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1. 发明申请

US20100152023A1 UZM-26 Family of Crystalline Aluminosilicate Compositions and Method of Preparing the Compositions 有权
标题翻译： UZM-26系列硅酸铝组合物及其制备方法
公开(公告)号：US20100152023A1
公开(公告)日：2010-06-17
申请号：US12335657
申请日：2008-12-16
申请人： Mark A. Miller , Gregory J. Lewis
发明人： Mark A. Miller , Gregory J. Lewis
IPC分类号： C01B39/04 , B01J29/072 , B01J29/06
CPC分类号： B01J29/70 , C01B39/04 , C01B39/06
摘要： This invention relates to a new family of crystalline aluminosilicate compositions designated the UZM-26 family. These include the species UZM-26P, UZM-26PX, UZM-26 and UZM-26X, which have unique structures. UZM-26P is an as synthesized layered composition, while UZM-26 is a calcined form of UZM-26P which has a three-dimensional structure. UZM-26PX is an ion-exchanged form of UZM-26P while UZM-26X is a calcined form of UZM-26PX which has a three-dimensional structure.
摘要翻译：本发明涉及一种名为UZM-26族的新型结晶硅铝酸盐组合物。这些包括具有独特结构的物种UZM-26P，UZM-26PX，UZM-26和UZM-26X。 UZM-26P是一种合成的层状组合物，而UZM-26是具有三维结构的UZM-26P的煅烧形式。 UZM-26PX是UZM-26P的离子交换形式，而UZM-26X是具有三维结构的UZM-26PX的煅烧形式。

2. 发明授权

US07578993B2 Process for preparing crystalline aluminosilicate compositions using charge density matching 有权
标题翻译：使用电荷密度匹配制备结晶硅铝酸盐组合物的方法
公开(公告)号：US07578993B2
公开(公告)日：2009-08-25
申请号：US10978001
申请日：2004-10-29
申请人： Gregory J. Lewis , Mark A. Miller , Jaime G. Moscoso , Ben A. Wilson
发明人： Gregory J. Lewis , Mark A. Miller , Jaime G. Moscoso , Ben A. Wilson
IPC分类号： B01J29/70
CPC分类号： B01J29/70 , C01B33/38 , C01B37/00 , C01B39/04 , C01B39/48
摘要： A process for preparing crystalline alumino-silicate compositions has been developed. The process involves preparing a charge density mismatch reaction mixture comprising sources of aluminum, silicon, optionally an E metal and at least one charge density mismatch (CDM) template. The CDM template is an organic nitrogen containing template, in the hydroxide form, e.g. tetraethylammonium hydroxide and is characterized in that it is incapable of inducing crystallization. To this mixture there is added a solution comprising a second templating agent termed a crystallization template (CT). The CT can be an organic template different from the CDM template, an alkali metal, an alkaline earth metal and mixtures thereof.
摘要翻译：已经开发了制备结晶铝硅酸盐组合物的方法。该方法包括制备电荷密度不匹配反应混合物，其包含铝，硅，任选的E金属和至少一种电荷密度不匹配（CDM）模板的来源。 CDM模板是含有有机氮的模板，以氢氧化物形式，例如，四乙基氢氧化铵，其特征在于它不能诱导结晶。向该混合物中加入包含称为结晶模板（CT）的第二模板剂的溶液。 CT可以是与CDM模板，碱金属，碱土金属及其混合物不同的有机模板。

3. 发明授权

US06388159B1 Xylene isomerization process using UZM-5 and UZM-6 zeolites 失效
标题翻译：使用UZM-5和UZM-6沸石的二甲苯异构化方法
公开(公告)号：US06388159B1
公开(公告)日：2002-05-14
申请号：US09705839
申请日：2000-11-03
申请人： Deng-Yang Jan , Gregory J. Lewis , Jaime G. Moscoso , Mark A. Miller , Qianjun Chen
发明人： Deng-Yang Jan , Gregory J. Lewis , Jaime G. Moscoso , Mark A. Miller , Qianjun Chen
IPC分类号： C07C522
CPC分类号： C07C5/2724 , B01J29/04 , B01J29/70 , B01J2229/26 , B01J2229/42 , C01B39/06 , C01B39/065 , C01B39/48 , C07C2/66 , C07C6/126 , C07C7/13 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C15/067 , C07C15/08
摘要： A process for isomerising xylene using a new family of related crystalline aluminosilicate zeolites has been developed. These zeolites are represented by the empirical formula: Mmn+Rrp+Al(1−x)ExSiyOz where M is an alkali or alkaline earth metal such as lithium and strontium, R is a nitrogen containing organic cation such as tetramethyl-ammonium and E is a framework element such as gallium.
摘要翻译：已经开发了使用新的相关结晶硅铝酸盐沸石族异构化二甲苯的方法。这些沸石由经验式表示：其中M是碱金属或碱土金属如锂和锶，R是含氮有机阳离子如四甲基铵，E是骨架元素如镓。

4. 发明授权

US08349291B2 Calcined UZM-22 and UZM-22HS aluminosilicate zeolites 有权
标题翻译：煅烧的UZM-22和UZM-22HS铝硅酸盐沸石
公开(公告)号：US08349291B2
公开(公告)日：2013-01-08
申请号：US12821555
申请日：2010-06-23
申请人： Mark A. Miller , Jaime G. Moscoso , Gregory J. Lewis
发明人： Mark A. Miller , Jaime G. Moscoso , Gregory J. Lewis
IPC分类号： C01B39/46 , C01B39/48
CPC分类号： B01J29/70 , C01B39/06 , C01B39/48 , C10G29/205 , C10G45/64 , C10G49/08 , C10G50/00
摘要： Crystalline microporous zeolites designated calcined UZM-22 and UZM-22HS have been synthesized. The calcined UZM-22 is represented by the empirical formula: M1′mn+Al1-xExSiyOz and UZM-22HS has an empirical formula of: M1an+Al(1-x)ExSiy′Oz″ where M1 and M1′ are exchangeable cations such as lithium or strontium and E is a framework element such as gallium. Both zeolites are obtained from an as synthesized microporous crystalline composition having an empirical formula of: Mmn+RrAl1-xExSiyOz either by calcination for UZM-22 or by various treatments such as ammonium hexafluorosilicate treatment for UZM-22HS.M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium.
摘要翻译：已经合成了称为煅烧UZM-22和UZM-22HS的结晶微孔沸石。煅烧的UZM-22由经验式表示：M1'mn + Al1-xExSiyOz，UZM-22HS具有经验式：M1an + Al（1-x）ExSiy'Oz“，其中M1和M1'是可交换阳离子作为锂或锶，E是诸如镓的骨架元素。两种沸石均由具有经验式：Mmn + RrAl1-xExSiyOz的合成微孔结晶组合物获得，其通过煅烧UZM-22或通过各种处理如六氟硅酸铵处理用于UZM-22HS。M是碱，碱土，或稀土金属如锂和锶，R是单电荷的有机铵阳离子，如胆碱阳离子，E是骨架元素如镓。

5. 发明授权

US08158104B2 UZM-7 aluminosilicate zeolite, method of preparation and processes using UZM-7 有权
标题翻译： UZM-7铝硅酸盐沸石，使用UZM-7的制备方法和工艺
公开(公告)号：US08158104B2
公开(公告)日：2012-04-17
申请号：US13172453
申请日：2011-06-29
申请人： Gregory J. Lewis , Mark A. Miller , Lisa M. Knight
发明人： Gregory J. Lewis , Mark A. Miller , Lisa M. Knight
IPC分类号： C01B39/48 , C01B39/04
CPC分类号： C01B39/48 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J37/10 , C07C2/12 , C07C2/58 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G35/095 , C10G47/16 , C10G73/00 , C10G2300/1044 , C10G2300/1059 , C10G2300/1096 , C10G2400/02 , C10G2400/30 , C07C15/02 , C07C9/16
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized designated UZM-7. These zeolites are represented by the empirical formula. Mmn+Rrp+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium, potassium and barium, R is an organoammonium cation such as the choline or the diethyldimethylammonium cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列结晶硅铝酸盐沸石，称为UZM-7。这些沸石由经验公式表示。 Mmn + Rrp + Al（1-x）ExSiyOz其中M为碱金属，碱土金属或稀土金属如锂，钾和钡，R为有机铵阳离子，如胆碱或二乙基二甲基铵阳离子，E为骨架元素如镓。这些沸石的特征在于独特的x射线衍射图案和组合物，并且具有用于进行各种烃转化方法的催化性能。

6. 发明授权

US07744850B2 UZM-22 aluminosilicate zeolite, method of preparation and processes using UZM-22 有权
标题翻译： UZM-22铝硅酸盐沸石，制备方法和使用UZM-22的方法
公开(公告)号：US07744850B2
公开(公告)日：2010-06-29
申请号：US11462056
申请日：2006-08-03
申请人： Mark A. Miller , Jaime G. Moscoso , Gregory J. Lewis
发明人： Mark A. Miller , Jaime G. Moscoso , Gregory J. Lewis
IPC分类号： C01B39/04
CPC分类号： B01J29/70 , C01B39/48 , C07C2/58 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G45/64 , C10G50/00 , C07C9/16
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium. These zeolites are similar to ZSM-18 but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列结晶硅铝酸盐沸石。这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M是碱金属，碱土金属或稀土金属如锂和锶，R是单一带电的有机铵阳离子，如胆碱阳离子，E是骨架元素，镓。这些沸石类似于ZSM-18，但是其特征在于独特的x射线衍射图和组成，并具有用于进行各种烃转化方法的催化性能。

7. 发明申请

US20100160701A1 HYDROCARBON CONVERSION PROCESSES USING THE UZM-27 FAMILY OF CRYSTALLINE ALUMINOSILICATE COMPOSITIONS 有权
标题翻译：使用UZM-27型水晶铝酸盐组合物的碳氢化合物转化方法
公开(公告)号：US20100160701A1
公开(公告)日：2010-06-24
申请号：US12337723
申请日：2008-12-18
申请人： Mark A. Miller , Gregory J. Lewis
发明人： Mark A. Miller , Gregory J. Lewis
IPC分类号： C07C2/02 , C07C2/24 , C07C5/22
CPC分类号： C07C2/12 , C07C5/22
摘要： This invention relates to hydrocarbon conversion processes using a new family of crystalline aluminosilicate compositions designated the UZM-27 family. These include the UZM-27 and UZM-27HS which have unique structures. UZM-27 is a microporous composition which has a three-dimensional structure and is obtained by calcining the as synthesized form designated UZM-27P. UZM-27HS is a high silica version of UZM-27 and includes an essentially pure silica version of UZM-27.
摘要翻译：本发明涉及使用称为UZM-27族的新型结晶硅铝酸盐组合物的烃转化方法。这些包括具有独特结构的UZM-27和UZM-27HS。 UZM-27是具有三维结构的微孔组合物，通过煅烧为UZM-27P的合成形式获得。 UZM-27HS是UZM-27的高二氧化硅版本，包括基本上纯二氧化硅版本的UZM-27。

8. 发明申请

US20080170987A1 Crystalline Aluminosilicates: UZM-13, UZM-17, UZM-19 and UZM-25 有权
标题翻译：结晶硅铝酸盐：UZM-13，UZM-17，UZM-19和UZM-25
公开(公告)号：US20080170987A1
公开(公告)日：2008-07-17
申请号：US12036893
申请日：2008-02-25
申请人： Gregory J. Lewis , Lisa M. Knight , Mark A. Miller , Stephen T. Wilson
发明人： Gregory J. Lewis , Lisa M. Knight , Mark A. Miller , Stephen T. Wilson
IPC分类号： B01J29/04
CPC分类号： B01J29/06 , B01J29/70 , C01B39/48
摘要： A series of crystalline layered and microporous compositions have been prepared. Compositions that have a layered structure and are identified as UZM-13, UZM-17 and UZM-19. Upon calcination at a temperature of about 400° C. to about 600° C., these compositions form a microporous crystalline zeolite with a three dimensional framework which has been identified as UZM-25. A process for preparing all these compositions and processes for using these compositions are also disclosed.
摘要翻译：已经制备了一系列结晶层状和微孔组合物。具有分层结构并被识别为UZM-13，UZM-17和UZM-19的组合物。在约400℃至约600℃的温度下煅烧时，这些组合物形成具有三维框架的微孔结晶沸石，其已被鉴定为UZM-25。还公开了制备所有这些组合物和使用这些组合物的方法的方法。

9. 发明授权

US07344694B2 UZM-12 and UZM-12HS: crystalline aluminosilicate zeolitic compositions and processes for preparing and using the compositions 有权
标题翻译： UZM-12和UZM-12HS：结晶硅铝酸盐沸石组合物和制备和使用组合物的方法
公开(公告)号：US07344694B2
公开(公告)日：2008-03-18
申请号：US10959453
申请日：2004-10-06
申请人： Mark A. Miller , Gregory J. Lewis , Jana L. Gisselquist , Jaime G. Moscoso , R. Lyle Patton
发明人： Mark A. Miller , Gregory J. Lewis , Jana L. Gisselquist , Jaime G. Moscoso , R. Lyle Patton
IPC分类号： C01B39/30
CPC分类号： C01B39/48 , B01J29/50 , C01B39/305
摘要： A series of crystalline alumino-silicate zeolites identified as UZM-12 have been synthesized. These UZM-12 compositions have the ERI topology, a Si/Al>5.5 and can be prepared as nanocrystallites having an average particle size of about 15 to about 50 nanometers and a spheroidal morphology. The UZM-12 composition can be treated to remove at least a fraction of the framework aluminum atoms thereby providing zeolites with a Si/Al>5.75 and identified as UZM-12HS. Both the UZM-12 and UZM-12HS can catalyze various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列标准为UZM-12的结晶铝硅酸盐沸石。这些UZM-12组合物具有ERI拓扑结构，Si / Al> 5.5，并且可以制备为具有约15至约50纳米的平均粒度和球形形态的纳米晶体。可以处理UZM-12组合物以除去至少一部分骨架铝原子，从而提供具有Si / Al> 5.75的沸石并鉴定为UZM-12HS。 UZM-12和UZM-12HS都可以催化各种烃转化过程。

10. 发明申请

US20120004484A1 UZM-7 ALUMINOSILICATE ZEOLITE, METHOD OF PREPARATION AND PROCESSES USING UZM-7 有权
标题翻译： UZM-7铝酸锌沸石，使用UZM-7的制备方法和工艺
公开(公告)号：US20120004484A1
公开(公告)日：2012-01-05
申请号：US13172453
申请日：2011-06-29
申请人： Gregory J. Lewis , Mark A. Miller , Lisa M. Knight
发明人： Gregory J. Lewis , Mark A. Miller , Lisa M. Knight
IPC分类号： C07C2/02 , C01B39/46 , C01B39/48
CPC分类号： C01B39/48 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J37/10 , C07C2/12 , C07C2/58 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G35/095 , C10G47/16 , C10G73/00 , C10G2300/1044 , C10G2300/1059 , C10G2300/1096 , C10G2400/02 , C10G2400/30 , C07C15/02 , C07C9/16
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized designated UZM-7. These zeolites are represented by the empirical formula. Mmn+Rrp+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium, potassium and barium, R is an organoammonium cation such as the choline or the diethyldimethylammonium cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列结晶硅铝酸盐沸石，称为UZM-7。这些沸石由经验公式表示。 Mmn + Rrp + Al（1-x）ExSiyOz其中M为碱金属，碱土金属或稀土金属如锂，钾和钡，R为有机铵阳离子，如胆碱或二乙基二甲基铵阳离子，E为骨架元素如镓。这些沸石的特征在于独特的x射线衍射图案和组合物，并且具有用于进行各种烃转化方法的催化性能。

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