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1. 发明授权

US4160807A Sulfonamido oximes, metal complexes thereof, and solutions containing such compounds for use in extraction of metal values 失效
标题翻译：磺胺肟，其金属络合物和含有这些化合物的溶液用于提取金属价值
公开(公告)号：US4160807A
公开(公告)日：1979-07-10
申请号：US90922678
申请日：1978-05-24
申请人： HENKEL CORP
发明人： VIRNIG MICHAEL J , MACKAY KENNETH D
IPC分类号： C01G3/00 , C01G9/00 , C01G51/00 , C01G53/00 , C22B3/34 , C07C143/78 , B01D11/04 , C07C143/79
CPC分类号： C22B3/0031 , C01G3/003 , C01G9/003 , C01G51/003 , C01G53/003 , Y02P10/234
摘要： Certain sulfonamido oximes, metal complexes thereof and solutions of said compounds in essentially water-immiscible, liquid hydrocarbon solvents are disclosed. The sulfonamido oximes have the general structural formula: wherein A, R1, R2 and R3 are as defined in the specification and claims hereof. Particular metal values are recovered from their aqueous solutions by using sulfonamido oximes dissolved in essentially water-immiscible liquid hydrocarbon solvents. The extraction process involves contacting the metal value containing aqueous solution with the solution of the sulfonamido oxime in essentially water-immiscible liquid hydrocarbon solvent and stripping the mertal values from the loaded organic phase.
摘要翻译：公开了某些磺酰胺肟，其金属络合物和所述化合物在基本上与水不混溶的液体烃溶剂中的溶液。亚磺酰氨基肟具有以下通式结构式：其中A，R 1，R 2和R 3如本说明书和权利要求中所定义。通过使用溶解在基本上与水不混溶的液体烃溶剂中的磺酰胺肟，从其水溶液中回收特定的金属值。提取过程包括将含金属含量的水溶液与磺酰胺肟的溶液在基本上与水不混溶的液体烃溶剂中接触并从负载的有机相中汽提出来的值。

2. 发明专利

JPS62277349A COLLECTION OF AMINO ACID 失效
公开(公告)号：JPS62277349A
公开(公告)日：1987-12-02
申请号：JP11997687
申请日：1987-05-15
申请人： HENKEL CORP
发明人： MATTISON PHILLIP L , WIRTH RONALD P , VIRNIG MICHAEL J , KRBECHEK LEROY
IPC分类号： B01D61/14 , B01D61/16 , B01D61/24 , C07C67/00 , C07C227/00 , C07C227/28 , C07C227/40

3. 发明申请

WO9319212A3 RECOVERY OF PRECIOUS METAL 审中-公开
标题翻译：恢复重金属
公开(公告)号：WO9319212A3
公开(公告)日：1993-10-28
申请号：PCT/US9301994
申请日：1993-03-11
申请人： HENKEL CORP
发明人： VIRNIG MICHAEL J
IPC分类号： C22B3/24 , C22B11/00 , C22B11/08
CPC分类号： C22B11/08 , C22B3/24 , C22B3/42 , C22B11/04 , Y02P10/234 , Y10S423/14
摘要： An improved process for recovery of precious metals such as gold or silver using novel ion exchnage resins having aryl guanidyl functionality from aryl guanidine compounds having a pKa at 25°C less than 13 and preferably less than 12. The resins have improved elution properties compared to known guanidine reagents using caustic eluant solutions, particularly improved eluant solutions such as a mixture of sodium hydroxide and sodium benzoate. A selective elution of base metals may be carried out before elution of the precious metals from the resins having guanidyl functionality.

4. 发明公开

EP0958390A4 IMPROVEMENT IN THE PROCESS OF RECOVERY OF METALS 失效
标题翻译：改进的金属回收过程
公开(公告)号：EP0958390A4
公开(公告)日：2000-03-08
申请号：EP97954561
申请日：1997-12-22
申请人： HENKEL CORP
发明人： VIRNIG MICHAEL J , KORDOSKY GARY A , WOLFE GEORGE A , MACKENZIE J MURDOCH
IPC分类号： C01G3/00 , C01G9/00 , C01G53/00 , C22B3/16 , C22B3/30 , C22B15/00
CPC分类号： C01G3/003 , C01G9/003 , C01G53/003 , C22B3/0017 , C22B15/0078 , C22B23/0446 , Y02P10/234 , Y02P10/236
摘要： An improved process for the extraction of a metal from an aqueous ammoniacal solution comprising: (i) contacting the aqueous ammoniacal solution with an extraction reagent comprised of a water insoluble extractant for the metal, to provide an organic phase, now containing metal values, and an aqueous phase from which metal values have been extracted; (ii) contacting the organic phase with an aqueous stripping solution to provide an aqueous strip phase, now containing metal values, and an organic phase from which metal values have been stripped; and (iii) recovering the metal values from the aqueous stripping solution; the improvement wherein (a) the extraction reagent contains an ammonia antagonist having only hydrogen bond acceptor properties; (b) the stripping solution is an aqueous highly acidic solution; and (c) the organic phase is washed with a weakly acidic aqueous solution prior to stripping with the highly acidic aqueous stripping solution. The extractant is preferably an oxime extractant, either a ketoxime or an aldoxime. The preferred hydrocarbon solvent is kerosene and the preferred antagonist is 2,2,4-trimethylpentane-1,3-diol diisobutyrate.

5. 发明公开

EP0879301A4 IMPROVED BETA-DIKETONES FOR THE EXTRACTION OF COPPER FROM AQUEOUS AMMONIACAL SOLUTIONS 失效
标题翻译： Betadiketones对铜从氨水溶液中分离
公开(公告)号：EP0879301A4
公开(公告)日：1999-04-14
申请号：EP97904756
申请日：1997-01-30
申请人： HENKEL CORP
发明人： VIRNIG MICHAEL J , KORDOSKY GARY A
IPC分类号： C07C45/68 , C07C49/76 , C07C49/782 , C22B3/26 , C22B15/00 , C07C49/12
CPC分类号： C07C49/782 , C07C45/68 , C07C49/76 , C22B3/0021 , C22B15/0078 , Y02P10/234 , Y02P10/236
摘要： Novel modified and improved beta-diketones and their use in the extraction of copper from aqueous ammoniacal solutions containing copper values, resulting from commercial processes, including, but not limited to, leaching of copper containing ores, such as sulfidic ores, or concentrates resulting from flotation of such sulfidic ores. The novel diketones are those highly sterically hindered, which may be represented by formula (I) or (II) where in formula (I), R1 through R7 are the same or different, and are chosen from the group consisting of hydrogen, an aryl radical, an alkaryl radical containing from 6 to about 18 carbon atoms, and an alkyl radical containing from 1 to about 13 carbon atoms, with the provisos that (a) any two of R1 through R7 may together form a carbocyclic ring, (b) no more than four of R1 through R7 may be hydrogen, and (c) the overall molecule contains at least 14 carbon atoms. In formula (II), R is phenyl or alkyl substituted phenyl, R' is alkyl, and R'', R''' and R'''' are the same or different and are chosen from the group consisting of H, alkyl having from 1 to about 8 carbon atoms, and aralkyl having from 7 to about 14 carbon atoms, with the proviso that (a) no more than two of R'', R''' and R'''' are H and (b) the total number of carbons in all R groups is at least 13. The preferred beta-diketones of Formula (II) are selected from the group consisting of 1-phenyl-2-benzyl-3-isoheptyl-1,3-propanedione, 1-phenyl-2-methyl-3-isoheptyl-1,3-propanedione, 1-phenyl-4-ethyl-1,3-nonanedione and 1-phenyl-4,4-dimethyl-1,3-undecanedione.

6. 发明公开

EP0979221A4 A PROCESS FOR MAKING STERICALLY-HINDERED BETA-DIKETONES 失效
标题翻译：生产工艺阻碍β-二酮
公开(公告)号：EP0979221A4
公开(公告)日：2001-05-23
申请号：EP98904898
申请日：1998-02-12
申请人： HENKEL CORP
发明人： MARTIN KEVIN V , MATTISON PHILLIP L , VIRNIG MICHAEL J
IPC分类号： C07C45/45 , C07C49/76 , C07C45/00
CPC分类号： C07C49/76 , C07C45/455
摘要： A process for making a sterically-hindered beta-diketone involving: (a) providing a solution comprising: (i) an ester; (ii) a base; and (iii) a solvent; (b) adding a ketone selected from the group consisting of an aromatic ketone and a hindered aliphatic ketone, to the solution, to form a condensation reaction mixture, whereby either the ester or the ketone is hindered; (c) reacting the solution with the ketone to form a sterically-hindered beta-diketone; and (d) recovering the sterically-hindered beta-diketone from the condensation reaction mixture.

7. 发明公开

EP0871800A4 METHOD FOR RECOVERING COPPER 失效
标题翻译：一种获得铜
公开(公告)号：EP0871800A4
公开(公告)日：1999-01-27
申请号：EP96926958
申请日：1996-05-30
申请人： HENKEL CORP
发明人： VIRNIG MICHAEL J , MACKENZIE J MURDOCH
IPC分类号： C22B3/28 , C22B3/30 , C22B15/00 , C25C1/12 , C25D1/12 , B01D11/04
CPC分类号： C22B15/0084 , C22B3/0012 , C22B3/0017 , C25C1/12 , Y02P10/234 , Y02P10/236
摘要： An improved process is described for the recovery of copper from an aqueous feed solution using solvent extraction and electrowinning in which the electrowinning is conducted in a first step (EW1) wherein the electrolyte is flowing perpendicular to the cathode surface without auxiliary mixing of the electrolyte between electrodes, and a second step (EW2) wherein the electrolyte is flowing parallel to the cathode surface. In a second embodiment, solvent extraction of copper and solvent extraction of acid are conducted in alternate steps to allow more complete recovery of copper.

8. 发明公开

EP0809714A4 MODIFIERS FOR ALDOXIME EXTRACTANT OF METAL VALUES 失效
标题翻译：改性剂ALDOXIMEEXTRAKTANT贵金属
公开(公告)号：EP0809714A4
公开(公告)日：1998-05-06
申请号：EP96903718
申请日：1996-02-12
申请人： HENKEL CORP
发明人： VIRNIG MICHAEL J , MATTISON PHILLIP L , KRBECHEK LEROY O , MACKENZIE MURDOCH
IPC分类号： C07C251/48 , C22B3/30 , C22B15/00 , C07C251/00 , C09K3/00
CPC分类号： C22B15/00 , C07C251/48 , C22B3/0017 , Y02P10/234
摘要： Alternative equilibrium modifiers for use with aldoxime extractants, such as hydroxyl aryl aldoxime extractants, employed in the process for extraction of metal values, particularly copper values, in the extraction from aqueous solutions, in which the extractant and modifiers are employed in an organic solvent phase, the solvent being a water insoluble, water immiscible hydrocarbon solvent, such as a kerosene.

9. 发明专利

CA2213102C MODIFIERS FOR ALDOXIME EXTRACTANT OF METAL VALUES 未知
公开(公告)号：CA2213102C
公开(公告)日：2009-01-27
申请号：CA2213102
申请日：1996-02-12
申请人： HENKEL CORP
发明人： MATTISON PHILLIP L , KRBECHEK LEROY O , MACKENZIE MURDOCH , VIRNIG MICHAEL J
IPC分类号： C22B3/30 , C07C251/48 , C22B15/00
摘要： Alternative equilibrium modifiers for use with aldoxime extractants, such as hydroxyl aryl aldoxime extractants, employed in the process for extraction of metal values, particularly copper values, in the extraction from aqueous solutions, in which the extractant and modifiers are employed in an organic solvent phase, the solvent being a wate r insoluble, water immiscible hydrocarbon solvent, such as a kerosene.

10. 发明专利

AU734689B2 Improvement in the process of recovery of metals 未知
公开(公告)号：AU734689B2
公开(公告)日：2001-06-21
申请号：AU7873998
申请日：1997-12-22
申请人： HENKEL CORP
发明人： VIRNIG MICHAEL J , KORDOSKY GARY A , WOLFE GEORGE A , MACKENZIE J MURDOCH
IPC分类号： C01G3/00 , C01G9/00 , C01G53/00 , C22B3/16 , C22B3/30 , C22B15/00 , C22B3/26
摘要： An improved process for the extraction of a metal from an aqueous ammoniacal solution comprising:(i) contacting the aqueous ammoniacal solution with an extraction reagent comprised of a water insoluble extractant for the metal, to provide an organic phase, now containing metal values, and an aqueous phase from which metal values have been extracted;(ii) contacting the organic phase with an aqueous stripping solution to provide an aqueous strip phase, now containing metal values, and an organic phase from which metal values have been stripped; and(iii) recovering the metal values from the aqueous stripping solution;the improvement wherein (a) the extraction reagent contains an ammonia antagonist having only hydrogen bond acceptor properties; (b) the stripping solution is an aqueous highly acidic solution; and (c) the organic phase is washed with a weakly acidic aqueous solution prior to stripping with the highly acidic aqueous stripping solution. The extractant is preferably an oxime extractant, either a ketoxime or an aldoxime. The preferred hydrocarbon solvent is kerosene and the preferred antagonist is 2,2,4-trimethylpentane-1,3-diol diisobutyrate.

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