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    • 3. 发明专利
    • New (meth)acrylate having secondary hydroxy group and method for producing the same
    • 具有二级羟基的新(甲基)丙烯酸酯及其生产方法
    • JP2009256288A
    • 2009-11-05
    • JP2008110091
    • 2008-04-21
    • Dic CorpDic株式会社
    • TAJIRI HIROSUKEAOKI TORU
    • C07C69/732C07C69/675C07C233/20C12N1/19C12P7/62C12P13/02C12P13/16
    • PROBLEM TO BE SOLVED: To provide a new (meth)acrylate having a secondary hydroxy group and usable as a monomer for a polymer material, and to provide a method for producing the (meth)acrylate having the secondary hydroxy group by an esterification reaction of a fatty acid having the secondary hydroxy group with a hydroxyacrylate by using an enzymic reaction.
      SOLUTION: The new (meth)acrylate is provided having the secondary hydroxy group. The method is also provided for producing the new (meth)acrylate having the secondary hydroxy group by the esterification reaction of the fatty acid having the secondary hydroxy group with the hydroxyacrylate under a mild condition by using a lipase obtained from a specific microorganism for providing the (meth)acrylate or an arming yeast presenting the lipase on a cell cortex under a mild condition.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供具有仲羟基并可用作聚合物材料的单体的新的(甲基)丙烯酸酯,并提供通过以下方法制备具有仲羟基的(甲基)丙烯酸酯的方法: 通过使用酶反应将具有仲羟基的脂肪酸与羟基丙烯酸酯进行酯化反应。 解决方案:提供具有仲羟基的新的(甲基)丙烯酸酯。 该方法还用于通过使用从特定微生物获得的脂肪酶在温和条件下通过具有仲羟基的脂肪酸与羟基丙烯酸酯的酯化反应来制备具有仲羟基的新的(甲基)丙烯酸酯, (甲基)丙烯酸酯或在温和条件下在细胞皮质上呈递脂肪酶的布发酵母。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Method for producing ester derivative
    • 生产酯衍生物的方法
    • JP2009254315A
    • 2009-11-05
    • JP2008110092
    • 2008-04-21
    • Dic CorpDic株式会社
    • TAJIRI HIROSUKEAOKI TORU
    • C12P7/62C12P13/00
    • PROBLEM TO BE SOLVED: To provide a method for producing an acrylate compound useful as a monomer for a polymer material by reacting a (meth)acrylic acid derivative with an aliphatic carboxylic acid or polybasic carboxylic acid which may have hydroxyl groups by using enzymatic reaction. SOLUTION: Provided is a method for producing a (meth)acrylate by the esterification reaction of an aliphatic carboxylic acid or polybasic carboxylic acid which may have hydroxyl groups with a hydroxyacrylate under a mild condition using a lipase derived from a specific microorganism or an arming yeast presenting the lipase on the cell surface layer. COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供一种制备用作聚合物材料单体的丙烯酸酯化合物的方法,其通过使(甲基)丙烯酸衍生物与可具有羟基的多元羧酸通过使用 酶反应。 解决方案:提供通过使用来自特定微生物的脂肪酶,在温和条件下通过可能具有羟基的羟基的脂肪族羧酸或多元羧酸的酯化反应制备(甲基)丙烯酸酯的方法,或 一种在细胞表面层上呈现脂肪酶的武装酵母。 版权所有(C)2010,JPO&INPIT