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    • 4. 发明申请
    • PROCESS FOR MAKING DYNAMICALLY-LOADED ARTICLES COMPRISING PROPYLENE-BASED ELASTOMERS, COMPOSITION FOR USE IN SUCH PROCESSES, AND ARTICLE MADE USING SUCH PROCESSES
    • 制造包含丙烯基弹性体的动态装载物的方法,在这些方法中使用的组合物和使用这种方法制备的制品
    • WO2007084219A1
    • 2007-07-26
    • PCT/US2006/046707
    • 2006-12-07
    • EXXONMOBIL CHEMICAL PATENTS INC.WESTWOOD, Alistair, DuncanSAHNOUNE, Abdelhadi
    • WESTWOOD, Alistair, DuncanSAHNOUNE, Abdelhadi
    • C08K13/02C08L23/10
    • C08L23/10C08K3/013C08K5/14C08K7/02C08L23/0815C08L23/142C08L23/16C08L2312/00C08L2312/04C08L2666/06C08L2666/02
    • The invention relates to a process for making an article subject to dynamic loading, the process comprises: (i) shaping a polymer-containing composition in the green state, the composition comprising (a) a continuous phase of a polymeric component of at least 15 wt%, based on the total weight of the polymer component of a propylene elastomer having a heat of fusion of less than 70 J/g and an isotactic triad tacticity of 50 to 99% and optionally containing units derived from a diene, the polymeric component having a density of less than 0.9 g/cm3 and (b) from 20 to 120 phr, preferably 30 to 100 phr, most preferably 40 to 90 phr based on the total weight of the polymer component of a reinforcing filler component; and (c) a peroxide curative. The composition is combined with a fibrous reinforcement which is then cured to a cure state as determined by ODR @ 17O0C, 30 min MH-ML of from 5 to 80 dNm. The invention especially relates to such processes when providing under Demattia testing conditions a crack length of less than 15 mm at room temperature over 9OK cycles, preferably 10 mm, more preferably 7 mm, and most preferably 4 mm, and a 10 % modulus of 0.7 to 10 MPa, preferably 1.4 to 9 MPa and most preferably 2 to 8 MPa.
    • 本发明涉及一种用于制造经受动态载荷的制品的方法,该方法包括:(i)成型为具有生坯状态的含聚合物的组合物,所述组合物包含(a)聚合物组分的连续相至少15 重量%,基于熔融热小于70J / g的丙烯弹性体的聚合物组分的总重量和50至99%的全同立构三单元组立构规整度和任选地含有源自二烯的单元,聚合物组分 基于增强填料组分的聚合物组分的总重量,其密度小于0.9g / cm 3,(b)20至120phr,优选30至100phr,最优选40至90phr; 和(c)过氧化物治疗剂。 将组合物与纤维增强剂结合,然后将其固化至固化状态,如通过ODR @ 170℃,30分钟MH-ML为5至80dNm测定。 本发明特别涉及这样的方法,当在Demattia测试条件下,在室温下在9K循环,优选10mm,更优选7mm,最优选4mm和10%模量为0.7的情况下,在室温下提供小于15mm的裂纹长度 10MPa,优选为1.4〜9MPa,最优选为2〜8MPa。
    • 7. 发明申请
    • FOAMABLE THERMOPLASTIC REACTOR BLENDS AND FOAM ARTICLE THEREFROM
    • 可发泡的热塑性反应器共混物及其泡沫制品
    • WO2012094099A2
    • 2012-07-12
    • PCT/US2011/064139
    • 2011-12-09
    • EXXONMOBIL CHEMICAL PATENTS INC.JIANG, PeijunSAHNOUNE, AbdelhadiDEKMEZIAN, Armenag
    • JIANG, PeijunSAHNOUNE, AbdelhadiDEKMEZIAN, Armenag
    • C08J9/04C08J9/06C08L23/10C08F10/06
    • C08L23/10C08F255/02C08J9/0061C08J2205/052C08J2323/10C08J2423/12C08L23/12C08L23/142C08L2203/14C08L2205/02C08L2205/025C08L2666/06
    • This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt% propylene and from 0 to less than 10 wt% comonomer, said first propylene component having a Tm of 120°C or more; and (b) a second propylene polymer component comprising from 30 to 90 wt% propylene and 70 to 10 wt% comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120°C; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%; and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec -1 and temperature of 180°C; and where when the blend is foamed with a foaming agent, the foamed article has a density of 800 kg/m 3 or less.
    • 本发明涉及包含反应器内聚合物共混物的可发泡共混物,其包含:(a)第一丙烯聚合物组分,其包含90至100wt%的丙烯和0至小于10wt%的共聚单体, 所述第一丙烯组分的Tm为120℃或更高; 和(b)包含30-90重量%丙烯和70-10重量%共聚单体的第二丙烯聚合物组分,所述第二丙烯聚合物具有30,000g / mol或更高的Mw,并且所述第二含丙烯聚合物具有结晶度 与第一聚合物相差至少5%,其中聚合物共混物在与发泡剂结合之前具有:(i)至少120℃的Tm; (ii)10dg / min或更高的MFR; (iii)至少8MPa的拉伸强度; (iv)至少200%的断裂伸长率; 和(v)当在1秒-1的应变速率和180℃的温度下测量伸长粘度时,断裂伸长粘度与线性粘度之比为5或更大; 当混合物用发泡剂发泡时,发泡制品的密度为800kg / m 3或更低。