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    • 1. 发明授权
    • Refractive index and absorption detector for liquid chromatography based
on Fabry-Perot interferometry
    • 基于法布里 - 珀罗干涉法的液相色谱折射率和吸收检测器
    • US4455089A
    • 1984-06-19
    • US460467
    • 1983-01-24
    • Edward S. YeungSteven D. Woodruff
    • Edward S. YeungSteven D. Woodruff
    • G01B9/02G01N21/05G01N21/45G01N30/74
    • G01N30/74G01N21/45G01N2030/746G01N21/05
    • A refractive index and absorption detector for liquid chromatography. It is based in part on a Fabry-Perot interferometer and is used for the improved detection of refractive index and absorption. It includes a Fabry-Perot interferometer having a normally fixed first partially reflecting mirror and a movable second partially reflecting mirror. A chromatographic flow-cell is positioned between the mirrors along the optical axis of a monochromatic laser beam passing through the interferometer. A means for deriving information about the interference fringes coming out of the interferometer is used with a mini-computer to compute the refractive index of the specimen injected into the flow cell. The minicomputer continuously scans the interferometer for continuous refractive index readings and outputs the continuous results of the scans on a chart recorder. The absorption of the specimen can concurrently be scanned by including a second optical path for an excitation laser which will not interfere with the first laser, but will affect the specimen so that absorption properties can be detected. By first scanning for the refractive index of the specimen, and then immediately adding the excitation laser and subsequently scanning for the refractive index again, the absorption of the specimen can be computed and recorded.
    • 液相色谱的折射率和吸收检测器。 它部分基于法布里 - 珀罗干涉仪,用于改进折射率和吸收的检测。 它包括具有通常固定的第一部分反射镜和可动第二部分反射镜的法布里 - 珀罗干涉仪。 色谱流动池位于通过干涉仪的单色激光束的光轴之间的反射镜之间。 与微型计算机一起使用用于导出关于从干涉仪出来的干涉条纹的信息的装置来计算注入到流动池中的样本的折射率。 小型计算机连续扫描干涉仪以获得连续折射率读数,并在图表记录仪上输出扫描的连续结果。 可以通过包括不会干扰第一激光的激发激光器的第二光路来同时扫描样品的吸收,但会影响样品,从而可以检测吸收特性。 首先扫描样品的折射率,然后立即加入激发激光,然后再次扫描折射率,可以计算和记录样品的吸收。
    • 3. 发明申请
    • LASER BASED ANALYSIS USING A PASSIVELY Q-SWITCHED LASER
    • 使用普通Q开关激光器进行基于激光的分析
    • US20140209794A1
    • 2014-07-31
    • US13749842
    • 2013-01-25
    • Steven D. WoodruffDustin L. Mcintyre
    • Steven D. WoodruffDustin L. Mcintyre
    • G01J1/42
    • G01J3/443G01N21/6402G01N21/65G01N21/718
    • A device for Laser based Analysis using a Passively Q-Switched Laser comprising an optical pumping source optically connected to a laser media. The laser media and a Q-switch are positioned between and optically connected to a high reflectivity mirror (HR) and an output coupler (OC) along an optical axis. The output coupler (OC) is optically connected to the output lens along the optical axis. A means for detecting atomic optical emission comprises a filter and a light detector. The optical filter is optically connected to the laser media and the optical detector. A control system is connected to the optical detector and the analysis electronics. The analysis electronics are optically connected to the output lens. The detection of the large scale laser output production triggers the control system to initiate the precise timing and data collection from the detector and analysis.
    • 一种用于使用被动Q开关激光器的基于激光的分析的装置,包括光学连接到激光介质的光泵浦源。 激光介质和Q开关位于光学连接到高反射镜(HR)和输出耦合器(OC)之间并且光学连接。 输出耦合器(OC)沿光轴与输出透镜光学连接。 用于检测原子光发射的装置包括滤光器和光检测器。 光学滤波器光学连接到激光介质和光学检测器。 控制系统连接到光学检测器和分析电子器件。 分析电子器件光学连接到输出透镜。 大规模激光输出生产的检测触发了控制系统,从检测器和分析开始精确的定时和数据采集。
    • 4. 发明授权
    • Gas sensing system employing raman scattering
    • 采用拉曼散射的气体传感系统
    • US08674306B2
    • 2014-03-18
    • US13300988
    • 2011-11-21
    • Joel FalkPeng Kevin ChenMichael Paul BuricSteven D. Woodruff
    • Joel FalkPeng Kevin ChenMichael Paul BuricSteven D. Woodruff
    • G01N21/35
    • G01N21/65
    • A gas detection system includes a light detector, a pump laser with spectral emission between UV and IR wavelengths and structured to generate a laser beam, a hollow waveguide structured to receive a sample gas, the hollow waveguide having a bandwidth sufficient to transmit the laser beam and Stokes Raman photons scattered by the sample gas, and an optical system. The optical system is structured to: (i) direct the laser beam into the hollow waveguide such that it propagates in the hollow waveguide in one or more low-order low-loss waveguide modes, and (ii) direct Raman signals generated within the hollow waveguide in response to the laser beam interacting with the sample gas toward the light detector, the Raman signal including the Stokes Raman photons.
    • 气体检测系统包括光检测器,在UV和IR波长之间具有光谱发射并被构造为产生激光束的泵激光器,构造成接收样品气体的中空波导,所述中空波导具有足以传输激光束的带宽 和斯托克斯拉曼光子由样品气体分散,以及光学系统。 光学系统被构造成:(i)将激光束引导到中空波导中,使得其在一个或多个低阶低损耗波导模式中在中空波导中传播,以及(ii)在中空波导内产生的直接拉曼信号 波导响应于与样品气体朝向光检测器相互作用的激光束,拉曼信号包括斯托克斯拉曼光子。
    • 6. 发明授权
    • Micro-polarimeter for high performance liquid chromatography
    • 用于高效液相色谱的微型偏光仪
    • US4498774A
    • 1985-02-12
    • US489031
    • 1983-04-27
    • Edward E. YeungLarry E. SteenhoekSteven D. WoodruffJeng-Chung Kuo
    • Edward E. YeungLarry E. SteenhoekSteven D. WoodruffJeng-Chung Kuo
    • G01N21/05G01N21/21G01N30/74G01N31/06
    • G01N30/74G01N21/21G01N2030/746G01N21/05
    • A micro-polarimeter interfaced with a system for high performance liquid chromatography, for quantitatively analyzing micro and trace amounts of optically active organic molecules, particularly carbohydrates. A flow cell with a narrow bore is connected to a high performance liquid chromatography system. Thin, low birefringence cell windows cover opposite ends of the bore. A focused and polarized laser beam is directed along the longitudinal axis of the bore as an eluent containing the organic molecules is pumped through the cell. The beam is modulated by air gap Faraday rotators for phase sensitive detection to enhance the signal to noise ratio. An analyzer records the beams's direction of polarization after it passes through the cell. Calibration of the liquid chromatography system allows determination of the quantity of organic molecules present from a determination of the degree to which the polarized beam is rotated when it passes through the eluent.
    • 与用于高效液相色谱的系统接口的微旋光仪,用于定量分析微量和痕量的光学活性有机分子,特别是碳水化合物。 具有窄孔的流动池连接到高效液相色谱系统。 薄,低双折射单元窗口覆盖孔的相对端。 聚焦和偏振的激光束沿着孔的纵向轴线引导,因为含有有机分子的洗脱液被泵送通过细胞。 光束由气隙法拉第旋转器调制,用于相位敏感检测,以增强信噪比。 分析仪在通过电池后记录光束的极化方向。 液相色谱系统的校准允许通过确定偏振光束通过洗脱液时旋转的程度来确定存在的有机分子的量。
    • 7. 发明授权
    • Laser interlock system
    • 激光互锁系统
    • US08934511B1
    • 2015-01-13
    • US14023822
    • 2013-09-11
    • Steven D. WoodruffDustin L. Mcintyre
    • Steven D. WoodruffDustin L. Mcintyre
    • H01S3/00H01S3/10
    • H01S3/0014F02P23/04H01S3/091
    • A method and device for providing a laser interlock having a first optical source, a first beam splitter, a second optical source, a detector, an interlock control system, and a means for producing dangerous optical energy. The first beam splitter is optically connected to the first optical source, the first detector and the second optical source. The detector is connected to the interlock control system. The interlock control system is connected to the means for producing dangerous optical energy and configured to terminate its optical energy production upon the detection of optical energy at the detector from the second optical source below a predetermined detector threshold. The second optical source produces an optical energy in response to optical energy from the first optical source. The optical energy from the second optical source has a different wavelength, polarization, modulation or combination thereof from the optical energy of the first optical source.
    • 一种用于提供具有第一光源,第一分束器,第二光源,检测器,互锁控制系统和用于产生危险光能的装置的激光互锁的方法和装置。 第一分束器光学连接到第一光源,第一检测器和第二光源。 检测器连接到互锁控制系统。 联锁控制系统连接到用于产生危险光能的装置,并被配置为在检测器处从第二光源检测到低于预定检测器阈值的光能时终止其光能产生。 第二光源响应于来自第一光源的光能产生光能。 来自第二光源的光能具有与第一光源的光能不同的波长,偏振,调制或其组合。
    • 8. 发明申请
    • Gas Sensing System Employing Raman Scattering
    • 采用拉曼散射的气体传感系统
    • US20120176600A1
    • 2012-07-12
    • US13300988
    • 2011-11-21
    • Joel FalkPeng Kevin ChenMichael Paul BuricSteven D. Woodruff
    • Joel FalkPeng Kevin ChenMichael Paul BuricSteven D. Woodruff
    • G01J3/44G01J3/00
    • G01N21/65
    • A gas detection system includes a light detector, a pump laser with spectral emission between UV and IR wavelengths and structured to generate a laser beam, a hollow waveguide structured to receive a sample gas, the hollow waveguide having a bandwidth sufficient to transmit the laser beam and Stokes Raman photons scattered by the sample gas, and an optical system. The optical system is structured to: (i) direct the laser beam into the hollow waveguide such that it propagates in the hollow waveguide in one or more low-order low-loss waveguide modes, and (ii) direct Raman signals generated within the hollow waveguide in response to the laser beam interacting with the sample gas toward the light detector, the Raman signal including the Stokes Raman photons.
    • 气体检测系统包括光检测器,在UV和IR波长之间具有光谱发射并被构造为产生激光束的泵激光器,构造成接收样品气体的中空波导,所述中空波导具有足以传输激光束的带宽 和斯托克斯拉曼光子由样品气体分散,以及光学系统。 光学系统被构造成:(i)将激光束引导到中空波导中,使得其在一个或多个低阶低损耗波导模式中在中空波导中传播,以及(ii)在中空波导内产生的直接拉曼信号 波导响应于与样品气体朝向光检测器相互作用的激光束,拉曼信号包括斯托克斯拉曼光子。