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    • 4. 发明申请
    • FOAMABLE THERMOPLASTIC REACTOR BLENDS AND FOAM ARTICLE THEREFROM
    • 可膨胀热塑性反应器混合物和泡沫体
    • WO2012094099A3
    • 2012-10-04
    • PCT/US2011064139
    • 2011-12-09
    • EXXONMOBIL CHEM PATENTS INCJIANG PEIJUNSAHNOUNE ABDELHADIDEKMEZIAN ARMENAG
    • JIANG PEIJUNSAHNOUNE ABDELHADIDEKMEZIAN ARMENAG
    • C08J9/04C08F10/06C08J9/06C08L23/10
    • C08L23/10C08F255/02C08J9/0061C08J2205/052C08J2323/10C08J2423/12C08L23/12C08L23/142C08L2203/14C08L2205/02C08L2205/025C08L2666/06
    • This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt% propylene and from 0 to less than 10 wt% comonomer, said first propylene component having a Tm of 120°C or more; and (b) a second propylene polymer component comprising from 30 to 90 wt% propylene and 70 to 10 wt% comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120°C; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%; and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec-1 and temperature of 180°C; and where when the blend is foamed with a foaming agent, the foamed article has a density of 800 kg/m3 or less.
    • 本发明涉及包含反应器内聚合物共混物的可发泡共混物,其包含:(a)包含90至100重量%丙烯和0至小于10重量%共聚单体的第一丙烯聚合物组分,所述第一丙烯组分的Tm为 120℃以上; 和(b)第二丙烯聚合物组分,其包含30至90重量%的丙烯和70至10重量%的共聚单体,所述第二丙烯聚合物的Mw为30,000g / mol以上,所述第二丙烯聚合物具有结晶度 与第一聚合物不同,其中聚合物共混物在与发泡剂组合之前具有:(i)至少120℃的Tm; (ii)10dg / min以上的MFR; (iii)至少8MPa的拉伸强度; (iv)断裂伸长率至少为200%; 和(v)当在1秒-1的应变速率和180℃的温度下测量伸长粘度时,断裂时的拉伸粘度与线粘度之比为5以上; 并且当共混物用发泡剂发泡时,发泡制品的密度为800kg / m 3或更小。
    • 6. 发明申请
    • THERMOPLASTIC POLYOLEFIN BLENDS
    • 热塑性聚烯烃共混物
    • WO2012112259A3
    • 2012-10-18
    • PCT/US2012022177
    • 2012-01-23
    • EXXONMOBIL CHEM PATENTS INCTSE MUN FUJIANG PEIJUN
    • TSE MUN FUJIANG PEIJUN
    • C08L23/04C08F2/01C08F10/02C08J5/18
    • C08F10/02C08F4/65908C08F4/65912C08F4/65925C08F4/65927C08F10/00C08F110/02C08F210/16C08J5/18C08J2323/08C08J2423/08C08L23/0807C08L2205/02C08F2/001C08F2500/07C08F2500/11C08F2500/20C08F210/14C08F2500/08C08F4/65904
    • This invention relates to a blend composition comprising: 1) a linear ethylene containing polymer, such as a LLDPE, a HDPE or the like; and at least 1 weight percent of an in-reactor polymer blend comprising: (a) a first ethylene containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol; and (b) a second ethylene containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90°C (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Alternately the in-reactor polymer blend comprises: (a) a first ethylene polymer comprising 90 wt% to 100 wt% ethylene and from 0 wt% to less than 10 wt% comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 wt% to 90 wt% ethylene and 30 wt% to 10 wt% comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the in-reactor polymer blend has one or more of the following characteristics: (a) at least 78 wt% ethylene; (b) a Tm of at least 100°C over a density ranging from 0.84 to 0.92 g/cm3; (c) a elongation at break of 300% or more; (d) a strain hardening ratio M300/M100 of at least 1.2; (e) a ratio of complex viscosity at 0.01 rad/s to the complex viscosity at 100 rad/s of at least 30; and (f) a shear thinning index of less than -0.2.
    • 本发明涉及一种共混组合物,其包含:1)含线性乙烯的聚合物,例如LLDPE,HDPE等; 和至少1重量%的反应器内聚合物共混物,其包含:(a)密度大于0.90g / cm 3和Mw大于20,000g / mol的第一含乙烯聚合物; 和(b)密度小于0.90g / cm 3的第二含乙烯聚合物,其中聚合物共混物具有至少90℃的Tm(DSC第二熔体),密度小于0.92g / cm 3,和 第一和第二聚合物的密度相差至少1%。 或者,反应器内聚合物共混物包含:(a)包含90重量%至100重量%乙烯和0重量%至小于10重量%共聚单体的第一乙烯聚合物,所述第一乙烯聚合物组分的密度大于0.920g / cm3,Mw为20,000g / mol以上; 和(b)包含70重量%至90重量%的乙烯和30重量%至10重量%的共聚单体的第二乙烯聚合物,所述第二乙烯聚合物的密度为0.910g / cm 3或更小,其中反应器内聚合物共混物 具有以下一个或多个特征:(a)至少78重量%的乙烯; (b)在0.84至0.92g / cm 3的密度范围内至少100℃的Tm; (c)断裂伸长率在300%以上; (d)应变硬化率M300 / M100为至少1.2; (e)在0.01rad / s下的复数粘度与100rad / s下的复数粘度的比至少为30; 和(f)小于-0.2的剪切稀化指数。