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    • 6. 发明申请
    • PROCESS FOR THE PREPARATION OF FLOWABLE COMONOMER RICH POLYPROPYLENE
    • 制备流动性丰富的聚丙烯的方法
    • WO2011117224A1
    • 2011-09-29
    • PCT/EP2011/054312
    • 2011-03-22
    • BOREALIS AGTUOMINEN, OlliMALM, BoLESKINEN, Pauli
    • TUOMINEN, OlliMALM, BoLESKINEN, Pauli
    • C08F10/06C08F2/00C08F297/08C08L23/14C08F210/06
    • C08F210/06C08F110/06C08L23/14C08L23/16C08L2205/025C08L2205/03C08L2308/00C08F2/001C08F210/16C08F2500/12C08F2500/17
    • Process for producing a polypropylene composition, said composition comprises units derived from propylene and at least one C2 to C20 a -olefin other than propylene in an amount of at least 4.0 wt- % measured by Fourier transform infrared spectroscopy and given in wt.-%, and said process comprises the steps of producing in at least one first reactor a first polypropylene having a xylene cold soluble (XCS) content not exceeding 4.0 wt.-%, transferring said first polypropylene in a second reactor, producing in the second reactor in the presence of the first polypropylene a second polypropylene thereby obtaining a first polypropylene composition, said second polypropylene comprises units derived from propylene and at least one C2 to C20 a -olefin other than propylene in an amount of at least 9.0 wt-%, transferring said first polypropylene composition to a third reactor, producing in the third reactor in the presence of the first polypropylene composition a third polypropylene thereby obtaining the polypropylene composition, wherein said third polypropylene has a xylene cold soluble (XCS) content of below 9.0 wt- %, or • the intrinsic viscosity (IV) of the amorphous part (AM) of the xylene cold soluble (XCS) fraction of the third polypropylene is at least 3 dl/g.
    • 用于生产聚丙烯组合物的方法,所述组合物包含通过傅里叶变换红外光谱测量并且以重量%计的衍生自丙烯和至少一种丙烯以外的至少4.0重量%的至少4.0重量%的C 2 -C 20α-烯烃的单元, ,并且所述方法包括以下步骤:在至少一个第一反应器中生产具有不超过4.0重量%的二甲苯冷可溶物(XCS)含量的第一聚丙烯,在第二反应器中转移所述第一聚丙烯,在第二反应器中生产 第一聚丙烯存在第二聚丙烯,从而获得第一聚丙烯组合物,所述第二聚丙烯包含衍生自丙烯和至少一种量至少为9.0重量%的丙烯以外的至少一种C 2至C 20α-烯烃的单元,将所述 将第一聚丙烯组合物加入到第三反应器中,在第三聚丙烯组合物存在下在第三反应器中制备第三聚丙烯,由此得到 其中所述第三聚丙烯具有低于9.0重量%的二甲苯冷可溶物(XCS)含量,或者二甲苯冷可溶(XCS)部分的无定形部分(AM)的特性粘度(IV) 第三聚丙烯为至少3dl / g。
    • 8. 发明申请
    • RANDOM PROPYLENE COPOLYMERS FOR PIPES
    • 用于管道的随机丙烯共聚物
    • WO2011104100A1
    • 2011-09-01
    • PCT/EP2011/051611
    • 2011-02-03
    • Borealis AGBERGSTRA, MichielMALM, BoLESKINEN, PauliKOCK, CorneliaSUNDHOLM, Tua
    • BERGSTRA, MichielMALM, BoLESKINEN, PauliKOCK, CorneliaSUNDHOLM, Tua
    • C08L23/10
    • C08L23/10C08L2205/02C08L2666/06
    • Random propylene copolymer comprising (a) a first polypropylene being a first random propylene copolymer, said first random propylene copolymer has a melt flow rate MFR 10 (230 C) of not more than 1.5 g/10min, (b) a second polypropylene being a first propylene homopolymer or a second random propylene copolymer, (c) a third polypropylene being a second propylene homopolymer or a third random propylene copolymer, said third random propylene copolymer has a comonomer content of 0.5 to 3.5 wt. -%, wherein further (i) the first polypropylene differ from the second polypropylene and the third polypropylene by the melt flow rate MFR 2 (230 C) and/or by the comonomer content, (ii) the second polypropylene differ from the third polypropylene by the melt flow rate MFR 2 (230 C) and/or by the comonomer content [wt.-%], and (iii) the random propylene copolymer (R-PP) has a melt flow rate MFR 2 (230 C) of 0.05 to 10.00 g/10min.
    • 无规丙烯共聚物,其包含(a)第一无规丙烯共聚物的第一聚丙烯,所述第一无规丙烯共聚物的熔体流动速率MFR 10(230℃)不超过1.5g / 10min,(b)第二聚丙烯为第一 丙烯均聚物或第二无规丙烯共聚物,(c)第三聚丙烯是第二丙烯均聚物或第三无规丙烯共聚物,所述第三无规丙烯共聚物的共聚单体含量为0.5-3.5重量%。 - %,其中进一步(i)第一聚丙烯与第二聚丙烯和第三聚丙烯的熔体流动速率MFR 2(230℃)和/或共聚单体含量不同,(ii)第二聚丙烯与第三聚丙烯不同,第三聚丙烯通过 熔体流动速率MFR 2(230℃)和/或共聚单体含量[wt。-%],和(iii)无规丙烯共聚物(R-PP)的熔体流动速率MFR 2(230℃)为0.05-10.00 克/ 10分钟。
    • 10. 发明申请
    • POLYPROPYLENE COMPOSITION WITH HIGH STIFFNESS AND IMPACT STRENGTH
    • 具有高强度和抗冲击强度的聚丙烯组合物
    • WO2010089121A1
    • 2010-08-12
    • PCT/EP2010/000701
    • 2010-02-04
    • BOREALIS AGGAHLEITNER, MarkusMALM, BoBERNREITNER, KlausBRAUN, Juliane
    • GAHLEITNER, MarkusMALM, BoBERNREITNER, KlausBRAUN, Juliane
    • C08F10/06C08K3/00
    • C08F10/00C08F10/06C08F110/06C08F4/6543C08F4/6492C08F4/651C08F210/16C08F2500/04C08F2500/19C08F2500/12C08F2500/11C08F2500/20C08F2500/24
    • The present invention is directed to a polypropylene composition comprising a propylene homo- or copolymer (A) with a polydispersity index (Pl), determined according ISO 6721-1, of at least 5.8 Pa -1 ; and an inorganic filler (B) in an amount from 2.0 to 20 parts per weight based on 100 parts per weight of (A) + (B); The present invention is furthermore directed to a polypropylene composition comprising - a propylene homo- or copolymer (A); and an inorganic filler (B); whereby the following relation is fulfilled (80 F + 1700) MPa ≤ T wherein F are the parts per weight of component (B) based on 100 parts per weight of the total amount of (A) + (B). T is the tensile modulus in MPa, determined according to ISO 527-2, of the polypropylene composition measured on a test specimen prepared by injection molding according to ISO 1873-2. The present invention is also directed to a process for the production of the polypropylene compositions according to the invention and to an article made of the polypropylene compositions according to the invention. The present invention is furthermore directed to the use of the polypropylene compositions according to the invention for the production of pipes, car components, appliance housings, transport containers.
    • 本发明涉及一种聚丙烯组合物,其包含根据ISO 6721-1测定的至少5.8Pa-1的具有多分散指数(Pl)的丙烯均聚物或共聚物(A) 和每100重量份(A)+(B))为2.0〜20重量份的无机填料(B)。 本发明还涉及包含丙烯均聚物或共聚物(A)的聚丙烯组合物; 和无机填料(B); 由此满足以下关系(80 F + 1700)MPa = T其中F是基于(A)+(B)的总量的100重量份,组分(B)的每重量份数。 T是根据ISO 527-2测定的根据ISO 1873-2通过注射成型制备的试样上测量的聚丙烯组合物的拉伸弹性模量(MPa)。 本发明还涉及一种生产根据本发明的聚丙烯组合物和由本发明的聚丙烯组合物制成的制品的方法。 本发明还涉及根据本发明的聚丙烯组合物用于生产管道,汽车部件,电器外壳,运输容器的用途。