Co 3 O 4 , Sb 2 O 4 , activated carbon or a solid acid catalyst. This fuel cell using the membrane electrode is also provided. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供即使在固体聚合物型燃料电池的低加湿条件下的长期运行中也不会劣化的膜电极。解决方案：这种用于燃料电池的膜电极设置有在聚合物电解质膜的一个表面上供给含氧气体的阴极催化剂层和提供含氢气体的阳极催化剂层气体在其另一个表面上。用于燃料电池的膜电极的特征在于，在施加到其两个表面的膜和催化剂层之间的至少任一个界面上形成含有活性氧去除材料的活性氧去除层; 活性氧去除材料为活性炭或固体，活性氧除去材料为活性炭或固体酸催化剂。还提供了使用膜电极的该燃料电池。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2005019285A Fuel cell cell 审中-公开
标题翻译：燃料电池
公开(公告)号：JP2005019285A
公开(公告)日：2005-01-20
申请号：JP2003184313
申请日：2003-06-27
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： WATANABE SATORU , TSURUMAKI SHIGERU , ITO EIKI , MORIGA TAKUYA , NOJIMA SHIGERU , YAMADA TAMOTSU , SATO AKIO , KOBAYASHI TOSHIRO , YAMADA AKIHIKO , YOSHIDA HIROHISA
IPC分类号： H01M4/86 , H01M8/02 , H01M8/04 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a fuel cell cell in which an electrolyte membrane is constantly humidified even at the time of the dry condition operation of the fuel cell and which has high durability and high battery performance.
SOLUTION: This fuel cell 5 comprises an electrolyte membrane 4, an anode catalyst layer 3 formed on one side of the electrolyte membrane, a cathode catalyst layer 2 formed on the other side of the electrolyte membrane, and a water holding layer 1 which is formed between the electrolyte membrane and the cathode catalyst layer or between the electrolyte membrane and the anode catalyst layer, or between both of these, so as to contact the electrolyte membrane.
COPYRIGHT: (C)2005,JPO&NCIPI

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