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    • 1. 发明申请
    • Curable Silicone Composition That Provides A Highly Transparent Cured Silicone Material
    • 提供高度透明的固化硅胶材料的可固化硅酮组合物
    • US20110288246A1
    • 2011-11-24
    • US13147320
    • 2010-01-29
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • C08G77/38B05D3/02
    • C08L83/04C08G77/12C08G77/20C08L83/00
    • A curable silicone composition comprises (A) (A-1) an alkenyl-containing dialkylpolysiloxane and a viscosity of at least 1,000 mPa·s to not more than 20,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl, that contains from 2.5 to 5.0 mass % alkenyl group, and that has a ratio for the total number of moles of R12R2SiO1/2 and R13SiO1/2 units to 1 mole of the SiO4/2 unit in the range from 0.70 to 1.10; (B) an organopolysiloxane that contains at least 0.9 mass % silicon-bonded hydrogen; and (C) a hydrosilylation reaction catalyst. The curable composition provides a bending-tolerant and highly transparent cured silicone material that has a hardness in the range from 80 to 95, and a parallel light transmittance at 200° C. of a value that is at least 99% of the parallel light transmittance at 25° C.
    • 一种可固化的有机硅组合物包含(A)(A-1)含链烯基的二烷基聚硅氧烷,并且粘度至少为1,000mPa·s至不超过20,000mPa·s,(A-2)含链烯基的树脂形式 包含SiO 4/2单元,R 12 R 2 SiO 1/2单元和R 13 SiO 1/2单元的有机聚硅氧烷,其中R 1是烷基,R 2是含有2.5-5.0质量%链烯基的烯基,并且具有总摩尔数 的R12R2SiO1 / 2和R13SiO1 / 2单元与1摩尔的SiO 4/2单元在0.70至1.10的范围内; (B)含有至少0.9质量%硅键合氢的有机聚硅氧烷; 和(C)氢化硅烷化反应催化剂。 可固化组合物提供硬度为80-95的弯曲耐受性和高度透明的固化的硅氧烷材料,并且在200℃下的平行光透射率为平行透光率的至少99% 在25°C
    • 2. 发明授权
    • Curable silicone composition that provides a highly transparent cured silicone material
    • 提供高度透明的固化硅胶材料的可固化硅酮组合物
    • US08859693B2
    • 2014-10-14
    • US13146995
    • 2010-01-29
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • C08L83/07C09D183/04B05D3/10C08G77/38C08L83/04C08G77/20C08G77/12
    • C08L83/04C08G77/12C08G77/20C09D183/04C08L83/00C08K5/56
    • A curable silicone composition comprises (A) (A-1) a dialkylpolysiloxane that has at least two alkenyl groups in each molecule and a viscosity of at least 1,000 mPa·s to not more than 50,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl and that contains the alkenyl group in the range from at least 0.5 mass % to less than 3.5 mass %; (B) an organopolysiloxane that has at least three silicon-bonded hydrogen atoms; and (C) a hydrosilylation reaction catalyst. The curable composition provides a highly transparent cured silicone material that has a hardness in the range from at least 30 to not more than 80, a parallel light transmittance at 25° C. of at least 90%, and a parallel light transmittance at 200° C. that is at least 99% of the parallel light transmittance at 25° C.
    • 可固化的有机硅组合物包含(A)(A-1)在每个分子中具有至少两个烯基的二烷基聚硅氧烷和至少1,000mPa·s至不超过50,000mPa·s的粘度和(A-2)a 含有SiO 4/2单元,R 12 R 21 SiO 1/2单元和R 13 SiO 1/2单元的含链烯基的树脂状有机聚硅氧烷,其中R 1为烷基且R 2为链烯基并且含有至少0.5质量%〜 小于3.5质量% (B)具有至少三个与硅键合的氢原子的有机聚硅氧烷; 和(C)氢化硅烷化反应催化剂。 可固化组合物提供了一种高度透明的固化的硅氧烷材料,其硬度范围为至少30至不大于80,25℃下的平行透光率为至少90%,平行光透射率为200° 在25℃下平行光透射率至少为99%
    • 3. 发明授权
    • Curable silicone composition that provides a highly transparent cured silicone material
    • 提供高度透明的固化硅胶材料的可固化硅酮组合物
    • US08853332B2
    • 2014-10-07
    • US13147320
    • 2010-01-29
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • C08G77/38B05D3/02C08L83/04C08G77/12C08G77/20
    • C08L83/04C08G77/12C08G77/20C08L83/00
    • A curable silicone composition comprises (A) (A-1) an alkenyl-containing dialkylpolysiloxane and a viscosity of at least 1,000 mPa·s to not more than 20,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl, that contains from 2.5 to 5.0 mass % alkenyl group, and that has a ratio for the total number of moles of R12R2SiO1/2 and R13SiO1/2 units to 1 mole of the SiO4/2 unit in the range from 0.70 to 1.10; (B) an organopolysiloxane that contains at least 0.9 mass % silicon-bonded hydrogen; and (C) a hydrosilylation reaction catalyst. The curable composition provides a bending-tolerant and highly transparent cured silicone material that has a hardness in the range from 80 to 95, and a parallel light transmittance at 200° C. of a value that is at least 99% of the parallel light transmittance at 25° C.
    • 一种可固化的有机硅组合物包含(A)(A-1)含链烯基的二烷基聚硅氧烷,并且粘度至少为1,000mPa·s至不超过20,000mPa·s,(A-2)含链烯基的树脂形式 包含SiO 4/2单元,R 12 R 2 SiO 1/2单元和R 13 SiO 1/2单元的有机聚硅氧烷,其中R 1是烷基,R 2是含有2.5-5.0质量%链烯基的烯基,并且具有总摩尔数 的R12R2SiO1 / 2和R13SiO1 / 2单元与1摩尔的SiO 4/2单元在0.70至1.10的范围内; (B)含有至少0.9质量%硅键合氢的有机聚硅氧烷; 和(C)氢化硅烷化反应催化剂。 可固化组合物提供硬度为80-95的弯曲耐受性和高度透明的固化的硅氧烷材料,并且在200℃下的平行光透射率为平行透光率的至少99% 在25°C
    • 4. 发明授权
    • Curable silicone composition
    • 可固化硅酮组合物
    • US08691910B2
    • 2014-04-08
    • US12671388
    • 2008-07-30
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • C08L83/07
    • C08L83/04C08G77/12C08G77/20C09D183/04C08L83/00
    • A curable silicone composition comprising: an alkenyl-containing organopolysiloxane (A) that contains: a dialkylpolysiloxane (A-1) having on average at least 2 alkenyl groups in one molecule having a 25° C. viscosity in the range of 5,000 to 35,000 mPa·s, and a alkenyl-containing organopolysiloxane resin (A-2) consisting of SiO4/2 units, R12R2SiO1/2 units, and R13SiO1/2 units (where R1 designates alkyl groups with 1 to 10 carbon atoms, and R2 designates alkenyl groups) with the content of alkenyl groups ranging from 3.5 to 5.0 mass %, and with the ratio of the sum of the mole numbers of the R12R2SiO1/2 units and R13SiO1/2 units to 1 mole of the SiO4/2 units in the range from 0.5 to 1.4; an organopolysiloxane (B), wherein silicon-bonded hydrogen atoms are in an amount of at least 0.7 mass %; and a hydrosilylation catalyst (C). The composition is capable of forming a flex-resistant highly transparent cured silicone product with non-tacky surface.
    • 一种可固化的有机硅组合物,其包含:含烯基的有机聚硅氧烷(A),其含有:在一分子中平均具有至少2个烯基的二烷基聚硅氧烷(A-1),其粘度在25〜35,000mPa s和由SiO 4/2单元组成的含烯基的有机聚硅氧烷树脂(A-2),R12R2SiO1 / 2单元和R13SiO1 / 2单元(其中R1表示具有1-10个碳原子的烷基,R2表示烯基 ),烯基的含量范围为3.5〜5.0质量%,R12R2SiO1 / 2单元和R13SiO1 / 2单元的摩尔数相对于1摩尔SiO 4/2单元的比例为 0.5〜1.4; 有机聚硅氧烷(B),其中与硅键合的氢原子的量为至少0.7质量%; 和氢化硅烷化催化剂(C)。 该组合物能够形成具有非粘性表面的耐挠曲高透明固化硅氧烷产品。
    • 5. 发明申请
    • Curable Silicone Composition
    • 可固化硅酮组合物
    • US20110077344A1
    • 2011-03-31
    • US12671388
    • 2008-07-30
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • Chiichiro HasegawaMakoto YoshitakeHiroshi Akitomo
    • C08L83/07
    • C08L83/04C08G77/12C08G77/20C09D183/04C08L83/00
    • A curable silicone composition comprising: an alkenyl-containing organopolysiloxane (A) that contains: a dialkylpolysiloxane (A-1) having on average at least 2 alkenyl groups in one molecule having a 25° C. viscosity in the range of 5,000 to 35,000 mPa·s, and a alkenyl-containing organopolysiloxane resin (A-2) consisting of SiO4/2 units, R12R2SiO1/2 units, and R13SiO1/2 units (where R1 designates alkyl groups with 1 to 10 carbon atoms, and R2 designates alkenyl groups) with the content of alkenyl groups ranging from 3.5 to 5.0 mass %, and with the ratio of the sum of the mole numbers of the R12R2SiO1/2 units and R13SiO1/2 units to 1 mole of the SiO4/2 units in the range from 0.5 to 1.4; an organopolysiloxane (B), wherein silicon-bonded hydrogen atoms are in an amount of at least 0.7 mass %; and a hydrosilylation catalyst (C). The composition is capable of forming a flex-resistant highly transparent cured silicone product with non-tacky surface.
    • 一种可固化的有机硅组合物,其包括:含烯基的有机聚硅氧烷(A),其含有:在一分子中平均具有至少2个烯基的二烷基聚硅氧烷(A-1),其粘度在25〜35,000mPa s和由SiO 4/2单元组成的含烯基的有机聚硅氧烷树脂(A-2),R12R2SiO1 / 2单元和R13SiO1 / 2单元(其中R1表示具有1-10个碳原子的烷基,R2表示烯基 ),烯基的含量范围为3.5〜5.0质量%,R12R2SiO1 / 2单元和R13SiO1 / 2单元的摩尔数相对于1摩尔SiO 4/2单元的比例为 0.5〜1.4; 有机聚硅氧烷(B),其中与硅键合的氢原子的量为至少0.7质量%; 和氢化硅烷化催化剂(C)。 该组合物能够形成具有非粘性表面的耐挠曲高透明固化硅氧烷产品。
    • 6. 发明申请
    • Curable Silicone Rubber Composition
    • 可固化硅橡胶组合物
    • US20110281123A1
    • 2011-11-17
    • US13147003
    • 2010-01-29
    • Hiroaki YoshidaNozomi IshigamiChiichiro HasegawaMakoto Yoshitake
    • Hiroaki YoshidaNozomi IshigamiChiichiro HasegawaMakoto Yoshitake
    • C09D183/05B32B27/06B05D3/10C08L83/05
    • C08L83/04C08G77/12C08G77/20C09D183/04Y10T428/31663C08L83/00
    • A curable silicone rubber composition comprises (A) an alkenyl-containing organopolysiloxane comprising (A-1) a dialkylpolysiloxane that has an average of at least two alkenyl groups in each molecule and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is C1-10 alkyl and R2 is alkenyl and that contains the alkenyl group in the range from more than 2.5 mass % to not more than 5.0 mass %; (B) an organopolysiloxane that contains the silicon-bonded hydrogen atom; and (C) a hydrosilylation reaction catalyst in a catalytic quantity. The curable composition provides a cured silicone material that has a hardness of not more than 75 and an elongation of at least 35%. Also, a composite in which the cured silicone material provided by the thermosetting of the curable composition is integrated into a single article with a substrate.
    • 一种可固化硅橡胶组合物包含(A)含有烯基的有机聚硅氧烷,其包含(A-1)在每个分子中平均具有至少两个烯基的二烷基聚硅氧烷和(A-2)含烯基的树脂形式的有机聚硅氧烷 其包含SiO 4/2单元,R 12 R 2 SiO 1/2单元和R 13 SiO 1/2单元,其中R 1是C 1-10烷基,R 2是链烯基并且含有在大于2.5质量%至不超过5.0质量%范围内的链烯基 %; (B)含有硅键合氢原子的有机聚硅氧烷; 和(C)催化剂的氢化硅烷化反应催化剂。 该固化性组合物提供硬度为75以下,伸长率为35%以上的固化的硅酮材料。 另外,将通过可固化组合物的热固化提供的固化的硅氧烷材料与基材整合成单个制品的复合材料。
    • 7. 发明申请
    • Curable Silicone Composition That Provides A Highly Transparent Cured Silicone Material
    • 提供高度透明的固化硅胶材料的可固化硅酮组合物
    • US20110294950A1
    • 2011-12-01
    • US13146995
    • 2010-01-29
    • Chiichiro HasegawaMakoto YoshtakeHiroshi Akitomo
    • Chiichiro HasegawaMakoto YoshtakeHiroshi Akitomo
    • C09D183/04B05D3/10C08L83/07
    • C08L83/04C08G77/12C08G77/20C09D183/04C08L83/00C08K5/56
    • A curable silicone composition comprises (A) (A-1) a dialkylpolysiloxane that has at least two alkenyl groups in each molecule and a viscosity of at least 1,000 mPa·s to not more than 50,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl and that contains the alkenyl group in the range from at least 0.5 mass % to less than 3.5 mass %; (B) an organopolysiloxane that has at least three silicon-bonded hydrogen atoms; and (C) a hydrosilylation reaction catalyst. The curable composition provides a highly transparent cured silicone material that has a hardness in the range from at least 30 to not more than 80, a parallel light transmittance at 25° C. of at least 90%, and a parallel light transmittance at 200° C. that is at least 99% of the parallel light transmittance at 25° C.
    • 可固化的有机硅组合物包含(A)(A-1)在每个分子中具有至少两个烯基的二烷基聚硅氧烷和至少1,000mPa·s至不大于50,000mPa·s的粘度和(A-2)a 含有SiO 4/2单元,R 12 R 21 SiO 1/2单元和R 13 SiO 1/2单元的含链烯基的树脂状有机聚硅氧烷,其中R 1为烷基且R 2为链烯基并且含有至少0.5质量%〜 小于3.5质量% (B)具有至少三个与硅键合的氢原子的有机聚硅氧烷; 和(C)氢化硅烷化反应催化剂。 可固化组合物提供了一种高度透明的固化的硅氧烷材料,其硬度范围为至少30至不大于80,25℃下的平行透光率为至少90%,平行光透射率为200° 在25℃下平行光透射率至少为99%