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    • 1. 发明授权
    • Method for color image formation
    • 彩色图像形成方法
    • US5118593A
    • 1992-06-02
    • US762170
    • 1991-09-19
    • Kokichi WakiShigeo Hirano
    • Kokichi WakiShigeo Hirano
    • G03C7/30G03C7/392G03C7/413
    • G03C7/39224G03C7/413
    • A method of color image formation is disclosed, comprising imagewise exposing a color photographic light-sensitive material comprising a reflective support having provided thereon at least one light-sensitive layer containing a color coupler capable of forming a color image upon coupling with an oxidation product of an aromatic primary amine developing agent and a silver halide emulsion, and processing the exposed light-sensitive material with a color developing solution containing substantially no benzyl alcohol within a development time of 2 minutes and 30 seconds, wherein said processing is carried out in the pressence of at least one compound represented by formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each represents a hydrogen atom, a hydroxyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, an acyl group, or a sulfonyl group; or R.sup.1 and R.sup.2, or R.sup.3 and R.sup.4 together form a ring; X represents a substituted or unsubstituted lower alkylene group; and n represents an integer of from 1 to 4. Disadvantages due to use of benzyl alcohol can be eliminated, and reduction in color density noted when color development processing is conducted over a short time without using benzyl alcohol can be prevented.
    • 公开了一种彩色图像形成方法,包括成像曝光彩色照相感光材料,该彩色照相感光材料包括反射支撑体,其上设置有至少一个含有能够形成彩色图像的彩色成像器的感光层, 芳族伯胺显影剂和卤化银乳剂,并且在2分30秒的显影时间内用基本上不含苄醇的显色溶液处理曝光的感光材料,其中所述处理在压力下进行 的至少一种由式表示的化合物,其中R 1,R 2,R 3和R 4各自表示氢原子,羟基,取代或未取代的烷基,取代或未取代的烯基,取代或未取代的炔基 ,酰基或磺酰基; 或R 1和R 2,或R 3和R 4一起形成环; X表示取代或未取代的低级亚烷基; 并且n表示1至4的整数。可以防止由于使用苄醇而引起的缺点,并且可以防止在不使用苄醇的情况下在短时间内进行显色处理时注意到的色浓度的降低。
    • 2. 发明授权
    • Photothermographic material and method for forming images
    • 光热成像材料和形成图像的方法
    • US06593069B2
    • 2003-07-15
    • US09809024
    • 2001-03-16
    • Toyohisa OyaKazunobu KatohShigeo Hirano
    • Toyohisa OyaKazunobu KatohShigeo Hirano
    • G03C134
    • G03C1/49845G03C1/49827G03C7/305Y10S430/166
    • A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler compound on the same side of a support: wherein, in the formula (1), V1 to V4 each independently represent hydrogen atom or a substituent, and V5 represents a substituted or unsubstituted alkyl group, aryl group or heterocyclic group: Q1—NHNH—V6  (2) wherein, in the formula (2), Q1 represents a 5- to 7-membered unsaturated ring bonding to NHNH—V6 at a carbon atom, and V6 represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group. The photothermographic material of the present invention shows good photographic properties including sensitivity, fog and so forth, and enables control of color tone of the photothermographic material in an arbitrary wavelength region even as a monosheet type photothermographic material.
    • 一种光热成像材料,其至少包含(a)感光卤化银,(b)可还原的银盐,(c)由下式(1)或(2)表示的还原化合物,(d)粘合剂和(e) 其中在式(1)中,V1至V4各自独立地表示氢原子或取代基,V5表示取代或未取代的烷基,芳基或杂环基:其中, 在式(2)中,Q1表示在碳原子上与NHNH-V6键合的5至7元不饱和环,V 6表示氨基甲酰基,酰基,烷氧基羰基,芳氧基羰基,磺酰基 或氨磺酰基。本发明的光热敏成像材料显示出良好的照相性质,包括灵敏度,雾度等,并且即使作为单片型光热敏成像材料也能够控制光热成像材料在任意波长区域中的色调。
    • 3. 发明授权
    • Heat-developable recording material
    • 热显影记录材料
    • US06358677B1
    • 2002-03-19
    • US09528450
    • 2000-03-17
    • Masahiko TaniguchiKatsuyuki WatanabeShigeo HiranoMinoru Sakai
    • Masahiko TaniguchiKatsuyuki WatanabeShigeo HiranoMinoru Sakai
    • G03C1498
    • G03C1/49845
    • A heat-developable recording material having, at least on one side and the same side of the support, (a) reducible silver salt, (b) a reducing agent other than a compound represented by the general formula (1) below, (c) a binder, and (d) at least one compound represented by the general formula (1) below; content of the compound represented by the general formula (1) being 0.01 to 100 mol % with respect to the reducing agent: [where in the general formula (1), R1, R2, R3, X1 and X2 independently represent a hydrogen atom; halogen atom; or substituent which is bound to the benzene ring via a carbon atom, oxygen atom, nitrogen atom, sulfur atom or phosphorus atom. At least either X1 or X2 represents a group represented as —NR4R5, where R4 and R5 independently represent a group selected from a hydrogen atom, alkyl group and the like.]
    • (a)可还原银盐,(b)除了下述通式(1)表示的化合物以外的还原剂,(c)的可热显影记录材料,至少在一个侧面和同一侧上,(c) )粘合剂,和(d)至少一种由下述通式(1)表示的化合物; 通式(1)表示的化合物的含量相对于还原剂为0.01〜100摩尔%[其中,在通式(1)中,R 1,R 2,R 3,X 1和X 2独立地表示氢原子; 卤素原子; 或通过碳原子,氧原子,氮原子,硫原子或磷原子与苯环结合的取代基。 X 1或X 2中至少有一个表示为-NR 4 R 5的基团,其中R 4和R 5独立地表示选自氢原子,烷基等的基团。
    • 4. 发明授权
    • Photothermographic or thermographic image-forming material
    • 光热成像或热成像成像材料
    • US6165707A
    • 2000-12-26
    • US333271
    • 1999-06-15
    • Shigeo HiranoSatoru TodaMasahiko TaniguchiHiroyuki Suzuki
    • Shigeo HiranoSatoru TodaMasahiko TaniguchiHiroyuki Suzuki
    • G03C1/498G03C1/34
    • G03C1/49845
    • An image-forming material comprising a support and a constituent layer(s) comprising at least (a) a thermographic image-forming layer containing a reducible silver salt, a reducing agent of the reducible silver salt and a binder or (b) a photothermographic image-forming layer containing a light-sensitive silver halide as a photocatalyst, reducible silver salt, a reducing agent of the reducible silver salt and a binder, wherein the image-forming material comprises a compound represented by formula (I-1) or (II-1) in at least one constituent layer: ##STR1## wherein R represents a secondary alkyl group or a cycloalkyl group; and M.sup.1 and M.sup.2 each represents a hydrogen atom, a metal ion or an ammonium ion; ##STR2## wherein R.sup.1 represents a secondary alkyl group, a cycloalkyl group, an aryl group, or a primary alkyl group substituted with a substituent bonded via a hetero atom; and M.sup.1 and M.sup.2 each represents a hydrogen atom, a metal ion or an ammonium ion.
    • 一种成像材料,其包括载体和构成层,其至少包含(a)含有可还原银盐的热成像图像形成层,可还原银盐的还原剂和粘合剂或(b)光热敏成像 含有感光卤化银作为光催化剂的成像层,可还原银盐,可还原银盐的还原剂和粘合剂,其中成像材料包含由式(I-1)或( II-1)至少一个构成层:其中R表示仲烷基或环烷基; M1和M2各自表示氢原子,金属离子或铵离子; 其中R1表示被通过杂原子键合的取代基取代的仲烷基,环烷基,芳基或伯烷基; M1和M2各自表示氢原子,金属离子或铵离子。
    • 9. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US5397689A
    • 1995-03-14
    • US95180
    • 1993-07-23
    • Nobutaka OhkiNaoki AsanumaOsamu TakahashiShigeo Hirano
    • Nobutaka OhkiNaoki AsanumaOsamu TakahashiShigeo Hirano
    • G03C7/392G03C1/46
    • G03C7/39216
    • A silver halide photographic material is disclosed which comprises a support having thereon at least one layer containing at least one member of compounds represented by the following general formula (1) or (2): ##STR1## wherein L represents an unsubstituted alkylene group; X represents --O(C.dbd.O)R.sub.2, --O(P.dbd.O) (R.sub.2) (R.sub.3) or a halogen atom; R.sub.1 represents a substituent group; R.sub.2 and R.sub.3 each represents a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group or a substituted or unsubstituted amino group; n represents 0, 1 or 2 and when n is 2, two R.sub.1 groups may be the same or different; R.sub.4 represents an unsubstituted alkyl group having 2 to 20 carbon atoms; and R.sub.5 represents an unsubstituted alkyl group, the number of carbon atoms of which is larger by 2 than the number of carbon atoms of R.sub.4.
    • 公开了一种卤化银照相材料,其包括其上具有至少一层的载体,所述至少一层包含至少一种由以下通式(1)或(2)表示的化合物成分:(1) 其中L表示未取代的亚烷基; X表示-O(C = O)R 2,-O(P = O)(R 2)(R 3)或卤素原子; R1表示取代基; R2和R3各自表示取代或未取代的烷氧基,取代或未取代的芳氧基或取代或未取代的氨基; n表示0,1或2,当n为2时,两个R 1基可以相同或不同; R4表示未取代的碳原子数2〜20的烷基, R5表示未取代的烷基,其碳原子数比R4的碳原子数大2。
    • 10. 发明授权
    • Silver halide photographic materials
    • 卤化银照相材料
    • US5338658A
    • 1994-08-16
    • US52284
    • 1993-04-26
    • Shigeo Hirano
    • Shigeo Hirano
    • G03C1/06G03C1/485
    • G03C1/48546Y10S430/141
    • A silver halide photographic material which contains at least one compound represented by the following general formula (I) in at least one silver halide photographic emulsion layer or one hydrophilic colloid layer, whereby achieving high Dmax and low Dmin: ##STR1## wherein T, U, V, and W each represents CH or N; R.sup.1 represents a substituent group; R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represents a hydrogen atom or a substituent group, provided that at least one among the substituents of R.sup.2 to R.sup.6 represents a group to be eliminated in the form of R.sup.m --H (m=an integer from 2 to 6) under an alkaline condition; X represents a counter ion for adjusting the charge balance; n represents the number of counter ions necessary to adjust the charge balance; and further, any pair of adjacent groups among the substituents from R.sup.1 to R.sup.6 may combine with each other to form a ring.
    • 一种卤化银照相材料,其在至少一个卤化银照相乳剂层或一个亲水胶体层中含有至少一种由以下通式(I)表示的化合物,由此达到高Dmax和低Dmin:(I)其中 T,U,V和W各自表示CH或N; R1表示取代基; R2,R3,R4,R5和R6each表示氢原子或取代基,条件是R2至R6的取代基中的至少一个表示以Rm-H形式除去的基团(m = 2的整数) 至6)在碱性条件下; X表示用于调整电荷平衡的抗衡离子; n表示调整电荷平衡所需的抗衡离子数; 此外,R 1〜R 6的取代基中的任意一对相邻基团可以相互结合形成环。