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1. 发明专利

JPS62273947A SUBSTITUTED THIONAPHTHOQUINONE COMPOUND AND HERBICIDE CONTAINING SAID COMPOUND AS ACTIVE COMPONENT 失效
公开(公告)号：JPS62273947A
公开(公告)日：1987-11-28
申请号：JP11859486
申请日：1986-05-23
申请人： MITSUBISHI CHEM IND , KAWASAKI KASEI CHEMICALS
发明人： OKADA ITARU , NAKAZAWA MAKOTO , WATANABE HISAO , SUGANUMA HIROYUKI , KUSABE KOJI
IPC分类号： A01N35/06 , C07C67/00 , C07C313/00 , C07C323/30
摘要： NEW MATERIAL:The compound of formula I [R is alkyl, alkenyl, aralkyl, etc., which may be substituted with halogen, cyano, OH, etc.; W is NHR , group of formula II (R is H or alkyl, alkenyl, etc., which may be substituted with cyano, OH, etc.; R is alkyl or alkenyl; R is alkyl, benzyl, etc.), etc.]. EXAMPLE:2-(alpha-Methyl)benzylamino-3-methylthio-1,4-naphthoquinone. USE:A herbicide having excellent herbicidal effect against various weeds in plowed field or paddy field and free from phytotoxicity to crops. Useful as a selective herbicide for the field of rice, wheat, cotton, corn, etc. PREPARATION:The compound of formula I can be produced by reacting the compound of formula III with a mercaptan in a solvent such as methanol in the presence of a base (e.g. NaOH) at 0-100 deg.C for 1-10hr.

2. 发明专利

JPS62228053A SULFINYL-OR SULFONYLNAPHTHOQUINONE COMPOUND AND HERBICIDE CONTAINING SAID COMPOUND AS ACTIVE COMPONENT 失效
公开(公告)号：JPS62228053A
公开(公告)日：1987-10-06
申请号：JP9640586
申请日：1986-04-25
申请人： MITSUBISHI CHEM IND , KAWASAKI KASEI CHEMICALS
发明人： OKADA ITARU , NAKAZAWA MAKOTO , WATANABE HISAO , SUGANUMA HIROYUKI , KUSABE KOJI
IPC分类号： C07D213/36 , A01N41/10 , C07C67/00 , C07C313/00 , C07C317/36 , C07C317/40 , C07C317/44 , C07D265/30 , C07D295/10
摘要： NEW MATERIAL:The compound of formula I (X is H, halogen, nitro, amino, OH, alkyl, etc.; R is alkyl, alkenyl, alkynyl, etc., which may be substituted with halogen, cyano, OH, etc.; R and R are H or alkyl, alkynyl, alkenyl, etc., which may be substituted with halogen, cyano, OH, etc.; R and R may together with N form a heterocyclic group, etc.; n is 1 or 2). EXAMPLE:2-Methylamino-3-methylsulfinyl-1,4-naphthoquinone. USE:A herbicide exhibiting excellent herbicidal effect against a number of weeds in plowed field and paddy field without affecting adverse effect to crops. PREPARATION:The compound of formula I can be produced by reacting the compound of formula II with an oxidizing agent (e.g. m-chloroperbenzoic acid) in a solvent such as dichloromethane at -20-+100 deg.C for 1-5hr.

3. 发明专利

PT87302A 未知
公开(公告)号：PT87302A
公开(公告)日：1988-05-01
申请号：PT8730288
申请日：1988-04-22
申请人： MITSUBISHI CHEM IND
发明人： OKADA ITARU , OKUI SHUKO , TAKAHASHI YOJI , FUKUCHI TOSHIKI
IPC分类号： A01N43/30 , A01N43/56 , C07D231/14 , C07D231/16 , C07D231/38 , C07D231/40 , C07D405/12 , C07D231/00
摘要： A novel pyrazole derivative and an insecticidal or miticidal composition containing the derivative as the effective ingredient are disclosed. The pyrazole derivative of the present invention has an excellent controlling effect also against harmful insects and mites exhibiting resistance to conventional insecticides and does not disturb the ecosystem since it is less toxic and less residual.

4. 发明专利

ES2021167B3 DERIVADOS DE PIRAZOL Y COMPOSICIONES INSECTICIDAS, MITICIDAS Y FUNGICIDAS QUE LOS CONTIENEN, COMO INGREDIENTE ACTIVO 未知
公开(公告)号：ES2021167B3
公开(公告)日：1991-10-16
申请号：ES89102263
申请日：1989-02-09
申请人： MITSUBISHI CHEM IND
发明人： OKADA ITARU , SUZUKI SHIGERU , OKUI SHUKO , TAKAHASHI YOJI , FUKUCHI TOSHIKI , NAKAJIMA TETSUO
IPC分类号： A01N43/50 , C07D401/12

5. 发明专利

DE3002365A1 未知
公开(公告)号：DE3002365A1
公开(公告)日：1980-07-31
申请号：DE3002365
申请日：1980-01-23
申请人： MITSUBISHI CHEM IND
发明人： IMAHORI SEIICHI , NIWA TOSHIO , OKADA ITARU , SATO KUNINORI
IPC分类号： C09B62/09 , D06P3/66 , D06P3/85 , C09B62/08 , D06P3/84

6. 发明专利

DE3879262T2 未知
公开(公告)号：DE3879262T2
公开(公告)日：1993-09-02
申请号：DE3879262
申请日：1988-04-21
申请人： MITSUBISHI CHEM IND
发明人： OKADA ITARU , OKUI SHUKO , TAKAHASHI YOJI , FUKUCHI TOSHIKI
IPC分类号： A01N43/30 , A01N43/56 , C07D231/14 , C07D231/16 , C07D231/38 , C07D231/40 , C07D405/12
摘要： A novel pyrazole derivative and an insecticidal or miticidal composition containing the derivative as the effective ingredient are disclosed. The pyrazole derivative of the present invention has an excellent controlling effect also against harmful insects and mites exhibiting resistance to conventional insecticides and does not disturb the ecosystem since it is less toxic and less residual.

7. 发明专利

AT86979T 未知
公开(公告)号：AT86979T
公开(公告)日：1993-04-15
申请号：AT88106430
申请日：1988-04-21
申请人： MITSUBISHI CHEM IND
发明人： OKADA ITARU , OKUI SHUKO , TAKAHASHI YOJI , FUKUCHI TOSHIKI
IPC分类号： A01N43/30 , A01N43/56 , C07D231/14 , C07D231/16 , C07D231/38 , C07D231/40 , C07D405/12
摘要： A novel pyrazole derivative and an insecticidal or miticidal composition containing the derivative as the effective ingredient are disclosed. The pyrazole derivative of the present invention has an excellent controlling effect also against harmful insects and mites exhibiting resistance to conventional insecticides and does not disturb the ecosystem since it is less toxic and less residual.

8. 发明专利

DE3872808T2 未知
公开(公告)号：DE3872808T2
公开(公告)日：1993-03-04
申请号：DE3872808
申请日：1988-09-08
申请人： MITSUBISHI CHEM IND
发明人： OKADA ITARU , OKUI SHUKO , NISHIMATA MANA , TAKAHASHI YOJI , FUKUCHI TOSHIKI
IPC分类号： C07D231/54 , C07D231/56 , A01N43/56
摘要： A pyrazole derivative represented by the following formula (I): wherein R and R independently represent a hydrogen atom or a C1-C4 alkyl group; R represents a hydrogen atom, a C1-C4 alkyl group, a phenyl group or a benzyl group, which bonds to one of the nitrogen atoms of the pyrazole ring; R and R independently represent a hydrogen atom, a C1-C4 alkyl group or a phenyl group; R and R independently represent a hydrogen atom, a halogen atom, a C1-C6 alkyl group, a C3-C6 cycloalkyl group, a C1-C4 alkoxy group, a C1-C4 halogenoalkoxy group,a C1-C4 hydroxyalkoxy group, a C2-C7 alkoxyalkoxy group, a nitro group, a trifluoromethyl group, a phenyl group, a phenoxy group, a benzyloxy group, an amino group, a C1-C4 alkylamino group, a C2-C8 dialkylamino group, a cyano group, a carboxyl group, a C2-C5 alkoxycarbonyl group, a C4-C7 cycloalkoxycarbonyl group, a C3-C9 alkoxyalkoxycarbonyl group, a C2-C7 alkylaminocarbonyl group, a C3-C11 dialkylaminocarbonyl group, a piperidinocarbonyl group, a morpholinocarbonyl group, a trimethylsilyl group, a C1-C4 alkylthio group, a C1-C4 alkylsulfinyl group or a C1-C4 alkylsulfonyl group; " X represents an oxygen atom, a sulfur atom, NHO or NR wherein R represents a hydrogen atom or a C1-C4 alkyl group; Y represents an oxygen atom or a sulfur atom; m represents 1 or 2; and n represents 0 or 1, and an insecticidal or miticidal composition containing the derivative as the effective ingredient are disclosed. The pyrazole derivative of the present invention has an excellent controlling effect also against harmful insects and mites exhibiting resistance to conventional insecticides and does not disturb the ecosystem since it is less toxic and less residual.

9. 发明专利

DE3872808D1 未知
公开(公告)号：DE3872808D1
公开(公告)日：1992-08-20
申请号：DE3872808
申请日：1988-09-08
申请人： MITSUBISHI CHEM IND
发明人： OKADA ITARU , OKUI SHUKO , NISHIMATA MANA , TAKAHASHI YOJI , FUKUCHI TOSHIKI
IPC分类号： C07D231/54 , C07D231/56 , A01N43/56
摘要： A pyrazole derivative represented by the following formula (I): wherein R and R independently represent a hydrogen atom or a C1-C4 alkyl group; R represents a hydrogen atom, a C1-C4 alkyl group, a phenyl group or a benzyl group, which bonds to one of the nitrogen atoms of the pyrazole ring; R and R independently represent a hydrogen atom, a C1-C4 alkyl group or a phenyl group; R and R independently represent a hydrogen atom, a halogen atom, a C1-C6 alkyl group, a C3-C6 cycloalkyl group, a C1-C4 alkoxy group, a C1-C4 halogenoalkoxy group,a C1-C4 hydroxyalkoxy group, a C2-C7 alkoxyalkoxy group, a nitro group, a trifluoromethyl group, a phenyl group, a phenoxy group, a benzyloxy group, an amino group, a C1-C4 alkylamino group, a C2-C8 dialkylamino group, a cyano group, a carboxyl group, a C2-C5 alkoxycarbonyl group, a C4-C7 cycloalkoxycarbonyl group, a C3-C9 alkoxyalkoxycarbonyl group, a C2-C7 alkylaminocarbonyl group, a C3-C11 dialkylaminocarbonyl group, a piperidinocarbonyl group, a morpholinocarbonyl group, a trimethylsilyl group, a C1-C4 alkylthio group, a C1-C4 alkylsulfinyl group or a C1-C4 alkylsulfonyl group; " X represents an oxygen atom, a sulfur atom, NHO or NR wherein R represents a hydrogen atom or a C1-C4 alkyl group; Y represents an oxygen atom or a sulfur atom; m represents 1 or 2; and n represents 0 or 1, and an insecticidal or miticidal composition containing the derivative as the effective ingredient are disclosed. The pyrazole derivative of the present invention has an excellent controlling effect also against harmful insects and mites exhibiting resistance to conventional insecticides and does not disturb the ecosystem since it is less toxic and less residual.

10. 发明专利

BR8802011A 未知
公开(公告)号：BR8802011A
公开(公告)日：1989-11-21
申请号：BR8802011
申请日：1988-04-22
申请人： MITSUBISHI CHEM IND
发明人： OKADA ITARU , OKUI SHUKO , TAKAHSSHI YOJI , FUKUCHI TOSHIKI
IPC分类号： A01N43/30 , A01N43/56 , C07D231/14 , C07D231/16 , C07D231/38 , C07D231/40 , C07D405/12 , C07D231/12 , C07D413/12 , A01N43/84
摘要： A novel pyrazole derivative and an insecticidal or miticidal composition containing the derivative as the effective ingredient are disclosed. The pyrazole derivative of the present invention has an excellent controlling effect also against harmful insects and mites exhibiting resistance to conventional insecticides and does not disturb the ecosystem since it is less toxic and less residual.

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