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    • 9. 发明公开
    • Ferroelectric liquid crystals
    • FerroelektrischeFlüssigkristalle。
    • EP0390759A1
    • 1990-10-03
    • EP90850094.5
    • 1990-03-05
    • International Business Machines Corporation
    • Betterton, Kathleen MaryHinsberg, William DinanNguyen, Huu TinhTang, Wing TsangTwieg, Robert James
    • C07C327/32C09K19/28
    • C09K19/28C07C327/32C09K19/322
    • Disclosed are compounds of the general formula:
      R-O-Ar-COS-Ph-COO-R′
      characterized by the presence of the thioester (-COS-) core and wherein R is an alkyl group with typically 8 to 16 carbon atoms, Ar is a substituted aromatic core group such as 1,4-­benzene, 2,6-naphthalene, 4,4′-biphenyl, or 4,4′-­diphenylethane, and R′ is a chiral branched alkyl group such as the 1-substituted cases 1-methylpropyl through 1-methyl­octyl or 2-substituted case such as 2-methylbutyl. These materials or their mixtures possess ferroelectric phases and as such are of interest for electro-optical applications. In certain cases specific materials are of particular interest due to the existence of stable ferrorelectric phases near room temperature with large polarization density and fast electro-­optic response.
    • 公开了以下通式的化合物:RO-Ar-COS-Ph-COO-R min,其特征在于存在硫酯(-COS-)核,其中R是具有通常8至16个碳原子的烷基,Ar是 取代的芳族核心基团如1,4-苯,2,6-萘,4,4min-联苯或4,4min-二苯基乙烷,R min是手性支链烷基,例如1-取代的例子 通过1-甲基辛基或2-取代的例如2-甲基丁基的1-甲基丙基。 这些材料或其混合物具有铁电相,因此对于电光学应用是令人感兴趣的。 在某些情况下,由于在室温附近存在稳定的铁电相,具有大的极化密度和快速的电光响应,特定材料是特别感兴趣的。