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    • 1. 发明授权
    • Apparatus and method for separating zirconium isotopes using balanced
ion electromigration
    • 使用平衡离子电化分离ZIRCONIUM同位素的装置和方法
    • US5183542A
    • 1993-02-02
    • US461578
    • 1990-01-05
    • John F. JackovitzRichard P. KunkleSteven H. Peterson
    • John F. JackovitzRichard P. KunkleSteven H. Peterson
    • B01D59/42G21C3/07
    • B01D59/42G21C3/07Y02E30/40
    • Both a method and apparatus for separating zirconium isotopes by balanced ion migration in a counterflowing electrolyte are disclosed herein. In the method of the invention, zirconium chloride is dissolved in a solution of HCl, and a voltage of between 2 and 50 volts is applied across the electrolyte to create a flow of zirconium ions toward the cathode, and a counterflow of chlorine ions toward the anode which is balanced such that the lighter weight isotopes of zirconium migrate toward the cathode while the heavier weight zirconium isotopes stay in the vicinity of the anode. The apparatus of the invention includes a polarizing assembly formed from a bundle of small diameter glass tubes aligned between the anode and the cathode. The internal shape of the tubes impedes kinetic agitation movement of the zirconium ions in all directions except in the direction between the anode and the cathode, thereby expediting the separation process. Glass frits are used to partition off the electrolyte in the region of both the anode and the cathode so that the isotopes which eventually accumulate in these regions may be drawn off with a minimum of fluid agitation.
    • 本文公开了通过在逆流电解质中的平衡离子迁移分离锆同位素的方法和装置。 在本发明的方法中,将氯化锆溶解在HCl溶液中,并且在电解液之间施加2至50伏的电压以产生朝向阴极的锆离子流,并且将氯离子逆向向 阳极平衡,使得较轻的锆的同位素向阴极迁移,而较重的锆同位素停留在阳极附近。 本发明的装置包括一个偏振组件,该偏振组件由一排在阳极和阴极之间排列的小直径玻璃管组成。 管的内部形状阻止锆离子在除了阳极和阴极之间的方向上的所有方向上的动力学搅拌运动,从而加速了分离过程。 使用玻璃料将阳极和阴极区域中的电解质分隔开,使得最终在这些区域中积聚的同位素可以用最少的流体搅动排出。
    • 5. 发明授权
    • Method of preparing high capacity nickel electrode powder
    • 制备高容量镍电极粉末的方法
    • US3941614A
    • 1976-03-02
    • US558110
    • 1975-03-13
    • John F. JackovitzEarl A. Pantier
    • John F. JackovitzEarl A. Pantier
    • H01M4/32H01M4/52H01M4/16
    • H01M4/32H01M4/52
    • An electrode plate is made by loading a supporting porous metallic plaque with active battery material made by: (1) hydrolyzing the reaction product of a starting material comprising an admixture of Ni oxide and effective amounts of sodium peroxide fused at temperatures between about 800.degree.C-1150.degree.C, the hydrolyzed solid reaction product containing electrochemically active Ni hydrated oxides and hydroxide forms, (2) if desirable, drying the product below about 65.degree.C, and (3) adding, at some step in the method, an amount of cobalt containing additive effective to provide about 2-12 wt% total Co in the active battery material based on Ni oxide plus Co content.
    • 电极板通过用活性电池材料装载支撑多孔金属板制成,该活性电池材料通过以下步骤制备:(1)水解包含Ni氧化物和有效量的过氧化钠的起始材料的反应产物,其在约800℃ -1150℃,含有电化学活性的Ni水合氧化物和氢氧化物形式的水解固体反应产物,(2)如果需要,将产物干燥在约65℃以下,和(3)在该方法的某个步骤中加入量 的含钴添加剂有效地提供基于Ni氧化物和Co含量的活性电池材料中的总共Co的约2-12重量%。
    • 7. 发明授权
    • Separator systems for silver-iron batteries
    • 银色电池分离器系统
    • US4804598A
    • 1989-02-14
    • US133589
    • 1987-12-14
    • John F. JackovitzHilary MoyesEdward S. Buzzelli
    • John F. JackovitzHilary MoyesEdward S. Buzzelli
    • C08J9/36H01M2/16H01M10/32
    • H01M2/1686H01M10/32H01M2/1653H01M2300/0014
    • A silver-iron battery is made comprising a case 14 and a cover 15 within which are disposed at least one silver electrode 11, at least one iron electrode 12, a separator system 13 between the electrodes and an alkaline electrolyte, where the separator system contains at least a layer of low density polyethylene, having a density of from about 0.91 g./cm.sup.3 to about 0.92 g./cm.sup.3, graft co-polymerized with an acrylic material, disposed next to the silver electrodes, and at least a layer of high density polyethylene, having a density of from about 0.95 g./cm.sup.3 to about 0.96 g./cm.sup.3, graft co-polymerized with an acrylic material, disposed next to the iron electrodes, and where a layer of cellophane can also be included next to the low density polyethylene and a middle layer of low density polyethylene and be included between the cellophane and the high density polyethylene.
    • 制成银 - 铁电池,其包括壳体14和盖15,在该壳体中设置有至少一个银电极11,至少一个铁电极12,电极之间的隔板系统13和碱性电解质,其中分离器系统包含 至少一层低密度聚乙烯,其密度为约0.91g / cm 3至约0.92g / cm 3,与布置在银电极旁边的丙烯酸材料接枝共聚,以及至少一层 密度为约0.95g / cm 3至约0.96g / cm 3的高密度聚乙烯,与邻近铁电极设置的丙烯酸材料接枝共聚,下面还可以包含玻璃纸层 到低密度聚乙烯和低密度聚乙烯的中间层,并被包括在玻璃纸和高密度聚乙烯之间。