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    • 2. 发明授权
    • 2,6,6-Trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols and
-1,3-cyclohexadiene-1-methanols and organoleptic uses thereof
    • 2,6,6-三甲基-α-(异)丙烯-1-环己烯-1-甲醇和1,3-环己二烯-1-甲醇及其感官用途
    • US4278098A
    • 1981-07-14
    • US119858
    • 1980-02-08
    • Richard A. WilsonWilliam L. SchreiberBraja D. MookherjeeJacob KiwalaJoaquin F. VinalsManfred H. VockGilbert StorkFrederick L. Schmitt
    • Richard A. WilsonWilliam L. SchreiberBraja D. MookherjeeJacob KiwalaJoaquin F. VinalsManfred H. VockGilbert StorkFrederick L. Schmitt
    • A24B15/30A24B15/34C07C29/09C07C29/40C07C29/68C07C33/14C11B9/00A24B3/12A24B15/36
    • C11B9/0034A24B15/34C07C29/09C07C29/40C07C29/68C07C33/14C07C403/08C07B2200/09C07C2101/16
    • Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.Addition of one or more of the 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols or -1,3-cyclohexadiene-1-methanols of our invention to consumable materials is indicated to produce:A. In foodstuffs, chewing gums, toothpastes and medicinal products, sweet, camphoraceous, damascenone, raspberry-like, raspberry juice-like, rosey, woody/ionone-like, oriental, tobacco-like, tea-like, grape-like, fruity and ionone-like aromas and flavor notes;B. In perfumes, colognes and perfumed articles, leathery, hay, woody, mustard, minty, spicey (clove) and pulegone-like aromas and hay/tobacco and honey ionone-like topnotes with safronal-like nuances; andC. In tobaccos and tobacco flavors, a sweet-musty, hay-tobacco-like, fruity-raspberry, ionone-like aroma prior to smoking and a fruity tobacco-like, Virginia tobacco-like aroma on smoking both in the main stream and in the side stream.
    • 描述了用于食品,口香糖,牙膏和药用产品风味和香气,吸烟烟草风味和香气以及香料和香料制品香气增强,增强和赋予组合物的方法和组合物; 以及2,6,6-三甲基-α-(异)丙烯基-1-环己烯-1-甲醇的食品,口香糖,牙膏,药用产品,吸烟烟草,香料和香料制品香气和/或调味材料,以及 -1,3-环己二烯-1-甲醇衍生物或其一般结构定义的其几何或立体异构体中的一种或多种:其中R 1,R 2或R 3中的一个为甲基,R 1,R 2和R 3中的另外两个为 表示氢; 虚线是碳 - 碳双键或碳 - 碳单键; 条件是当R1是氢时,虚线是碳 - 碳双键。 将本发明的一种或多种2,6,6-三甲基-α-(异)丙烯-1-环己烯-1-甲醇或-1,3-环己二烯-1-甲醇添加到消耗材料中被指示产生 :A.在食品,口香糖,牙膏和药用产品中,甜,樟脑,大马士革,覆盆子样,覆盆子汁,玫瑰,木/紫罗兰酮样,东方,烟草状,茶状,葡萄状 ,水果和紫罗兰酮样香气和风味香气; B.香水,古龙水和香水制品,革质,干草,木质,芥末,小茴香,香料(丁香)和香菇样香气和干草/烟草和蜂蜜类似紫罗兰酮的顶峰,具有丰富的细微差别; 在烟草和烟草香料中,在吸烟之前是一种甜味,干草烟样,果香 - 覆盆子,类胡萝卜素的香气,并且在主流中吸烟时具有类似烟草般的弗吉尼亚烟草样香气 并在旁边的流。
    • 6. 发明授权
    • 5-Isopropyl-3-nonene-2,8-dione as flavorant and as a flavor enhancer in
conjunction with smoking tobacco and smoking tobacco articles
    • 5-异丙基-3-壬烯-2,8-二酮作为调味剂和作为增味剂与吸烟烟草和烟草制品结合
    • US4210158A
    • 1980-07-01
    • US973398
    • 1978-12-26
    • Joaquin F. VinalsJacob KiwalaRichard A. WilsonBraja D. Mookherjee
    • Joaquin F. VinalsJacob KiwalaRichard A. WilsonBraja D. Mookherjee
    • A24B15/32A24B3/12
    • A24B15/32
    • Described is the use of cis and/or trans isomers of 5-isopropyl-3-nonene-2,8-dione as flavorants or as flavor enhancers in conjunction with smoking tobacco and smoking tobacco articles and mixtures of same and optical isomers of same in smoking tobaccos, smoking tobacco flavors, substitute smoking tobaccos and substitute smoking tobacco flavors in aroma imparting, enhancing or augmenting compositions whereby, prior to smoking, hay-like notes, bready notes and solanone-like notes with burley tobacco-like aromas and cocoa-like nuances are imparted, enhanced or augmented and, on smoking, burley and cocoa-like notes as well as more body and mouthfeel as well as natural tobacco taste and smoke impact are imparted to smoking tobaccos, smoking tobacco flavors and smoking tobacco articles as well as substitute smoking tobaccos, substitute smoking tobacco flavors and substitute smoking tobacco articles.
    • 描述了5-异丙基-3-壬烯-2,8-二酮的顺式和/或反式异构体作为调味剂或作为增味剂与吸烟烟草和烟草制品及其相同的混合物和其相同的光学异构体的使用 吸烟烟草,吸烟烟草味道,替代烟草烟草和替代吸烟烟草香料赋予香气,增强或增加组合物,从而在吸烟之前,类似干草样的笔记,已经是笔记和具有白肋烟烟草样香味的椰子酮样香料, 传染,增强或增强的细微差别,以及吸烟,白肋烟和可可样笔记以及更多的身体和口感以及天然烟草味道和烟雾的影响,还可以吸烟烟草,吸烟烟草味和烟草制品 作为替代烟草烟草,替代吸烟烟草香精和替代吸烟烟草制品。
    • 9. 发明授权
    • 2,6,6-Trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols and
-1,3-cyclohexadiene-1-methanols and organoleptic uses thereof
    • 2,6,6-三甲基-α-(异)丙烯-1-环己烯-1-甲醇和1,3-环己二烯-1-甲醇及其感官用途
    • US4243823A
    • 1981-01-06
    • US39361
    • 1979-05-15
    • Richard A. WilsonWilliam L. SchreiberBraja D. MookherjeeJacob KiwalaJoaquin F. VinalsManfred H. VockGilbert StorkFrederick L. Schmitt
    • Richard A. WilsonWilliam L. SchreiberBraja D. MookherjeeJacob KiwalaJoaquin F. VinalsManfred H. VockGilbert StorkFrederick L. Schmitt
    • C07C29/09C07C29/40C07C29/68C07C33/14C07C403/00C11B9/00
    • C11B9/0034C07C29/09C07C29/40C07C29/68C07C33/14C07C403/08C07C2101/16
    • Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.Addition of one or more of the 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols or -1,3-cyclohexadiene-1-methanols of our invention to consumable materials is indicated to produce:A. In foodstuffs, chewing gums, toothpastes and medicinal products, sweet, camphoraceous, damascenone, raspberry-like, raspberry juice-like, rosey, woody/ionone-like, oriental, tobacco-like, tea-like, grape-like, fruity and ionone-like aromas and flavor notes;B. In perfumes, colognes and perfumed articles, leathery, hay, woody, mustard, minty, spicey (clove) and pulegone-like aromas and hay/tobacco and honey ionone-like topnotes with safronal-like nuances; andC. In tobaccos and tobacco flavors, a sweet-musty, hay-tobacco-like, fruity-raspberry, ionone-like aroma prior to smoking and a fruity tobacco-like, Virgina tobacco-like aroma on smoking both in the main stream and in the side stream.
    • 描述了用于食品,口香糖,牙膏和药用产品风味和香气,吸烟烟草风味和香气以及香料和香料制品香气增强,增强和赋予组合物的方法和组合物; 以及2,6,6-三甲基-α-(异)丙烯基-1-环己烯-1-甲醇的食品,口香糖,牙膏,药用产品,吸烟烟草,香料和香料制品香气和/或调味材料,以及 -1,3-环己二烯-1-甲醇衍生物或其一般结构定义的其几何或立体异构体中的一种或多种:其中R 1,R 2或R 3中的一个为甲基,R 1,R 2和R 3中的另外两个为 表示氢; 虚线是碳 - 碳双键或碳 - 碳单键; 条件是当R1是氢时,虚线是碳 - 碳双键。 将本发明的一种或多种2,6,6-三甲基-α-(异)丙烯-1-环己烯-1-甲醇或-1,3-环己二烯-1-甲醇添加到消耗材料中被指示产生 :A.在食品,口香糖,牙膏和药用产品中,甜,樟脑,大马士革,覆盆子样,覆盆子汁,玫瑰,木/紫罗兰酮样,东方,烟草状,茶状,葡萄状 ,水果和紫罗兰酮样香气和风味香气; B.香水,古龙水和香水制品,革质,干草,木质,芥末,小茴香,香料(丁香)和香菇样香气和干草/烟草和蜂蜜类似紫罗兰酮的顶峰,具有惊人的细微差别; 在烟草和烟草香料中,在吸烟之前是一种甜味,干草烟样,果香 - 覆盆子,类胡萝卜素的香味,并且在主流中吸烟时具有果香烟样,维吉娜烟草样香气 并在旁边的流。