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1. 发明授权

US07825159B2 Mixtures of aromatic esters for marking or tagging organic products, marker compositions comprising the same and manufacturing methods thereof 有权
标题翻译：用于标记或标记有机产品的芳族酯的混合物，包含其的标记组合物及其制备方法
公开(公告)号：US07825159B2
公开(公告)日：2010-11-02
申请号：US12000072
申请日：2007-12-07
申请人： Justin J. Frederico , Bharat Desai , Michael J. Smith , Michael P. Hinton
发明人： Justin J. Frederico , Bharat Desai , Michael J. Smith , Michael P. Hinton
IPC分类号： A01N43/08
CPC分类号： C10L1/003 , A61K31/343 , A61K2300/00
摘要： The present invention is directed to a mixture of at least two different alkylated phenolphthalein ester compounds. Specifically, the present invention is directed to a mixture of at least two different compounds of formula I: wherein R1 represents a straight chain alkyl group having 1 to 11 carbon atoms; R2 represents a hydrogen atom or a group of the formula C(O)R4 where R4 is a hydrogen atom or a straight chain alkyl group having 1 to 11 carbon atoms; X2-X5 independently represent hydrogen; X6-X13 is same or different, and represents hydrogen or a straight or branched chain alkyl group having 1 to 12 carbon atoms. It further relates to a marker composition containing said mixtures dissolved in a solvent.
摘要翻译：本发明涉及至少两种不同的烷基化酚酞化合物的混合物。具体地说，本发明涉及至少两种不同式I化合物的混合物：其中R1代表具有1至11个碳原子的直链烷基; R 2表示氢原子或式C（O）R 4的基团，其中R 4是氢原子或具有1至11个碳原子的直链烷基; X2-X5独立地表示氢; X6-X13相同或不同，表示氢或碳原子数1〜12的直链或支链烷基。它还涉及含有溶解在溶剂中的所述混合物的标记组合物。

2. 发明申请

US20080139646A1 Mixtures of aromatic esters for marking or tagging organic products, marker compositions comprising the same and manufacturing methods thereof 有权
标题翻译：用于标记或标记有机产品的芳族酯的混合物，包含其的标记组合物及其制备方法
公开(公告)号：US20080139646A1
公开(公告)日：2008-06-12
申请号：US12000072
申请日：2007-12-07
申请人： Justin J. Frederico , Bharat Desai , Michael J. Smith , Michael P. Hinton
发明人： Justin J. Frederico , Bharat Desai , Michael J. Smith , Michael P. Hinton
IPC分类号： A61K31/343
CPC分类号： C10L1/003 , A61K31/343 , A61K2300/00
摘要： The present invention is directed to a mixture of at least two different alkylated phenolphthalein ester compounds. Specifically, the present invention is directed to a mixture of at least two different compounds of formula I: wherein R1 represents a straight chain alkyl group having 1 to 11 carbon atoms; R2 represents a hydrogen atom or a group of the formula C(O)R4 where R4 is a hydrogen atom or a straight chain alkyl group having 1 to 11 carbon atoms; X2-X5 independently represent hydrogen; X6-X13 is same or different, and represents hydrogen or a straight or branched chain alkyl group having 1 to 12 carbon atoms. It further relates to a marker composition containing said mixtures dissolved in a solvent.
摘要翻译：本发明涉及至少两种不同的烷基化酚酞化合物的混合物。具体而言，本发明涉及至少两种不同式I化合物的混合物：其中R 1表示具有1至11个碳原子的直链烷基; R 2表示氢原子或式C（O）R 4的基团，其中R 4是氢原子或直链具有1至11个碳原子的烷基; X2-X5独立地表示氢; X6-X13相同或不同，表示氢或碳原子数1〜12的直链或支链烷基。它还涉及含有溶解在溶剂中的所述混合物的标记组合物。

3. 发明授权

US06514917B1 Molecular tags for organic solvent systems 有权
标题翻译：有机溶剂系统的分子标签
公开(公告)号：US06514917B1
公开(公告)日：2003-02-04
申请号：US09588501
申请日：2000-06-07
申请人： Michael J. Smith , Bharat Desai , Justin J. Frederico
发明人： Michael J. Smith , Bharat Desai , Justin J. Frederico
IPC分类号： C10M13328
CPC分类号： C10L1/003 , C09B29/0809 , C09B29/081 , C09B29/095 , C09B29/12 , C10L1/14 , C10L1/188 , C10L1/223 , C10L1/226 , C10L1/2437 , C10L1/2641 , C10M133/28 , C10M171/007 , C10N2230/20
摘要： Colorless markers for petroleum products and methods and composition for detecting them.
摘要翻译：石油产品的无色标记及其检测方法和组成

4. 发明授权

US5882358A Colored transmission fluid 失效
标题翻译：彩色传动液
公开(公告)号：US5882358A
公开(公告)日：1999-03-16
申请号：US662208
申请日：1996-06-12
申请人： Michael J. Smith , Bharat Desai
发明人： Michael J. Smith , Bharat Desai
IPC分类号： C09B1/28 , C09B1/32 , C09B67/42 , C10M133/12 , C10M133/54 , C10M171/00 , C10N30/20 , C10N40/04 , C09B67/00
CPC分类号： C10M171/007 , C10M133/12 , C10M2215/06 , C10M2215/064
摘要： Automatic transmission fluid containing a red dye stable even in long-lived transmission fluids.
摘要翻译：含有红色染料的自动变速箱液体即使在长寿命的传动液体中也稳定。

5. 发明授权

US06482651B1 Aromatic esters for marking or tagging petroleum products 有权
标题翻译：用于标记或标记石油产品的芳族酯
公开(公告)号：US06482651B1
公开(公告)日：2002-11-19
申请号：US09343467
申请日：1999-06-30
申请人： Michael J. Smith , Bharat Desai
发明人： Michael J. Smith , Bharat Desai
IPC分类号： G01N3700
CPC分类号： C10L1/003 , C07C69/017 , C07D307/88 , C09B11/08 , Y10T436/13
摘要： A compound represented by formula I is used as a marker for organic products, wherein Ar1 and Ar2 each independently represent a substituted or unsubstituted phenylene group or a substituted or unsubstituted naphthylene group; R1 represents a straight or branched chain alkyl group having 1 to 22 carbon atoms; R2 represents a hydrogen atom or a group of the formula C(O)R4 where R4 is a hydrogen atom or a straight or branched chain alkyl group having 1 to 22 carbon atoms; and R3 represents a hydrogen atom, a straight or branched chain alkyl group having 1 to 12 carbon atoms, a straight or branched chain alkoxy group having 1 to 12 carbon atoms, a hydroxyl group, or a substituted or unsubstituted phenyl group or a substituted or unsubstituted naphthyl group; and Z represents a hydrogen atom or a group of atoms that combine with Ar2 or R3 to form a lactone ring.
摘要翻译：式I表示的化合物用作有机产物的标记物，其中Ar 1和Ar 2各自独立地表示取代或未取代的亚苯基或取代或未取代的亚萘基; R1表示碳原子数1〜22的直链或支链烷基; R 2表示氢原子或式C（O）R 4的基团，其中R 4是氢原子或具有1至22个碳原子的直链或支链烷基; R 3表示氢原子，碳原子数1〜12的直链或支链烷基，碳原子数1〜12的直链或支链烷氧基，羟基或取代或未取代的苯基或取代或未取代的苯基，未取代的萘基; Z表示与Ar 2或R 3结合形成内酯环的氢原子或原子团。

6. 发明授权

US07163827B2 Aromatic esters for marking or tagging organic products 失效
标题翻译：用于标记或标记有机产品的芳族酯
公开(公告)号：US07163827B2
公开(公告)日：2007-01-16
申请号：US10288483
申请日：2002-11-06
申请人： Michael J. Smith , Bharat Desai
发明人： Michael J. Smith , Bharat Desai
IPC分类号： G01N37/00
CPC分类号： C10L1/003 , C07C69/017 , C07D307/88 , C09B11/08 , Y10T436/13
摘要： A compound represented by formula I is used as a marker for organic products. wherein Ar1 and Ar2 each independently represent a substituted or unsubstituted phenylene group or a substituted or unsubstituted naphthylene group; R1 represents a straight or branched chain alkyl group having 1 to 22 carbon atoms; R2 represents a hydrogen atom or a group of the formula C(O)R4 where R4 is a hydrogen atom or a straight or branched chain alkyl group having 1 to 22 carbon atoms; and R3 represents a hydrogen atom, a straight or branched chain alkyl group having 1 to 12 carbon atoms, a straight or branched chain alkoxy group having 1 to 12 carbon atoms, a hydroxyl group, or a substituted or unsubstituted phenyl group or a substituted or unsubstituted naphthyl group; and Z represents a hydrogen atom or a group of atoms that combine with Ar2 or R3 to form a lactone ring.
摘要翻译：由式I表示的化合物用作有机产物的标记。其中Ar 1和Ar 2各自独立地表示取代或未取代的亚苯基或取代或未取代的亚萘基; R 1表示具有1至22个碳原子的直链或支链烷基; R 2表示氢原子或式C（O）R 4的基团，其中R 4是氢原子或直链或具有1至22个碳原子的支链烷基; R 3表示氢原子，碳原子数1〜12的直链或支链烷基，碳原子数1〜12的直链或支链烷氧基，羟基或取代基或未取代的苯基或取代或未取代的萘基; Z表示与Ar 2或R 3结合的氢原子或一组原子以形成内酯环。

7. 发明授权

US6002056A Colorless petroleum markers 失效
标题翻译：无色石油标记
公开(公告)号：US6002056A
公开(公告)日：1999-12-14
申请号：US2952
申请日：1998-01-05
申请人： Michael J. Smith , Bharat Desai
发明人： Michael J. Smith , Bharat Desai
IPC分类号： C10L1/00 , C10L1/14 , C10L1/18 , C10L1/183 , C10L1/20 , C10M171/00 , C10L1/10 , C10M101/02
CPC分类号： C10L1/003 , C10L1/14 , C10L1/1855 , C10L1/20 , C10M171/007
摘要： Petroleum products are marked with a marker such as thymolphthalein or cresolphthalein. When the marked petroleum products are contacted with a developing reagent, a color develops.
摘要翻译：石油产品标有诸如百里酚酞或甲酚酞等标记物。当标记的石油产品与显影试剂接触时，会产生颜色。

8. 发明授权

US5558808A Colored transmission fluid 失效
公开(公告)号：US5558808A
公开(公告)日：1996-09-24
申请号：US474891
申请日：1995-06-07
申请人： Michael J. Smith , Bharat Desai
发明人： Michael J. Smith , Bharat Desai
IPC分类号： C09B1/28 , C09B1/32 , C09B67/42 , C10M133/12 , C10M133/54 , C10M171/00 , C10N30/20 , C10N40/04 , C10M129/16 , C10M129/20
CPC分类号： C10M171/007 , C10M133/12 , C10M2215/06 , C10M2215/064
摘要： Automatic transmission fluid containing a red dye stable even in long-lived transmission fluids.

9. 发明授权

US5858930A Liquid Benz-iso-Quinoline derivatives 失效
标题翻译：液体苯 - 异喹啉衍生物
公开(公告)号：US5858930A
公开(公告)日：1999-01-12
申请号：US866032
申请日：1997-05-30
申请人： Bharat Desai , Michael J. Smith
发明人： Bharat Desai , Michael J. Smith
IPC分类号： C07D221/14 , C09B57/08 , C10M133/38 , C10M133/40 , C10M171/00 , C10N30/20 , C10N40/30 , C09K5/00
CPC分类号： C07D221/14 , C09B57/08 , C10M133/40 , C10M171/007 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： 1,8-Naphthalimide derivatives of Formula (I) are useful as fluorescent dyes: ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of branched alkyl groups containing 7-8 carbon atoms and alkyloxyalkyl groups containing 4 to 24 carbon atoms.
摘要翻译：式（I）的1,8-萘酰亚胺衍生物可用作荧光染料：其中R 1和R 2各自独立地选自含有7-8个碳原子的支链烷基和含有4至 24个碳原子。

10. 发明授权

US5744063A Higher purity imidazoline based amphoacetate surfactants and processes for the preparation thereof 失效
标题翻译：高纯度咪唑啉基二乙酸酯表面活性剂及其制备方法
公开(公告)号：US5744063A
公开(公告)日：1998-04-28
申请号：US801313
申请日：1997-02-18
申请人： Bharat Desai , Peter Lees , Jean-Marc Ricca , David J. Tracy
发明人： Bharat Desai , Peter Lees , Jean-Marc Ricca , David J. Tracy
IPC分类号： A61K8/00 , A61K8/40 , A61K8/44 , A61K8/49 , A61Q5/00 , A61Q5/02 , A61Q19/10 , B01F17/00 , B01F17/16 , B01F17/22 , B01F17/28 , C07C233/36 , C07C233/38 , C07D233/02 , C07D233/04 , C07D233/14 , C11D1/40 , C11D1/88 , C11D3/43 , C11D7/32 , C11D7/50 , B01F17/32
CPC分类号： C11D7/5022 , A61K8/442 , A61K8/4946 , A61Q19/10 , A61Q5/02 , B01F17/0042 , B01F17/0085 , C07C233/36 , C07C233/38 , C07D233/02 , C11D1/40 , C11D1/88 , C11D3/43 , C11D7/3209 , C11D7/3218 , C11D7/5013 , C11D7/5018 , Y10S516/915
摘要： Imadazoline-based amphoacetates of higher purity, containing essentially negligible amounts of unalkylated amido amines, lower amounts of glycolic acid salts and monochloroacetate salts, superior to currently available conventional amphoacetates, are provided. This is demonstrated by their improved surface-active properties. Lower inherent irritation properties may be expected due to improved purity. The higher purity amphoacetates can be obtained via processes utilizing precise pH control during the reaction of imidazoline, or its open-chain derivatives, with alkylating agents, e.g. sodium monochloroacetate. The pH can be controlled by adding the base slowly or automatically in response to a pH metering device to maintain a constant pH, or by a series of staged additions which are calculated to maintain pH within a stated range. The reaction may also be carried out by conducting the initial hydrolysis of the imidazoline ring structure, followed by alkylation. These higher-purity amphoacetates contain essentially fully alkylated products and lower amounts of glycolic acid derivatives, even though a ratio of SMCA to substituted imidazoline, or its open-ring derivative, of less than 1.5:1.0 and close to 1.0:1.0 is used.
摘要翻译：提供了更高纯度的基于咪达唑啉的两性乙酸盐，其含有基本上可忽略量的未烷基化的酰胺胺，较低量的乙醇酸盐和一氯乙酸盐，优于现有常规的两性乙酸盐。这通过其改进的表面活性特性证明。由于纯度的提高，预期会降低固有的刺激性能。可以通过在咪唑啉或其开链衍生物与烷基化试剂反应期间利用精确的pH控制的方法获得较高纯度的两性乙酸酯，例如。一氯乙酸钠。可以通过缓慢或自动地加入碱来控制pH，以响应于pH计量装置以保持恒定的pH，或通过一系列分级添加剂来计算，以将pH保持在规定范围内。该反应也可以通过进行咪唑啉环结构的初始水解，然后进行烷基化来进行。尽管SMCA与取代的咪唑啉或其开环衍生物的比例小于1.5：1.0且接近1.0：1.0，但这些较高纯度的两性乙酸盐基本上含有完全烷基化产物和较少量的乙醇酸衍生物。

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