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1. 发明授权

US5360563A Trisamidodithionodiphospates 失效
标题翻译：三氨基二硫代磷酸酯
公开(公告)号：US5360563A
公开(公告)日：1994-11-01
申请号：US68369
申请日：1993-05-27
申请人： Horst Zinke , Rolf Schumacher
发明人： Horst Zinke , Rolf Schumacher
IPC分类号： C07F9/24 , C07F9/22 , C07F9/572 , C07F9/59 , C07F9/6533 , C10M137/16 , C10N30/06 , C10N40/08 , C10N40/25
CPC分类号： C07F9/6533 , C07F9/22 , C07F9/5721 , C10M137/16 , C10M2223/047 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106
摘要： There are disclosed compounds of formulae I and Ia ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.13 alkyl which may be interrupted by oxygen, C.sub.5 -C.sub.6 cycloalkyl or, together with the linking N-atom, are a group of formula ##STR2## R is hydrogen or methyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.13 alkyl, andR.sub.4 and R.sub.5 are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl which may be interrupted by oxygen, C.sub.5 -C.sub.6 cycloalkyl or, together with the linking N-atom, are a group of formula ##STR3## withe proviso that R.sub.3, R.sub.4 and R.sub.5 are not simultaneously hydrogen and HNR.sub.1 R.sub.2 are not identical with NR.sub.3 R.sub.4 R.sub.5.The compounds are suitable for use as lubricant additives.
摘要翻译：公开了式I和Ia的化合物（Ia）其中R 1和R 2各自独立于可被氧，C 5 -C 6环烷基间隔的另一个C 1 -C 13烷基，或者与连接 N原子是式的基团R是氢或甲基，R 3是氢或C 1 -C 13烷基，R 4和R 5各自独立地是氢，可被氧中断的C 1 -C 18烷基， C 6环烷基或与连接的N-原子一起是式（Ia）的基团，条件是R3，R4和R5不同时为氢，且HNR1R2与NR3R4R5不相同。该化合物适合用作润滑剂添加剂。

2. 发明授权

US5167844A Lubricant formulations 失效
标题翻译：润滑剂配方
公开(公告)号：US5167844A
公开(公告)日：1992-12-01
申请号：US606401
申请日：1990-10-31
申请人： Rolf Schumacher , Horst Zinke
发明人： Rolf Schumacher , Horst Zinke
IPC分类号： C10M141/10 , C10N10/02 , C10N30/10 , C10N40/25
CPC分类号： C10M141/10 , C10M2207/023 , C10M2207/024 , C10M2207/026 , C10M2207/027 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2215/00 , C10M2215/06 , C10M2215/062 , C10M2215/064 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/084 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/106 , C10M2219/108 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/045 , C10N2210/01
摘要： Formulation containing A) a lubricant and a mixture of B) for example, at least one of the compounds O,O-bis-2-ethylhexylsodium dithiophosphate, O,O-bis-2-ethylhexylsodium thionophosphate, O,O-bis-2-methylpropylsodium dithiophosphate, O,O-bis-nonylphenylsodium dithiophosphate or S-[O,O-bis-2-ethylhexylthiophosphoryl]-potassium thioglycolate, C) at least one compound from the series of the aromatic amines, for example the diphenylamines or phenothiazines, and D) at least one compound from the series of the cyclic sterically hindered amines, the acyclic sterically hindered amines and the phenols of the formula ##STR1## wherein R.sup.4, R.sup.5 and A are, for example, alkyl radicals. Such lubricant formulations have a high degree of stability towards oxidative degradation.
摘要翻译：包含A）润滑剂和B）的混合物的配方，例如，至少一种化合物O，O-双-2-乙基己基二硫代磷酸钠，O，O-双-2-乙基己基硫代磷酸钠，O，O-双-2 二硫代磷酸二甲基丙基酯，二硫代磷酸O，O-双壬基苯基二硫代磷酸酯或S- [O，O-双-2-乙基己基硫代磷酰基] - 巯基乙酸钾，C）至少一种来自一系列芳族胺的化合物，例如二苯胺或吩噻嗪，和D）来自一系列环状空间位阻胺，无环位阻胺和式“IMAGE”的酚的至少一种化合物，其中R 4，R 5和A是例如烷基。这种润滑剂配方对氧化降解具有高度的稳定性。

3. 发明授权

US4917809A High-temperature lubricants 失效
标题翻译：高温润滑剂
公开(公告)号：US4917809A
公开(公告)日：1990-04-17
申请号：US115287
申请日：1987-11-02
申请人： Horst Zinke , Rolf Schumacher
发明人： Horst Zinke , Rolf Schumacher
IPC分类号： C10M141/10 , C10M169/04 , C10N10/04 , C10N30/06 , C10N40/00 , C10N40/08 , C10N40/25
CPC分类号： C10M141/10 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2219/108 , C10M2223/02 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/043 , C10M2223/045 , C10M2223/047 , C10M2223/049 , C10M2223/10 , C10N2210/02 , C10N2240/08
摘要： A composition comprising(a) one or more lubricants or hydraulic based on mineral oil or synthetic oils and(b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of(1) at least one compound of the formula I or II ##STR1## in which Y, Z, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 as well as a are as defined in patent claim 1 and(2) at least one compound of the formulae III or IV ##STR2## in which X, X.sup.1, X.sup.2, R.sup.11, R.sup.12, m, n, n*, k, b and M are as defined in patent claim 1.
摘要翻译：一种组合物，其包含（a）一种或多种润滑剂或基于矿物油或合成油的水力，和（b）相对于润滑剂组合物或液压油组合物的总重量为0.05至5重量％的（1 ）至少一种式I或II的化合物，其中Y，Z，R 1，R 2，R 3，R 4，R 5，R 6和R 7以及a如权利要求1中所定义，（2）至少一种式III或IV的化合物，其中X，X1，X2，R11，R12，m，n，n *，k，b和M如专利中所定义权利要求1。

4. 发明授权

US5362419A Dithiophosphoric acid derivatives as lubricant additives 失效
标题翻译：二硫代磷酸衍生物作为润滑剂添加剂
公开(公告)号：US5362419A
公开(公告)日：1994-11-08
申请号：US68375
申请日：1993-05-27
申请人： Horst Zinke , Rolf Schumacher
发明人： Horst Zinke , Rolf Schumacher
IPC分类号： C07F9/17 , C07F9/165 , C07F9/177 , C07F9/18 , C07F9/655 , C07F9/6574 , C10M137/10 , C10M167/00 , C10N30/06 , C10N40/08 , C10N40/20 , C10N40/25
CPC分类号： C10M167/00 , C07F9/1651 , C07F9/18 , C07F9/6551 , C10M137/105 , C10M2223/047 , C10M2225/00 , C10M2225/02 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106
摘要： There are disclosed compounds of formula I ##STR1## R.sub.1 and R.sub.2 are each independently of the other C.sub.3 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.5 -C.sub.6 cycloalkylmethyl, C.sub.9 -C.sub.10 bicycloalkylmethyl, C.sub.9 -C.sub.10 tricycloalkylmethyl, phenyl, C.sub.7 -C.sub.6 alkylphenyl or, taken together, are ##STR2## R.sub.3 is hydrogen or methyl, A is ##STR3## R.sub.4 is hydrogen or C.sub.1 -C.sub.6 alkyl, and R.sub.5 is a 5- or 6-membered saturated heterocyclic ring,R.sub.6 is hydrogen or methyl,n is an integer from 1 to 11 and m is an integer from 0 to 4.These compounds are particularly suitable for use as additives for lubricant compositions, hydraulic fluids and machining fluids.
摘要翻译：公开了式I的化合物（I）R 1和R 2各自独立地为C 3 -C 18烷基，C 5 -C 12环烷基，C 5 -C 6环烷基甲基，C 9 -C 10二环烷基甲基，C 9 -C 10三环烷基甲基，苯基，C 7 -C 6烷基苯基或取代一起，R 3是氢或甲基，A是CH 2 R 5或CH 2 [CH（OH）] mCH 2 OH，R 4是氢或C 1 -C 6烷基，R 5是5或6元饱和杂环， R6为氢或甲基，n为1〜11的整数，m为0〜4的整数。这些化合物特别适合用作润滑剂组合物，液压油和机械液的添加剂。

5. 发明授权

US06380139B1 Bisdithiophosphoric acid derivatives as lubricant additives 失效
标题翻译：二硫代磷酸衍生物作为润滑剂添加剂
公开(公告)号：US06380139B1
公开(公告)日：2002-04-30
申请号：US08451378
申请日：1995-05-26
申请人： Horst Zinke , Rolf Schumacher
发明人： Horst Zinke , Rolf Schumacher
IPC分类号： C10M13710
CPC分类号： C10M167/00 , C07F9/1651 , C10M137/105 , C10M2201/02 , C10M2223/047 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106
摘要： There are disclosed compounds of formula I wherein R1 and R2 are each independently of the other C3-C18alkyl, C5-C12cycloalkyl, C5-C6cycloalkylmethyl, C9-C10bicycloalkylmethyl, C9-C10tricycloalkylmethyl, phenyl, C7-C24alkylphenyl or, taken together, are R3 is C2-C18alkylene which is interrupted by —O—, —S—, or —NR4—, or is a group of formula R4 is hydrogen, C1-C18alkyl, phenyl-C1-C4alkyl, phenyl or C1-C6alkyl-substituted phenyl, R5 is hydrogen or methyl. These compounds are particularly suitable for use as additives for lubricant compositions, hydraulic fluids and machining fluids.
摘要翻译：公开了式I的化合物，其中R 1和R 2各自独立地为C 3 -C 18烷基，C 5 -C 12环烷基，C 5 -C 6环烷基甲基，C 9 -C 10二环烷基甲基，C 9 -C 10三环烷基甲基，苯基，C 7 -C 24烷基苯基或一起为R 3为C 2 -C 18亚烷基其被-O - ， - S-或-NR 4 - 中断，或者是式R 4的基团是氢，C 1 -C 18烷基，苯基-C 1 -C 4烷基，苯基或C 1 -C 6烷基取代的苯基，R 5是氢或甲基这些化合物特别适合用作润滑剂组合物，液压油和机械流体的添加剂。

6. 发明授权

US4544492A Lubricant compositions 失效
标题翻译：润滑剂组合物
公开(公告)号：US4544492A
公开(公告)日：1985-10-01
申请号：US605947
申请日：1984-05-01
申请人： Horst Zinke , Rolf Schumacher
发明人： Horst Zinke , Rolf Schumacher
IPC分类号： C07F9/165 , C07F9/6533 , C10M137/10 , C10N30/06 , C10M1/48
CPC分类号： C10M137/105 , C07F9/1651 , C07F9/6533 , C10M2223/047
摘要： Lubricant compositions containing (a) a mineral and/or synthetic base oil and (b) at least one compound of the formula I ##STR1## wherein a is 0 or 1, b is 1 to 6, R is H or alkoxycarbonyl, R.sup.1 and R.sup.2 are independently alkyl, cycloalkyl, aryl, aralkyl or are together substituted alkylene and X is hydroxyl, alkoxy, aryloxy, amino, substituted amino or the residue of a polyol, are described.
摘要翻译：含有（a）矿物和/或合成基础油的润滑剂组合物和（b）至少一种式I（I）化合物，其中a为0或1，b为1至6，R为H或烷氧基羰基描述了R1和R2独立地是烷基，环烷基，芳基，芳烷基或共同取代的亚烷基，X是羟基，烷氧基，芳氧基，氨基，取代的氨基或多元醇的残基。

7. 发明授权

US06463787B1 Mounting for a quartz crystal 失效
标题翻译：安装石英晶体
公开(公告)号：US06463787B1
公开(公告)日：2002-10-15
申请号：US09528935
申请日：2000-03-20
申请人： Rolf Schumacher , Mathias Wünsche
发明人： Rolf Schumacher , Mathias Wünsche
IPC分类号： H01L4108
CPC分类号： G01N29/036 , G01N2291/0256
摘要： In order to achieve reproducible vibration excitation of a quartz crystal even under the technical conditions which prevail when it is used for monitoring electroplating baths, a mounting for the quartz crystal 7 is proposed. The mounting for the quartz crystal 7 has two holding elements 3, 6, 14 detachably connected to one another as a form-fit, and at least two contact elements 5, 9 on the holding elements 3, 6, 14 brought into electrical contact with the contacting surfaces 32 of the quartz crystal 7. The quartz crystal 7 is fitted with the holding elements 3, 6, 14 and/or the contact elements 5, 9 at least one of the contact elements 9 being configured as a resilient body. The at least one resilient contact element 9 has an end face 34, 134 for electrically contacting the quartz crystal 7, the size of which face corresponds roughly to the size of the quartz crystal 7.
摘要翻译：即使在用于监测电镀槽的技术条件下，为了实现石英晶体的可再生振动激励，提出了一种用于石英晶体7的安装。用于石英晶体7的安装件具有两个彼此可拆卸地连接的保持元件6,6,14，并且保持元件3,6,14上的至少两个接触元件5,9与电极石英晶体7的接触表面32.石英晶体7与保持元件3,6,14和/或接触元件5,9配合，至少一个接触元件9构造为弹性体。至少一个弹性接触元件9具有用于电接触石英晶体7的端面34,134，其表面的大小大致对应于石英晶体7的尺寸。

8. 发明授权

US4778612A Boric acid complexes 失效
标题翻译：硼酸络合物
公开(公告)号：US4778612A
公开(公告)日：1988-10-18
申请号：US921921
申请日：1986-10-22
申请人： Hermann O. Wirth , Rolf Schumacher , Klaus Muller
发明人： Hermann O. Wirth , Rolf Schumacher , Klaus Muller
IPC分类号： C07F5/02 , C07F5/04 , C10M139/00 , C10N10/02 , C10N10/04 , C10N10/06 , C10N10/08 , C10N10/10 , C10N10/12 , C10N10/14 , C10N10/16 , C10N30/06 , C10N40/08 , C10N40/25 , C10M105/78
CPC分类号： C07F5/04 , C10M139/00 , C10M2223/045 , C10M2227/062 , C10N2210/02 , C10N2240/08
摘要： Compounds of formula I ##STR1## wherein R and R.sup.1 are identical or different and are a radical of the formula ##STR2## where R.sup.2, R.sup.3 and R.sup.4 are each independently C.sub.1 -C.sub.18 alkyl and together contain not more than 22 carbon atoms, and R.sup.3 and R.sup.4 are also hydrogen, or wherein R and R.sup.1 are C.sub.5 -C.sub.6 cycloalkyl, unsubstituted or C.sub.1 -C.sub.4 alkyl-substituted phenyl, or naphthyl, C.sub.7 -C.sub.14 aralyl, furfuryl or thienyl, and wherein Y is --S--, --O--, --NH--, --N(C.sub.1 -C.sub.12 alkyl)--, --CH.sub.2 --, --CH(C.sub.1 -C.sub.12 alkyl)-- or --C(C.sub.1 -C.sub.12 alkyl).sub.2 -- and X.sup..sym. is 1 equivalent of a metallic cation selected from the group consisting of Li.sup..sym., Na.sup..sym., K.sup..sym., Mg.sup.2.sym., Ca.sup.2.sym., Ba.sup.2.sym., Zn.sup.2.sym., Mn.sup.2.sym., Ni.sup.2.sym., Fe.sup.3.sym., Fe.sup.2.sym., Co.sup.2.sym., Cu.sup.2.sym., Al.sup.3.sym., Cr.sup.3.sym., VO.sup. 3.sym., ZrO.sup.2.sym., MoO.sub.2.sup.2.sym. and TiO.sup.2.sym., are suitable as additives for lubricants and hydraulic oils and bring about an improvement in the extreme-pressure properties and in the anti-wear properties.
摘要翻译：式I的化合物其中R和R 1相同或不同并且是下式的基团：其中R 2，R 3和R 4各自独立地为C 1 -C 18烷基并且一起含有不超过22个碳原子， R 3和R 4也是氢，或其中R和R 1是C 5 -C 6环烷基，未取代的或C 1 -C 4烷基取代的苯基或萘基，C 7 -C 14芳甲酰基，糠基或噻吩基，其中Y是-S-，-O-， -NH-，-N（C 1 -C 12烷基） - ， - CH 2 - ， - CH（C 1 -C 12烷基） - 或-C（C 1 -C 12烷基）2-和X（+）是1当量的金属阳离子，由Li（+），Na（+），K（+），Mg2（+），Ca2（+），Ba2（+），Zn2（+），Mn2（+），Ni2（+），Fe3 +），Fe2（+），Co2（+），Cu2（+），Al3（+），Cr3（+），VO3（+），ZrO2（+），MoO22（+）和TiO2（+）适用于润滑剂和液压油的添加剂，并且可以改善极压性能和抗磨损性能。

9. 发明授权

US5311645A Can distribution apparatus 失效
标题翻译：配电设备
公开(公告)号：US5311645A
公开(公告)日：1994-05-17
申请号：US945026
申请日：1992-09-14
申请人： Hans-Werner Schwalm , Rolf Schumacher , Reiner Reising
发明人： Hans-Werner Schwalm , Rolf Schumacher , Reiner Reising
IPC分类号： D01H9/18 , D01H11/00 , D04H11/00 , D01H13/02
CPC分类号： D01H9/185 , D01H11/005
摘要： A can distribution apparatus includes an assembly forming an endless path interconnecting a plurality of distribution locations for support movement of cans to and between distribution locations and an assembly for simultaneously advancing cans of varying degrees of fullness and readiness to a textile machine. The can distribution locations include a textile machine delivery location, a can return location, a full can supply location, and a can receipt location. The advancement of each can is effected simultaneous with the advancement of the other cans in the endless path independent of whether the can is empty, partially loaded or contains a full load and whether the full load is prepared for delivery or not. A detector detects the sliver fullness of each can on the endless path and signals this information to a control device which controls the distribution of cans to the various can distribution locations. A sliver end preparation device prepares full cans for delivery to a textile machine and a detector detects the presence or absence of an end in a preferred position. The control device prevents the distribution of cans having a full load of unprepared sliver to a textile machine in response to a signal from the detector.
摘要翻译：罐分配装置包括组件，该组件形成连接多个分配位置的环形路径，用于支撑罐和分配位置之间的运动，以及用于同时推进不同程度的丰满度和对纺织机械的准备的组件的组件。罐头分配位置包括纺织机械送货位置，可以返回位置，完全可以供应位置和可以接收位置。每个罐的前进可以随着其他罐在无尽路径中的前进而同时进行，而不管罐是空的，部分装载的还是包含满负荷，以及是否准备供货。检测器检测无限路径上每个罐的条子丰满度，并将该信息发送到控制装置，该控制装置控制罐分配到各种罐分配位置。纱条末端准备装置准备全罐以送到纺织机器，检测器检测在优选位置中是否存在末端。响应于来自检测器的信号，控制装置防止具有无准备条纹的满载的罐的分配到纺织机器。

10. 发明授权

US5091131A Method of attaching small plastic parts securely on compression molded parts 失效
标题翻译：在压缩成型件上安装小型塑料零件的方法
公开(公告)号：US5091131A
公开(公告)日：1992-02-25
申请号：US584922
申请日：1990-09-18
申请人： Rolf Schumacher , Ewald Eissler
发明人： Rolf Schumacher , Ewald Eissler
IPC分类号： B29C43/32 , B29C45/14
CPC分类号： B29C45/14778 , B29C45/14221 , B29C45/14344 , B29L2031/727
摘要： A method attaches small plastic parts securely in a defined position on compression molded parts consisting substantially of bonded or synthetic resin bound natural fibers or chips. The parts are compression molded into the desired shape in a compression mold from a preformed, loose layer of a mixture of at least one of natural fibers and chips and of binder introduced into the compression mold, while undergoing a setting reaction of the binder and a volume reduction of the layer. During the compression molding operation, at least one clearance or thin portion, smaller than the small plastic part, is formed in the wall of the compression molded part at the fastening point of the small plastic part on the compression molded part. Thereafter, a direct form-fitting injection molding of the small plastic part or parts onto the wall of the compression molded part at the fastening point is carried out. The finished compression molded part is placed in a defined position with the fastening point in a split injection mold for molding on the small plastic part, each mold half of the injection mold coming snugly into contact on the near side and the far side of the wall of the compression molded part. The plastic for forming the small plastic part is injected from one side of a mold half into the injection mold and, within the injection mold, completely fills the clearance of the compression molded part. The plastic reaches the mold half opposite the injection side through the clearance or the thin portion which breaks open under the pressure of the plastic injected therein.
摘要翻译：一种方法将小塑料部件牢固地固定在压缩模制部件上的限定位置，压缩部件基本上由粘合或合成树脂结合的天然纤维或芯片组成。这些部件在压缩模具中从预先形成的松散的天然纤维和碎片之一的混合物的松散层和引入压缩模具的粘合剂中压缩成所需的形状，同时经历粘合剂和该层的体积减少。在压缩成型操作期间，在压塑部件的小塑料部件的紧固点处，在压塑部件的壁上形成小于小塑料部分的至少一个间隙或薄部分。此后，进行在紧固点处将小塑料部件或压缩成型部件的壁上直接成形注塑成型。完成的压缩成型部件被放置在限定位置，紧固点位于用于在小塑料部件上成型的分割注塑模具中，注塑模具的每个半模在壁的近侧和远侧紧贴地接触的压缩部件。用于形成小塑料部件的塑料从半模的一侧被注入到注射模具中，并且在注塑模具内完全填充压缩模制部件的间隙。塑料通过间隙或者在其中注入的塑料的压力下断开的薄部分到达与注射侧相对的模具一半。

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