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    • 3. 发明申请
    • POLYETHYLENE COMPOSITION SUITABLE FOR STRETCH FILM APPLICATIONS, AND METHOD OF PRODUCING THE SAME
    • 适用于拉伸膜应用的聚乙烯组合物及其制造方法
    • WO2014058659A1
    • 2014-04-17
    • PCT/US2013/062822
    • 2013-10-01
    • DOW GLOBAL TECHNOLOGIES LLC
    • WANG, JianKAPUR, MridulaLIN, YijianEFFLER, Lawrence J.TAMBLING, Troy M.REIB, Robert N.
    • C08L23/04
    • C08F110/02C08J5/18C08L23/06C08L23/0815C08L2203/16C08L2205/025
    • The instant invention provides a polyethylene composition suitable for stretch film applications and, method of producing the same, and cast film made therefrom. The linear low density polyethylene composition suitable for stretch film applications according to the present invention comprises: less than or equal to 100 percent by weight of the units derived from ethylene; and less than 35 percent by weight of units derived from one or more α-olefin comonomers; wherein said linear low density polyethylene composition has a density in the range of from 0.900 to 0.930 g/cm3, a molecular weight distribution (Mw/Mn) in the range of from 2.5 to 4.5, a melt index (I2) in the range of from 0.3 to 10 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of from 2.2 to 3, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of said composition, and a zero shear viscosity ratio (ZSVR) in the range from 1 to 1.2.
    • 本发明提供了适用于拉伸膜应用的聚乙烯组合物及其制备方法,以及由其制成的流延薄膜。 适用于根据本发明的拉伸膜应用的线性低密度聚乙烯组合物包含:小于或等于100重量%的衍生自乙烯的单元; 和少于35重量%的衍生自一种或多种α-烯烃共聚单体的单元; 其中所述线性低密度聚乙烯组合物的密度范围为0.900-0.930g / cm3,分子量分布(Mw / Mn)在2.5-4.5范围内,熔体指数(I2)在 0.3至10g / 10分钟,存在于所述组合物的骨架中的每1000个碳原子的分子量分布(Mz / Mw)在2.2至3的范围内,乙烯基不饱和度小于0.1个乙烯基,并且零 剪切粘度比(ZSVR)在1〜1​​.2的范围内。
    • 9. 发明申请
    • MULTILAYER FILMS, ARTICLES COMPRISING THE SAME, METHODS OF MANUFACTURING MULTILAYER FILMS
    • 多层膜,包含其的制品,制造多层膜的方法
    • WO2018005577A1
    • 2018-01-04
    • PCT/US2017/039619
    • 2017-06-28
    • DOW GLOBAL TECHNOLOGIES LLC
    • LIN, YijianHUANG, WenyiBENSASON, Selim
    • B32B7/02B32B27/08B32B27/20B32B27/28B32B27/30B32B27/32B32B27/34B65D65/40
    • B32B27/08B32B7/02B32B7/035B32B27/20B32B27/285B32B27/306B32B27/32B32B27/34B32B38/0012B32B2038/0028B32B2250/05B32B2250/40B32B2264/104B32B2270/00B32B2274/00B32B2307/516B32B2307/724B32B2439/40B32B2439/70B65D65/40
    • The present invention provides multilayer films, packages formed from such films, and methods of making multilayer films. In one aspect, a multilayer film comprises multilayer film comprising at least 3 layers, each layer having opposing facial surfaces and arranged in the order A/B/C, wherein Layer A comprises a high density polyethylene having a M w,cc /M n,cc of at least 6.0, a M z,abs of at least 500,000 grams/mol as measured by triple detector GPC, and a density of 0.957 - 0.970 g/cm 3 , wherein the high density polyethylene comprises at least 90 percent by weight of Layer A; Layer B comprises a gas permeation layer, wherein a top facial surface of Layer B is in adhering contact with a bottom facial surface of Layer A; and Layer C comprises a high density polyethylene having a M w,cc /M n,cc of at least 6.0, a M z,abs of at least 500,000 grams/mol as measured by triple detector GPC, and a density of 0.957 - 0.970 g/cm 3 , wherein the high density polyethylene comprises at least 90 percent by weight of Layer C and wherein a top facial surface of Layer C is in adhering contact with a bottom facial surface of Layer B, wherein the film is oriented in the machine direction and wherein the film exhibits a normalized carbon dioxide transmission rate of at least 3000 cm 3 •mil/100 in 2 /day when measured according to ASTM F-2476 at 23 °C, 0% relative humidity, and 1 atm, and wherein the film exhibits a ratio of the carbon dioxide transmission rate to an oxygen transmission rate of at least 4.0, when the oxygen transmission rate is measured according to ASTM D3985 at 23 °C, 0% relative humidity, and 1 atm.
    • 本发明提供了多层膜,由这种膜形成的包装以及制造多层膜的方法。 在一个方面,多层膜包含多层膜,其包含至少3层,每层具有相对的面部表面并按A / B / C的顺序排列,其中层A包含具有M w,cc的高密度聚乙烯 通过三重检测器GPC测得的至少6.0,至少500,000克/摩尔的M z,abs,和密度 为0.957-0.970克/厘米3,其中高密度聚乙烯包含至少90重量%的层A; 层B包括气体渗透层,其中层B的顶部面部表面与层A的底部面部表面粘附接触; 并且层C包含M w,cc / M n,cc为至少6.0的高密度聚乙烯,M z,abs, 通过三重检测器GPC测量为至少500,000克/摩尔,密度为0.957-0.970克/厘米3,其中高密度聚乙烯包含至少90重量%的层C,并且其中 层C的顶部面部表面与层B的底部面部表面粘附接触,其中所述膜沿机器方向取向并且其中所述膜显示出至少3000cm 3的归一化二氧化碳透过率, 当按照ASTM F-2476在23℃,0%相对湿度和1大气压下测量时,所述薄膜显示出的比率为100m 2/100英寸2 /天 当在23℃,0%相对湿度和1个大气压下根据ASTM D3985测量氧气透过速率时,将二氧化碳透过率调节至至少4.0的透氧率。