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    • 6. 发明授权
    • 2,6,6-Trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols and
-1,3-cyclohexadiene-1-methanols and organoleptic uses thereof
    • 2,6,6-三甲基-α-(异)丙烯-1-环己烯-1-甲醇和1,3-环己二烯-1-甲醇及其感官用途
    • US4278098A
    • 1981-07-14
    • US119858
    • 1980-02-08
    • Richard A. WilsonWilliam L. SchreiberBraja D. MookherjeeJacob KiwalaJoaquin F. VinalsManfred H. VockGilbert StorkFrederick L. Schmitt
    • Richard A. WilsonWilliam L. SchreiberBraja D. MookherjeeJacob KiwalaJoaquin F. VinalsManfred H. VockGilbert StorkFrederick L. Schmitt
    • A24B15/30A24B15/34C07C29/09C07C29/40C07C29/68C07C33/14C11B9/00A24B3/12A24B15/36
    • C11B9/0034A24B15/34C07C29/09C07C29/40C07C29/68C07C33/14C07C403/08C07B2200/09C07C2101/16
    • Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.Addition of one or more of the 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols or -1,3-cyclohexadiene-1-methanols of our invention to consumable materials is indicated to produce:A. In foodstuffs, chewing gums, toothpastes and medicinal products, sweet, camphoraceous, damascenone, raspberry-like, raspberry juice-like, rosey, woody/ionone-like, oriental, tobacco-like, tea-like, grape-like, fruity and ionone-like aromas and flavor notes;B. In perfumes, colognes and perfumed articles, leathery, hay, woody, mustard, minty, spicey (clove) and pulegone-like aromas and hay/tobacco and honey ionone-like topnotes with safronal-like nuances; andC. In tobaccos and tobacco flavors, a sweet-musty, hay-tobacco-like, fruity-raspberry, ionone-like aroma prior to smoking and a fruity tobacco-like, Virginia tobacco-like aroma on smoking both in the main stream and in the side stream.
    • 描述了用于食品,口香糖,牙膏和药用产品风味和香气,吸烟烟草风味和香气以及香料和香料制品香气增强,增强和赋予组合物的方法和组合物; 以及2,6,6-三甲基-α-(异)丙烯基-1-环己烯-1-甲醇的食品,口香糖,牙膏,药用产品,吸烟烟草,香料和香料制品香气和/或调味材料,以及 -1,3-环己二烯-1-甲醇衍生物或其一般结构定义的其几何或立体异构体中的一种或多种:其中R 1,R 2或R 3中的一个为甲基,R 1,R 2和R 3中的另外两个为 表示氢; 虚线是碳 - 碳双键或碳 - 碳单键; 条件是当R1是氢时,虚线是碳 - 碳双键。 将本发明的一种或多种2,6,6-三甲基-α-(异)丙烯-1-环己烯-1-甲醇或-1,3-环己二烯-1-甲醇添加到消耗材料中被指示产生 :A.在食品,口香糖,牙膏和药用产品中,甜,樟脑,大马士革,覆盆子样,覆盆子汁,玫瑰,木/紫罗兰酮样,东方,烟草状,茶状,葡萄状 ,水果和紫罗兰酮样香气和风味香气; B.香水,古龙水和香水制品,革质,干草,木质,芥末,小茴香,香料(丁香)和香菇样香气和干草/烟草和蜂蜜类似紫罗兰酮的顶峰,具有丰富的细微差别; 在烟草和烟草香料中,在吸烟之前是一种甜味,干草烟样,果香 - 覆盆子,类胡萝卜素的香气,并且在主流中吸烟时具有类似烟草般的弗吉尼亚烟草样香气 并在旁边的流。