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    • 2. 发明专利
    • DE69525103D1
    • 2002-03-14
    • DE69525103
    • 1995-05-24
    • EASTMAN KODAK CO
    • MOOBERRY JARED BENSEIFERT JAMES JOSEPHHOKE DAVIDWU ZHENG ZHISOUTHBY DAVID THOMASCOMS FRANK DINO
    • G03C7/00G03C7/305G03C7/36
    • A photographic element comprises a substrate bearing an silver halide (AgX) emulsion layer having associated therewith a high dye-yield coupler of formula (I). In (I), COUP = coupler residue able to couple with oxidised colour developer to form a first dye; T = timing group; m = integer 0 to 2; L = -OC(=O)-, -OC(=S)-, -SC(=O)-, -SC(=S)- or -OC(=NSO2R) as linking gp. pref. -OC(=O)-; R = opt. substd. alkyl or aryl; DYE = releasable second dye or dye precursor of formula (II); R1 = H or opt. substd. alkyl, aryl or hetero aryl; R2 = opt. substd. alkyl, opt. forming a ring with Z1; A = opt. substd. aryl or heteroaryl, pref. phenyl naphthyl or thiazole (5-membered); B = heterocycle of formula (III); p = integer 0 to 3; Y = electron-withdrawing gp. pref. of Hammett sigma (para) value at least 0.3, pref. CN, COOH, SO2 or acyl; Y1, Z and Z1 = H or substd.; n = 0, 1 or 2. X = O, S or N(R5), pref. O; W = N or C(R4), pref. C(R4); R3 = substd. linked to (III) by a C or N atom of R3; R4 = H or substit.; R5 = H or alkyl, provided R3+R4 may form a ring; when the ring = phenyl, Z = H, W = C(R4) and X = O the phenyl ring does not contain a substit. having a Hammett sigma (para) value of 0.23 or more. Also claimed is a process of forming an image by image-wise exposure of the element followed by contact with oxidised colour developer.