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1. 发明授权

US4083870A Process for converting polyaminopolyaryl-methanes into diaminodiarylmethanes 失效
标题翻译：将聚氨基多芳基甲烷转化为二氨基二芳基甲烷的方法
公开(公告)号：US4083870A
公开(公告)日：1978-04-11
申请号：US441930
申请日：1974-02-12
申请人： Hans-Josef Buysch , Peter Ziemek , Roderich Raue
发明人： Hans-Josef Buysch , Peter Ziemek , Roderich Raue
IPC分类号： C07C211/50 , C07C67/00 , C07C209/00 , C07C209/68 , C08G18/32 , C08G18/76 , C08G59/50 , C07C85/24
CPC分类号： C07C209/68 , C08G18/3243 , C08G18/7671 , C08G59/5033
摘要： Polyaminopolyarylmethanes and an aromatic monoamine unsubstituted in an ortho or a para position to the amino group are heated in water to produce diaminodiarylmethanes.
摘要翻译：聚氨基多芳基甲烷和在氨基的邻位或对位未被取代的芳族单胺在水中加热以产生二氨基二芳基甲烷。

2. 发明授权

US4089901A Process for converting polyaminopolyaryl-methanes into diaminodiarylmethanes 失效
标题翻译：将聚氨基多芳基甲烷转化为二氨基二芳基甲烷的方法
公开(公告)号：US4089901A
公开(公告)日：1978-05-16
申请号：US441931
申请日：1974-02-12
申请人： Peter Ziemek , Roderich Raue , Hans-Josef Buysch
发明人： Peter Ziemek , Roderich Raue , Hans-Josef Buysch
IPC分类号： C07C217/84 , C07C67/00 , C07C209/00 , C07C209/68 , C07C211/50 , C07C213/00 , C08G18/32 , C08G18/76 , C08G59/50 , C07C85/24
CPC分类号： C08G18/3243 , C07C209/68 , C08G18/7671 , C08G59/5033
摘要： Polyaminopolyarylmethanes and a monoarylamine are heated in water in the presence of a solid acid catalyst insoluble in the reaction mixture to convert the polyarylaminopolyarylmethanes into diaminodiarylmethanes.
摘要翻译：聚氨基多芳基甲烷和单芳基胺在不溶于反应混合物的固体酸催化剂的存在下在水中加热，以将聚芳基胺多芳基甲烷转化成二氨基二芳基甲烷。

3. 发明授权

US4849306A Dry toners containing methinefanal pigments 失效
标题翻译：含有次甲醛颜料的干性调色剂
公开(公告)号：US4849306A
公开(公告)日：1989-07-18
申请号：US158520
申请日：1988-02-22
申请人： Roderich Raue , Hubertus Psaar , Horst Berneth
发明人： Roderich Raue , Hubertus Psaar , Horst Berneth
IPC分类号： G03G9/097 , C09B23/00 , C09B55/00 , G03G9/09
CPC分类号： G03G9/0916 , G03G9/0922
摘要： Dry toners for developing latent electrostatic images in electrostatic recording and printing methods contain, as charge-control substance, a pigment of the formulaF.sup.+ A.sup.- (I)in whichF represent a cationic radical of a methine dyestuff andA.sup.- represents an anion of a heteropolyacid based on tungsten and/or molybdenum with phosphorus, silicon, vanadium, cobalt, aluminum, manganese, chromium and/or nickel or a copper(I) hexacyanoferrate anion.
摘要翻译：用于在静电记录和印刷方法中显影静电潜像的干性调色剂含有作为电荷控制物质的式F + A-（I）的颜料，其中F表示次甲基染料的阳离子基团，A-表示阴离子基于钨和/或钼与磷，硅，钒，钴，铝，锰，铬和/或镍或铜（I）六氰基铁酸盐阴离子的杂多酸。

4. 发明授权

US4513142A Preparation of cationic methine dyestuffs 失效
标题翻译：阳离子次甲基染料的制备
公开(公告)号：US4513142A
公开(公告)日：1985-04-23
申请号：US412644
申请日：1982-08-30
申请人： Roderich Raue , Volker Huhne , Hans-Peter Kuhlthau
发明人： Roderich Raue , Volker Huhne , Hans-Peter Kuhlthau
IPC分类号： C09B23/00 , C09B23/06 , C09B23/10 , C09B23/14
CPC分类号： C09B23/06 , C09B23/105 , C09B23/145
摘要： A method of preparation of cationic dyestuffs having the formula ##STR1## wherein A, B, R, and R.sup.1 are defined in the specification carried out in the substantial absence of solvent and removing water formed in the reaction.
摘要翻译：具有式“IMAGE”的阳离子染料的制备方法，其中A，B，R和R 1在本说明书中定义，基本上不存在溶剂并除去反应中形成的水。

5. 发明授权

US4496719A 3H-Indol-2-yl cationic hydrazone dyestuffs 失效
标题翻译： 3H-吲哚-2-基阳离子腙染料
公开(公告)号：US4496719A
公开(公告)日：1985-01-29
申请号：US466709
申请日：1983-02-15
申请人： Roderich Raue
发明人： Roderich Raue
IPC分类号： C09B26/02 , C09B26/04 , C07D209/12 , C07D403/12
CPC分类号： C09B26/04
摘要： Hydrazone dyestuffs of the formula ##STR1## in which R denotes optionally substituted alkyl,R.sup.1 denotes alkyl and the two radicals can form a closed ring,R.sup.2 denotes optionally substituted alkyl,R.sup.3 denotes alkyl, alkoxy or halogen,R.sup.4 denotes alkyl, halogen, alkoxy, phenoxy, benzyloxy, benzyl, carboxyl, alkyl carboxylate, carboxamide, sulphonamide, alkylsulphonyl, phenylsulphonyl, cyano, nitro, trifluoromethyl, acetyl or benzoyl,B denotes ##STR2## D denotes alkylene, phenylene or naphthylene, E denotes halogen, hydroxyl, alkoxy or ##STR3## Z and Z.sup.1 denote hydrogen or --Y--Z.sup.2, Y denotes alkylene,Z.sup.2 denotes hydrogen, hydroxyl, pyridinium, ##STR4## Z.sup.3, Z.sup.4 and Z.sup.5 denote hydrogen or optionally substituted alkyl,Z.sup.3 also denotes phenyl, benzyl or ##STR5## Y.sup.1 denotes alkylene and s denotes 1-8, orZ and Z.sup.1 as well as Z.sup.3 and Z.sup.4 form a closed ring,G denotes alkylene, phenylene orG denotes alkylene, phenylene or ##STR6## m and n denote 0, 1 or 2 and X.sup.(-) denotes an anion,are used in particular for dyeing paper.
摘要翻译：其中R表示任选取代的烷基，R 1表示烷基且两个基团可以形成闭环，R 2表示任选取代的烷基，R 3表示烷基，烷氧基或卤素，R 4表示烷基，，卤素，烷氧基，苯氧基，苄氧基，苄基，羧基，羧酸烷基酯，甲酰胺，磺酰胺，烷基磺酰基，苯基磺酰基，氰基，硝基，三氟甲基，乙酰基或苯甲酰基，B表示亚烷基，亚苯基或亚萘基，E表示卤素，羟基，烷氧基或Z表示氢或-Y-Z2，Y表示亚烷基，Z2表示氢，羟基，吡啶鎓，Z3，Z4和Z5表示氢或任选取代的烷基 Z3也表示苯基，苄基或Y1表示亚烷基，s表示1-8或Z和Z1以及Z3和Z4形成闭环，G表示亚烷基，亚苯基或G表示亚烷基，亚苯基或 m和n表示0,1或2，X（ - ）表示阴离子特别用于染色纸。

6. 发明授权

US4419511A Process for the preparation of trimethine dyestuffs 失效
标题翻译：三甲基染料的制备方法
公开(公告)号：US4419511A
公开(公告)日：1983-12-06
申请号：US344262
申请日：1982-01-28
申请人： Roderich Raue
发明人： Roderich Raue
IPC分类号： C09B23/00 , C09B23/06
CPC分类号： C09B23/06
摘要： To prepare trimethine dyestuffs of the general formula ##STR1## wherein R represents a C.sub.1 - to C.sub.4 -alkyl radical,R.sup.1 represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, benzyl, cyclohexyl, C.sub.1 - to C.sub.4 -alkoxy, benzyloxy, phenoxy, halogen, trifluoromethyl, acetylamino, carboxylic acid C.sub.1 - to C.sub.4 -alkyl esters, carbonamide which may be substituted by C.sub.1 - to C.sub.4 -alkyl and/or phenyl, C.sub.1 - to C.sub.4 -alkylsulphonyl, phenylsulphonyl, cyano, nitro, benzoxazol-2-yl, benzimidazol-2-yl, benzthiazol-2-yl and sulphonamide which may be monosubstituted or disubstituted by C.sub.1 - to C.sub.4 -alkyl, or two radicals R.sup.1 represent a fused benzene ring,n denotes 1 to 4 andA.sup.- denotes an anionic radical, first an alkali metal salt of formic acid is reacted with a mixture of acetic acid and acetic anhydride and the product is then reacted with indoline compounds of the general formula ##STR2## in which R, R.sup.1 and n have the abovementioned meaning.
摘要翻译：为了制备通式“IMAGE”的三甲基染料，其中R表示C 1〜C 4 - 烷基，R 1表示氢，C 1至C 4 - 烷基，苄基，环己基，C 1至C 4 - 烷氧基，苄氧基，苯氧基，卤素三氟甲基，乙酰氨基，羧酸C 1至C 4烷基酯，可被C 1至C 4 - 烷基和/或苯基取代的碳酰胺，C 1至C 4 - 烷基磺酰基，苯基磺酰基，氰基，硝基，苯并恶唑-2-基苯并咪唑-2-基，苯并噻唑-2-基和磺酰胺，其可以被C 1 -C 4烷基单取代或二取代，或两个基团R 1表示稠合苯环，n表示1至4，A-表示阴离子基团首先将甲酸的碱金属盐与乙酸和乙酸酐的混合物反应，然后使产物与其中R，R 1和n具有上述含义的通式为“IMAGE”的二氢吲哚化合物反应。

7. 发明授权

US4326066A Triazolyl coumarin compounds, processes for their preparation and their use as whiteners and laser dyestuffs 失效
标题翻译：三唑基香豆素化合物，其制备方法及其作为增白剂和激光染料的用途
公开(公告)号：US4326066A
公开(公告)日：1982-04-20
申请号：US109957
申请日：1980-01-07
申请人： Udo Eckstein , Roderich Raue , Carl-Wolfgang Schellhammer
发明人： Udo Eckstein , Roderich Raue , Carl-Wolfgang Schellhammer
IPC分类号： C09B57/02 , D06L3/12 , C07D405/10 , C07D413/14 , C09K9/02
CPC分类号： C09B57/02 , D06L3/12
摘要： Coumarin compounds of the formula ##STR1## in which the substituents have the meanings given inthe description,are valuable whiteners for natural fibre materials, such as wool, or synthetic polycondensates. They can also be used as scintillators and laser dyestuffs.
摘要翻译：其中取代基具有在说明书中给出的含义的式“IMAGE”的香豆素化合物是天然纤维材料（例如羊毛或合成缩聚物）的有价值的增白剂。它们也可以用作闪烁体和激光染料。

8. 发明授权

US4301091A Fluorescent dyestuffs 失效
标题翻译：荧光染料
公开(公告)号：US4301091A
公开(公告)日：1981-11-17
申请号：US73773
申请日：1979-09-10
申请人： Rudolf Schieder , Helmut Telle , Roderich Raue , Wolfgang Brinkwerth
发明人： Rudolf Schieder , Helmut Telle , Roderich Raue , Wolfgang Brinkwerth
IPC分类号： C09B57/00 , C07C309/28 , C07C309/32 , C07F9/40 , C09B23/14 , D06L3/12 , H01S3/20 , H01S3/213 , C07C143/24 , D06P1/38
CPC分类号： C07C309/00 , C07F9/4056 , H01S3/20 , H01S3/213
摘要： Fluorescent dyestuffs of the formula ##STR1## wherein: R.sub.1 and R.sub.2 independently of one another represent hydrogen, a salt-forming cation, an alkyl radical with 1 to 8 carbon atoms or an aralkyl radical which is optionally substituted by non-chromophoric groups,R.sub.2 to R.sub.5 independently of one another represent hydrogen, alkyl, trifluoromethyl, alkoxy, aralkoxy, alkenyloxy, halogen or the carboxyl, cyano, alkylsulphonyl, arylsulphonyl, carboxamide or sulphonamide group or a carboxylic acid ester group, m and n independently of one another denote 0, 1 or 2 and the sum of m+n must be at least 2, and o, p, q and r independently of one another represent 0, 1 or 2.processes for their preparation, their use for whitening organic materials and a process for the production of a coherent laser emission using the fluorescent dyestuffs according to formula I.
摘要翻译：具有式（I）的荧光染料其中：R 1和R 2彼此独立地表示氢，形成盐的阳离子，具有1至8个碳原子的烷基或任选被非发色团取代的芳烷基 R 2至R 5彼此独立地表示氢，烷基，三氟甲基，烷氧基，芳烷氧基，烯氧基，卤素或羧基，氰基，烷基磺酰基，芳基磺酰基，甲酰胺或磺酰胺基或羧酸酯基，m和n独立地为一个另一个表示0,1或2，m + n的和必须至少为2，o，p，q和r彼此独立地表示0,1或2。

9. 发明授权

US4271395A Dyestuff laser 失效
标题翻译：染料激光
公开(公告)号：US4271395A
公开(公告)日：1981-06-02
申请号：US866521
申请日：1978-01-03
申请人： Uwe Brinkmann , Helmut Telle , Roderich Raue
发明人： Uwe Brinkmann , Helmut Telle , Roderich Raue
IPC分类号： H01S3/20 , C09B57/00 , H01S3/213
CPC分类号： H01S3/213
摘要： Laser light in the wavelength range of 420-480 nm is obtained with a dyestuff laser containing a dyestuff of the general formula ##STR1## wherein R and R.sub.1 independently of one another represent ##STR2## R.sub.2 denotes an optionally substituted alkyl radical with 1-4 C atoms, R.sub.3 and R.sub.4 independently of one another represent hydrogen or optionally substituted C.sub.1 -C.sub.4 -alkyl or conjointly with the nitrogen can form a 5-membered or 6-membered heterocyclic ring andm and n denote 1 or 2, andwhereinthe aromatic radicals contained in the formula can be further substituted, in a solvent which does not interfere with the emission, at a concentration, which emits laser beams, of, preferably, 10.sup.-2 to 10.sup.-5 mols/liter.
摘要翻译：使用含有通式为＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;的染料的染料激光获得波长范围为420-480nm的激光，其中R和R 1彼此独立地表示，表示任选取代的烷基具有1-4个C原子的基团，R 3和R 4彼此独立地表示氢或任选取代的C 1 -C 4烷基或与氮稠合形成5元或6元杂环，m和n表示1或2 并且其中式中所含的芳族基团可以在发射激光束的浓度不优于10-2至10-5摩尔/升的不干扰发射的溶剂中被进一步取代。

10. 发明授权

US4145537A Cationic dyestuffs 失效
标题翻译：阳离子染料
公开(公告)号：US4145537A
公开(公告)日：1979-03-20
申请号：US514999
申请日：1974-10-15
申请人： Hubertus Psaar , Roderich Raue
发明人： Hubertus Psaar , Roderich Raue
IPC分类号： C09B23/00 , C09B23/01 , C09B23/10 , D06P1/42 , D06P3/02 , C07D417/06
CPC分类号： D06P1/42 , C09B23/005 , C09B23/0058 , C09B23/105 , D06P3/022
摘要： Dyestuffs of the formula ##STR1## IN WHICH R denotes hydrogen, alkyl, alkenyl, cycloalkyl, aralkyl, aryl, alkoxy, aralkoxy, aryloxy, alkylamino, aralkylamino, arylamino, acylamino, carboxylic acid ester, carbonamido, acyl, halogen or nitrile, R.sub.1 denotes hydrogen, alkyl or aralkyl, R.sub.2 denotes hydrogen, alkyl, alkenyl, carbonamide or nitrile, R.sub.3 denotes alkyl, alkenyl or aralkyl, R.sub.4 denotes hydrogen, alkyl, alkenyl, aralkyl, alkoxy or aralkoxy, alkylamino, aralkylamino, acylamino, carbonamido, nitrile, nitro or halogen, R.sub.5 and R.sub.6 denote hydrogen, alkyl, aralkyl or a cycloaliphatic 5-membered or 6-membered ring, or R.sub.6 together with R.sub.1 forms a hydroaromatic 6-membered ring and An.sup.(-) represents an anion, and Processes for their preparation and their use for dyeing and printing natural and synthetic materials.
摘要翻译：式中，R表示氢，烷基，烯基，环烷基，芳烷基，芳基，烷氧基，芳烷氧基，芳氧基，烷基氨基，芳烷基氨基，芳基氨基，酰氨基，羧酸酯，碳酰氨基，酰基，卤素或腈，R1 表示氢，烷基或芳烷基，R2表示氢，烷基，烯基，碳酰胺或腈，R3表示烷基，烯基或芳烷基，R4表示氢，烷基，烯基，芳烷基，烷氧基或芳烷氧基，烷基氨基，芳烷基氨基，酰氨基，，硝基或卤素，R 5和R 6表示氢，烷基，芳烷基或脂环族5元或6元环，或者R 6与R 1一起形成水合芳族六元环，并且An（ - ）表示阴离子，而PROCESSES FOR 他们的制备及其用于染色和印刷天然和合成材料的使用。

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