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1. 发明申请

US20090306246A1 CROSSLINKED COMPOSITION COMPRISING A CORE/SHELL COPOLYMER, METHOD OF OBTAINING SAME AND USES THEREOF 审中-公开
标题翻译：包含核心/壳共聚物的交联组合物，其获得方法及其用途
公开(公告)号：US20090306246A1
公开(公告)日：2009-12-10
申请号：US12096237
申请日：2006-12-01
申请人： Laurent Gervat , Gilles Meunier , Christophe Navarro , Elisabeth Bay , Laure Mauboules
发明人： Laurent Gervat , Gilles Meunier , Christophe Navarro , Elisabeth Bay , Laure Mauboules
IPC分类号： C08L33/12
CPC分类号： C08L23/16 , A43B13/04 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , B60C2009/0021 , C08F255/02 , C08F265/04 , C08F279/02 , C08K3/06 , C08K3/22 , C08K3/36 , C08K5/0025 , C08K5/09 , C08K5/54 , C08L21/00 , C08L23/02 , C08L23/0815 , C08L23/22 , C08L51/00 , C08L51/04 , C08L51/06 , C08L61/06 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/02 , C08L2666/06
摘要： The invention relates to is a crosslinked composition containing in parts by weight: 20 to 100 parts of at least one elastomer (I), 2 to 50 parts of at least one core/shell copolymer (II), and 0 to 100 parts of at least one thermoplastic polymer (III). The invention also relates to a method of producing one such crosslinked composition, which is characterized in that it consists in: mixing an elastomer and a core/shell copolymer optionally in the presence of: a grafted polyolefin, a plasticizer, fillers and/or additives, and a suitably-selected crosslinking system, and subsequently crosslinking said mixture at a suitable temperature. In a preferred embodiment of the invention, the mixture is crosslinked at a temperature of between 150 and 320° C. The invention method be carried out in an internal mixer, or, alternately, in a twin-screw extruder or a Buss®-type co-kneader. Depending on the case, the resulting mass is calendared or extruded, cooled and subsequently granulated. The granules thus obtained are then ready to be transformed, by means of heating, into sheets, plates, extrusions, tubes or other desired products. The invention further relates to the use of one such composition in the production of ducts, pipes, tubing, couplers or similar for conveying fluids, such as the fluid transfer conduits, pipes and other elements which are used in the automobile industry in braking, cooling, steering and air-conditioning systems. The inventive crosslinked composition can also be used in the production of belts, tires, electrical cable sheaths, and shoe soles.”
摘要翻译：本发明涉及一种交联组合物，其含有重量份：20-100份至少一种弹性体（I），2-50份至少一种核/壳共聚物（II）和0-100份至少一种热塑性聚合物（III）。本发明还涉及生产一种这样的交联组合物的方法，其特征在于它包括：将弹性体和核/壳共聚物任选地在以下存在下混合：接枝聚烯烃，增塑剂，填料和/或添加剂和适当选择的交联体系，随后在合适的温度下交联所述混合物。在本发明的一个优选实施方案中，该混合物在150-320℃的温度下交联。本发明方法在内部混合器中进行，或者在双螺杆挤出机或Buss（R）型共捏合机。根据情况，将所得物料压延或挤出，冷却并随后造粒。然后将如此获得的颗粒通过加热转化成片，板，挤出物，管或其它所需产物。本发明还涉及一种这样的组合物在制造用于输送流体的管道，管道，管道，耦合器或类似物中的用途，例如用于汽车工业中的流体输送导管，管道和其它元件，用于制动，冷却，转向和空调系统。本发明的交联组合物也可用于生产带，轮胎，电缆护套和鞋底。“

2. 发明申请

US20090088526A1 COMPOSITION COMPRISING A COPOLYMER BASED ON ACRYLONITRILE AND A VINYLAROMATIC MONOMER, A COPOLYMER COMPRISING AT LEAST THREE BLOCKS AND A PARTICULATE COPOLYMER OF THE CORE-SHELL TYPE 审中-公开
标题翻译：包含基于丙烯腈和乙烯基单体的共聚物的组合物，包含至少三个嵌段的共聚物和核心类型的颗粒共聚物
公开(公告)号：US20090088526A1
公开(公告)日：2009-04-02
申请号：US12096506
申请日：2006-12-08
申请人： Laurent Gervat , Christophe Navarro , Pierre Gerard , Stephane Girois
发明人： Laurent Gervat , Christophe Navarro , Pierre Gerard , Stephane Girois
IPC分类号： C08L53/00 , C08L51/06 , C08L25/08
CPC分类号： C08L33/20 , C08L25/12 , C08L33/12 , C08L35/06 , C08L51/04 , C08L53/02 , C08L2666/24 , C08L2666/02
摘要： The invention relates to an impact-resistant transparent composition comprising a copolymer having repeat units resulting from the polymerization of acrylonitrile and of at least one vinylaromatic monomer, a particulate block copolymer and a core-shell copolymer.
摘要翻译：本发明涉及一种耐冲击透明组合物，其包含具有由丙烯腈和至少一种乙烯基芳族单体，颗粒嵌段共聚物和核 - 壳共聚物的聚合产生的重复单元的共聚物。

3. 发明申请

US20120157601A1 PROCESS FOR CORE-SHELL IMPACT MODIFIERS AND IMPACT MODIFIED THERMOPLASTIC COMPOSITION WITH ENHANCED HYDROLYTIC RESISTANCE 有权
标题翻译：核壳体冲击改性剂的改性和改性的热塑性组合物具有增强的耐水解性
公开(公告)号：US20120157601A1
公开(公告)日：2012-06-21
申请号：US13325762
申请日：2011-12-14
申请人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
发明人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
IPC分类号： C08F2/22 , C08L9/00 , C08L33/12
CPC分类号： C08F285/00 , C08F2/22 , C08F6/006 , C08F6/22 , C08F279/06 , C08L51/003 , C08L67/02 , C08L69/00 , C08F212/36 , C08F212/08 , C08F220/12
摘要： The present invention relates to a process for producing impact modifiers, impact modified thermoplastic molding compositions and in particular impact modified polycarbonate or polycarbonate/polyester blends having improved resistance to degradation. More particularly the present invention relates to a process for producing polymeric impact modifiers with a core-shell structure made by a multistage process comprising a control and adjustment if necessary of the pH value before and during the recovery step.
摘要翻译：本发明涉及一种生产抗冲改性剂，抗冲改性热塑性成型组合物的方法，特别涉及具有改进的降解抗性的抗冲改性聚碳酸酯或聚碳酸酯/聚酯共混物。更具体地说，本发明涉及一种制备具有由多级方法制成的核 - 壳结构的聚合物抗冲改性剂的方法，包括在恢复步骤之前和期间必要时控制和调节pH值。

4. 发明申请

US20120157630A1 IMPACT MODIFIED THERMOPLASTIC COMPOSITION 有权
标题翻译：冲击改性热塑性组合物
公开(公告)号：US20120157630A1
公开(公告)日：2012-06-21
申请号：US13325806
申请日：2011-12-14
申请人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin , Magali Bergeret-Richaud
发明人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin , Magali Bergeret-Richaud
IPC分类号： C08L69/00
CPC分类号： C08F279/02 , C08F6/006 , C08F6/22 , C08F279/06 , C08L51/04 , C08L67/02 , C08L69/00 , C08L2205/22 , C08F2/22
摘要： The present invention relates to thermoplastic compositions comprising as impact modifier a rubber containing graft polymer prepared by the process of emulsion polymerization and recovered by a special process controlling and adjusting the value, the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves. The present invention relates also to thermoplastic compositions comprising a polymeric impact modifier with a core-shell structure made by a multistage process and recovered by a special process controlling and adjusting the pH value comprising at least one gradient polymer the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves.
摘要翻译：本发明涉及热塑性组合物，其包含作为抗冲改性剂的橡胶，其包含通过乳液聚合方法制备的接枝聚合物，并通过控制和调节该值的特殊方法回收，热塑性组合物在成型体生产中的用途，以及模制的，身体本身。本发明还涉及热塑性组合物，其包含具有通过多阶段方法制备的核 - 壳结构的聚合抗冲改性剂，并通过控制和调节包含至少一种梯度聚合物的特定方法回收，所述梯度聚合物的使用在成型体的制造，以及模制的本体。

5. 发明申请

US20120157629A1 CORE SHELL PARTICLE MULTISTAGE POLYMER POWDER, ITS MANUFACTURING PROCESS 有权
标题翻译：核心粒子多元聚合物粉末及其制造工艺
公开(公告)号：US20120157629A1
公开(公告)日：2012-06-21
申请号：US13325749
申请日：2011-12-14
申请人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
发明人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
IPC分类号： C08L51/00 , C08F285/00
CPC分类号： C08F285/00 , C08F2/001 , C08F2/26 , C08F6/006 , C08F6/22 , C08L51/003 , C08L67/02 , C08L69/00 , C08F212/36 , C08F220/12 , C08F212/08
摘要： The present invention relates to new impact modifiers and a process for making these new impact modifiers and their use in polymeric compositions. More particularly the present invention relates to a new polymeric impact modifier with a core-shell structure made by a multistage polymerization process comprising at least one gradient polymer. The present invention relates as well to a process preparing such an impact modifier, especially its recovery process after the end of the polymerization. The present invention also relates to a thermoplastic composition comprising the new impact modifier.
摘要翻译：本发明涉及新的抗冲改性剂和制备这些新的抗冲改性剂及其在聚合物组合物中的用途的方法。更具体地说，本发明涉及具有核 - 壳结构的新的聚合物抗冲击改性剂，其通过包含至少一种梯度聚合物的多级聚合方法制成。本发明还涉及制备这种抗冲改性剂的方法，特别是其在聚合结束后的回收过程。本发明还涉及包含新的抗冲改性剂的热塑性组合物。

6. 发明申请

US20120157628A1 IMPACT MODIFIED THERMOPLASTIC COMPOSITION WITH HYDROLYTIC SENSITIVITY TO OBTAIN HIGHER FLUIDITY WHILE KEEPING HIGH IMPACT STRENGTH 审中-公开
标题翻译：具有保持高冲击强度的具有水溶性敏感性以获得更高流动性的改性热塑性组合物
公开(公告)号：US20120157628A1
公开(公告)日：2012-06-21
申请号：US13325792
申请日：2011-12-14
申请人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin , Magali Bergeret-Richaud
发明人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin , Magali Bergeret-Richaud
IPC分类号： C08F279/02 , C08L51/00
CPC分类号： C08F279/06 , C08F6/006 , C08F6/22 , C08L51/04 , C08L67/02 , C08L69/00 , C08L2205/22 , C08F2/22
摘要： The present invention relates to, amongst other things, a process for manufacturing an impact modifier, concerns impact modified thermoplastic molding compositions and in particular a process for manufacturing and recovering the impact modifiers and their use in polymeric thermoplastic compositions. More particularly the present invention relates to a polymeric impact modifier with a core-shell structure manufactured by a multistage process comprising a special recovery process so that the composition of the thermoplastic polymer containing the impact modifier has a high fluidity while keeping its high impact strength.
摘要翻译：本发明尤其涉及制造抗冲击改性剂的方法，涉及冲击改性的热塑性模塑组合物，特别涉及用于制造和回收冲击改性剂及其在聚合物热塑性组合物中的用途的方法。更具体地说，本发明涉及具有核 - 壳结构的聚合物抗冲改性剂，其通过包括特殊回收方法的多阶段方法制造，使得含有抗冲改性剂的热塑性聚合物的组成具有高流动性同时保持其高冲击强度。

7. 发明授权

US10011673B2 Impact modified thermoplastic composition 有权
公开(公告)号：US10011673B2
公开(公告)日：2018-07-03
申请号：US13325806
申请日：2011-12-14
申请人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin , Magali Bergeret-Richaud
发明人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin , Magali Bergeret-Richaud
IPC分类号： C08L51/04 , C08F279/02 , C08F6/00 , C08F6/22 , C08F279/06 , C08L67/02 , C08L69/00
CPC分类号： C08F279/02 , C08F6/006 , C08F6/22 , C08F279/06 , C08L51/04 , C08L67/02 , C08L69/00 , C08L2205/22 , C08F2/22
摘要： The present invention relates to thermoplastic compositions comprising as impact modifier a rubber containing graft polymer prepared by the process of emulsion polymerization and recovered by a special process controlling and adjusting the pH value, the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves. The present invention relates also to thermoplastic compositions comprising a polymeric impact modifier with a core-shell structure made by a multistage process and recovered by a special process controlling and adjusting the pH value comprising at least one gradient polymer the use of the thermoplastic compositions in the production of molded bodies, and to the molded, bodies themselves.

8. 发明授权

US09714314B2 Core shell particle multistage polymer powder, its manufacturing process 有权
公开(公告)号：US09714314B2
公开(公告)日：2017-07-25
申请号：US13325749
申请日：2011-12-14
申请人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
发明人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
IPC分类号： C08L51/00 , C08F285/00 , C08F2/00 , C08F2/26 , C08F6/00 , C08F6/22 , C08L67/02 , C08L69/00
CPC分类号： C08F285/00 , C08F2/001 , C08F2/26 , C08F6/006 , C08F6/22 , C08L51/003 , C08L67/02 , C08L69/00 , C08F212/36 , C08F220/12 , C08F212/08
摘要： The present invention relates to new impact modifiers and a process for making these new impact modifiers and their use in polymeric compositions. More particularly the present invention relates to a new polymeric impact modifier with a core-shell structure made by a multistage polymerization process comprising at least one gradient polymer. The present invention relates as well to a process preparing such an impact modifier, especially its recovery process after the end of the polymerization. The present invention also relates to a thermoplastic composition comprising the new impact modifier.

9. 发明授权

US09068036B2 Process for core-shell impact modifiers and impact modified thermoplastic composition with enhanced hydrolytic resistance 有权
标题翻译：核 - 壳抗冲击改性剂和具有增强的耐水解性的抗冲改性热塑性组合物的方法
公开(公告)号：US09068036B2
公开(公告)日：2015-06-30
申请号：US13325762
申请日：2011-12-14
申请人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
发明人： Christophe Navarro , Stephane Girois , Elisabeth Bay , Jean-Claude Saint-Martin
IPC分类号： C08L51/00 , C08F285/00 , C08F2/22 , C08F6/00 , C08F6/22 , C08F279/06 , C08L67/02 , C08L69/00
CPC分类号： C08F285/00 , C08F2/22 , C08F6/006 , C08F6/22 , C08F279/06 , C08L51/003 , C08L67/02 , C08L69/00 , C08F212/36 , C08F212/08 , C08F220/12
摘要： The present invention relates to a process for producing impact modifiers, impact modified thermoplastic molding compositions and in particular impact modified polycarbonate or polycarbonate/polyester blends having improved resistance to degradation. More particularly the present invention relates to a process for producing polymeric impact modifiers with a core-shell structure made by a multistage process comprising a control and adjustment if necessary of the pH value before and during the recovery step.
摘要翻译：本发明涉及一种生产抗冲改性剂，抗冲改性热塑性成型组合物的方法，特别涉及具有改进的降解抗性的抗冲改性聚碳酸酯或聚碳酸酯/聚酯共混物。更具体地说，本发明涉及一种制备具有由多级方法制成的核 - 壳结构的聚合物抗冲改性剂的方法，包括在恢复步骤之前和期间必要时控制和调节pH值。

10. 发明授权

US08183322B2 Composition containing a lactic acid homopolymer and a block copolymer 有权
标题翻译：含有乳酸均聚物和嵌段共聚物的组合物
公开(公告)号：US08183322B2
公开(公告)日：2012-05-22
申请号：US12678799
申请日：2008-08-26
申请人： Pierre Gerard , Christophe Navarro
发明人： Pierre Gerard , Christophe Navarro
IPC分类号： C08L53/00 , C08L67/00 , C08L69/00
CPC分类号： C08F293/005 , C08L53/00 , C08L2666/04 , C08L2666/14 , C08L2666/02
摘要： The present invention relates to a composition containing at least one lactic acid homopolymer and at least one block copolymer with a polydispersity index ranging from 1.5 to 5 and comprising: at least one block A that is miscible with the homopolymer and formed from monomers containing at least one methacrylate of formula CH2═C(CH3)—COOR1, and at least one block B that is immiscible with the homopolymer and formed from monomers containing at least one alkyl acrylate of formula CH2═CH—COOR2 and/or at least one methacrylate of formula CH2═C(CH3)—COOR3. The invention also relates to the use of this composition for the manufacture of medical articles, textile fibers, thermoformed plates or packaging, in particular films or bottles.
摘要翻译：本发明涉及含有至少一种乳酸均聚物和至少一种多分散指数为1.5至5的嵌段共聚物的组合物，其包含：至少一种与均聚物可混溶并由至少含有至少一种式CH 2 = C（CH 3）-COOR 1的甲基丙烯酸酯和至少一种与均聚物不混溶并由含有至少一种式CH 2 = CH-COOR 2的丙烯酸烷基酯和/或至少一种甲基丙烯酸甲酯的单体形成的嵌段B 式CH 2 = C（CH 3）-COOR 3。本发明还涉及该组合物用于制造医疗制品，纺织纤维，热成型板或包装，特别是薄膜或瓶子的用途。

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