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1. 发明申请

WO2007106099A1 METHOD FOR THE PREPARATION OF ALPHA-BETA-UNSATURATED CARBONYL COMPOUNDS 审中-公开
标题翻译：制备阿尔法 - 不饱和碳化合物的方法
公开(公告)号：WO2007106099A1
公开(公告)日：2007-09-20
申请号：PCT/US2006/012696
申请日：2006-04-04
申请人： BATTELLE MEMORIAL INSTITUTE , CARGILL INCORPORATED , HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
发明人： HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
IPC分类号： C07C51/377 , C07C57/04
CPC分类号： C07C231/14 , C07C51/377 , Y02P20/127 , C07C57/04 , C07C233/09
摘要： A process is disclosed for conversion of ammonium salts of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., α, β-unsaturated carbonyl compounds and/or ammonium salts of α, β-unsaturated carbonyl compounds recovered at a high molar yield. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译：公开了用于转化形成有用转化产物的β-羟基羰基化合物的铵盐的方法，包括例如以高摩尔收率回收的β-不饱和羰基化合物和/或β-不饱和羰基化合物的铵盐。转化产物可用于例如原料和/或最终用途的化学品。

2. 发明申请

WO2007106100A1 METHOD AND APPARATUS FOR CONVERSION OF β -HYDROXY CARBONYL COMPOUNDS 审中-公开
标题翻译：用于转化β-羟基碳化合物的方法和装置
公开(公告)号：WO2007106100A1
公开(公告)日：2007-09-20
申请号：PCT/US2006/012697
申请日：2006-04-04
申请人： BATTELLE MEMORIAL INSTITUTE , CARGILL, INCORPORATED , ZACHER, Alan, H. , HOLLADAY, Johnathan, E. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
发明人： ZACHER, Alan, H. , HOLLADAY, Johnathan, E. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
IPC分类号： C07C57/065 , C07C231/12
CPC分类号： C07C51/377 , C07C57/04
摘要： A process and apparatus are disclosed for conversion of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., acrylic acid [CAS No. 79-10-7], acrylates, and acrylamide [CAS No. 79-06-01]. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译：公开了用于转化形成有用转化产物的β-羟基羰基化合物的方法和装置，包括例如丙烯酸[CAS No.79-10-7]，丙烯酸酯和丙烯酰胺[CAS No.79-06-01]。转化产物可用作例如原料和/或最终用途的化学品。

3. 发明申请

WO2007146836A1 HYDROXYMETHYLFURFURAL REDUCTION METHODS AND METHODS OF PRODUCING FURANDIMETHANOL 审中-公开
标题翻译：羟丙基纤维素还原方法及其制备方法
公开(公告)号：WO2007146836A1
公开(公告)日：2007-12-21
申请号：PCT/US2007/070802
申请日：2007-06-08
申请人： BATTELLE MEMORIAL INSTITUTE , LILGA, Michael, A. , HALLEN, Richard, T. , WERPY, Todd, A. , WHITE, James, F. , HOLLADAY, Johnathan, E. , FRYE, John, G. , ZACHER, Alan, H.
发明人： LILGA, Michael, A. , HALLEN, Richard, T. , WERPY, Todd, A. , WHITE, James, F. , HOLLADAY, Johnathan, E. , FRYE, John, G. , ZACHER, Alan, H.
IPC分类号： C07D307/12 , C07D307/40
CPC分类号： C07D307/12 , C07D307/40
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H 2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250°C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H 2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30°C. A method of producing tetrahydofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译：提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 H 2被提供到反应器中，起始材料与含有选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh中的至少一种金属的催化剂接触，温度小于或等于250℃。氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H 2 H 2和氢化催化剂。在30℃或更高的温度下，HMF相对于果糖选择性氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器中提供包含HMF的进料。进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。

4. 发明申请

WO2008054804A2 HYDROXYMETHYL FURFURAL OXIDATION METHODS 审中-公开
标题翻译：羟丙基氧化氧化方法
公开(公告)号：WO2008054804A2
公开(公告)日：2008-05-08
申请号：PCT/US2007/023063
申请日：2007-10-31
申请人： BATTELLE MEMORIAL INSTITUTE , LILGA, Michael, A. , HALLEN, Richard, T. , HU, Jianli , WHITE, James, F. , GARY, Michel, J.
发明人： LILGA, Michael, A. , HALLEN, Richard, T. , HU, Jianli , WHITE, James, F. , GARY, Michel, J.
IPC分类号： C07D307/44 , C07D307/48 , B01J23/00
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O 2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50°C to about 200°C A method of producing an oxidation catalyst where ZrO 2 is provided and is calcined. The ZrO 2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O 2 .
摘要翻译：氧化羟甲基糠醛（HMF）的方法包括在包含水的溶剂中将包含HMF的原料提供到反应器中。将空气和O 2 2中的至少一个提供到反应器中。使起始材料与载体材料上的Pt催化剂接触，在载体材料上进行接触，反应器温度为约50℃至约200℃的制备氧化催化剂的方法，其中ZrO 2 并被煅烧。将ZrO 2 2与乙酰丙酮酸铂（II）混合以形成混合物。将混合物进行旋转蒸发以形成产物。将产物在氢气下煅烧和还原以形成活化产物。活化产物在2％O 2 2的流下被钝化。

5. 发明申请

WO1998008784A3 METHOD OF PHOTOCATALYTIC CONVERSION OF C-H ORGANICS 审中-公开
公开(公告)号：WO1998008784A3
公开(公告)日：1998-03-05
申请号：PCT/US1997/015173
申请日：1997-08-27
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： CAMAIONI, Donald, M. , LILGA, Michael, A.
IPC分类号： C07C67/035
摘要： The present invention is the addition of a semiconductor material and energy to the reaction mixture of organic, acid (for example, trifluoroacetate), and oxygen. A transition metal ion may be added to the reaction mixture. The semiconductor material converts energy to oxidants thereby promoting oxidation of the organic. Alternatively, using metal in combination with exposure to light may be used.

6. 发明申请

WO1992017425A1 METHOD AND REACTION PATHWAY FOR SELECTIVELY OXIDIZING ORGANIC COMPOUNDS 审中-公开
标题翻译：用于选择性氧化有机化合物的方法和反应途径
公开(公告)号：WO1992017425A1
公开(公告)日：1992-10-15
申请号：PCT/US1992001492
申请日：1992-02-25
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： BATTELLE MEMORIAL INSTITUTE , CAMAIONI, Donald, M. , LILGA, Michael, A.
IPC分类号： C07B33/00
CPC分类号： C07B33/00 , C07C67/035 , C07C69/63
摘要： A method of selectively oxidizing an organic compound in a single vessel comprises: a) combining an organic compound, an acid solution in which the organic compound is soluble, a compound containing two oxygen atoms bonded to one another, and a metal ion reducing agent capable of reducing one of such oxygen atoms, and thereby forming a mixture; b) reducing the compound containing the two oxygen atoms by reducing one of such oxygen atoms with the metal ion reducing agent to, 1) oxidizing the metal ion reducing agent to a higher valence state, and 2) produce an oxygen containing intermediate capable of oxidizing the organic compound; c) reacting the oxygen containing intermediate with the organic compound to oxidize the organic compound into an oxidized organic intermediate, the oxidized organic intermediate having an oxidized carbon atom; d) reacting the oxidized organic intermediate with the acid counter ion and higher valence state metal ion to bond the acid counter ion to the oxidized carbon atom and thereby produce a quantity of an ester incorporating the organic intermediate and acid counter ion; and e) reacting the oxidized organic intermediate with the higher valence state metal ion and water to produce a quantity of alcohol which is less than the quantity of ester, the acid counter ion incorporated in the ester rendering the carbon atom bonded to the counter ion less reactive with the oxygen containing intermediate in the mixture than is the alcohol with the oxygen containing intermediate.
摘要翻译：选择性地氧化单个容器中的有机化合物的方法包括：a）将有机化合物，其中可溶于有机化合物的酸溶液，含有彼此键合的两个氧原子的化合物和能够还原的金属离子还原剂还原一个这样的氧原子，从而形成混合物; b）通过用金属离子还原剂还原一个这样的氧原子来还原含有两个氧原子的化合物，1）将金属离子还原剂氧化成更高的化合价，和2）产生能够氧化的含氧中间体有机化合物; c）使含氧中间体与有机化合物反应，将有机化合物氧化成氧化的有机中间体，氧化的有机中间体具有氧化的碳原子; d）使氧化的有机中间体与酸性抗衡离子和较高价态的金属离子反应，以将酸性抗衡离子键合到氧化的碳原子上，从而产生一定量的含有有机中间体和酸性抗衡离子的酯; 和e）使氧化的有机中间体与较高价态的金属离子和水反应以产生少于酯的量的醇，所述酯中掺入的酸抗衡离子使得与抗衡离子键合的碳原子较少与含氧中间体的醇相比，混合物中的含氧中间体具有反应性。

7. 发明申请

WO1988001535A1 PROCESS FOR RECOVERY OF HYDROGEN AND ABSTRACTION OF SULFUR 审中-公开
标题翻译：氢的回收和硫的回收方法
公开(公告)号：WO1988001535A1
公开(公告)日：1988-03-10
申请号：PCT/US1987002160
申请日：1987-08-27
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： BATTELLE MEMORIAL INSTITUTE , JAMES, Brian, R. , LI-LEE, Chung , LILGA, Michael, A. , NELSON, David, A.
IPC分类号： B01D53/14
CPC分类号： B01J31/4038 , B01J31/226 , B01J31/2404 , B01J2231/70 , B01J2531/0216 , B01J2531/0219 , B01J2531/824 , C01B3/04 , C01B17/05 , C07F15/0066 , Y02E60/364 , Y02P20/584
摘要： A process of abstracting sulfur from H2S and generating hydrogen comprising dissolving Pd2X2(mu-dppm)2 in a solvent and then introducing H2S. The palladium complex abstracts sulfur, forming hydrogen and a (mu-S) complex. The (mu-S) complex is readily oxidizable to a (mu-SO2) adduct which spontaneously loses SO2 and regenerates the palladium complex.

8. 发明公开

EP1328502A2 ESTER COMPOUNDS AND THEIR USE IN FORMING ACRYLATES 审中-公开
标题翻译：酯类化合物和使用用于生产丙烯酸（酯）
公开(公告)号：EP1328502A2
公开(公告)日：2003-07-23
申请号：EP01981437.5
申请日：2001-10-09
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： WERPY, Todd, A. , LILGA, Michael, A.
IPC分类号： C07C69/67 , C07C69/54 , C07C67/08 , C07C67/327 , C07C57/065
CPC分类号： C07C69/67 , C07C67/327 , C07C69/54
摘要： The present invention provides compounds having the formula wherein n is 0 or 1; R2 through R12 are independently selected from hydrogen, C1 to C10 alkyl, C6 to C10 aryl, C1 to C10 alkoxy, C1 to C10 aryloxy, C1 to C10 aralkyl; and R1 is hydrogen, C1 to C10 alkyl, C6 to C10 aryl, or C1 to C10 aralkyl. Methods of making and using these compounds are also described. Methods of converting α-hydroxy carboxylic esters and acids to acrylates are also described.

9. 发明申请

WO2015116695A1 CONVERSION OF 2,3-BUTANEDIOL TO BUTADIENE 审中-公开
标题翻译： 2,3-丁二醇转化为丁二烯
公开(公告)号：WO2015116695A1
公开(公告)日：2015-08-06
申请号：PCT/US2015/013312
申请日：2015-01-28
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： LILGA, Michael, A. , FRYE, Jr., John, G. , LEE, Suh-Jane , ALBRECHT, Karl, O.
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , B01J19/00 , B01J21/066 , B01J21/08 , B01J23/06 , B01J23/08 , B01J23/10 , B01J27/1806 , B01J37/031 , B01J37/04 , B01J37/086 , B01J37/088 , B01J2523/00 , B01J2523/33 , B01J2523/35 , B01J2523/3781 , B01J2523/48 , C07C1/2078 , C07C1/30 , C07C29/60 , C07C49/203 , C07C2521/04 , C07C2521/06 , C07C2523/02 , C07C2523/08 , C07C2523/10 , C07C2527/167 , C07C2529/40 , C07C2529/70 , C07C33/03 , C07C11/167 , B01J2523/31 , B01J2523/3706 , B01J2523/23 , B01J2523/3762 , B01J2523/3775 , B01J2523/3793 , B01J2523/27 , B01J2523/3743 , B01J2523/36 , B01J2523/25 , B01J2523/51 , B01J2523/11 , B01J2523/305 , B01J2523/22 , B01J2523/375 , B01J2523/3768 , B01J2523/3725 , B01J2523/3718 , B01J2523/3737 , B01J2523/3756 , B01J2523/3787 , B01J2523/3712 , B01J2523/68 , B01J2523/49 , B01J2523/69 , B01J2523/41
摘要： A composition comprising 2,3-butanediol is dehydrated to methyl vinyl carbinol and/or 1,3-butadiene by exposure to a catalyst comprising (a) M x O y wherein M is a rare earth metal, a group IIIA metal, Zr, or a combination thereof, and x and y are based upon an oxidation state of M, or (b) M 3 a (PO 4 ) b where M 3 is a group IA, a group IIA metal, a group IIIA metal, or a combination thereof, and a and b are based upon the oxidation state of M 3 . Embodiments of the catalyst comprising M x O y may further include M 2 , wherein M 2 is a rare earth metal, a group IIA metal, Zr, Al, or a combination thereof. In some embodiments, 2,3-butanediol is dehydrated to methyl vinyl carbinol and/or 1,3-butadiene by a catalyst comprising M x O y , and the methyl vinyl carbinol is subsequently dehydrated to 1,3-butadiene by exposure to a solid acid catalyst.
摘要翻译：包含2,3-丁二醇的组合物通过暴露于包含（a）MxOy的催化剂而脱水成甲基乙烯基甲醇和/或1,3-丁二烯，其中M是稀土金属，IIIA族金属，Zr或组合并且x和y基于M的氧化态，或（b）M3a（PO4）b，其中M3是基团IA，IIA族金属，IIIA族金属或其组合，以及a和 b基于M3的氧化态。包含M x O y的催化剂的实施方案可以进一步包括M2，其中M2是稀土金属，IIA族金属，Zr，Al或它们的组合。在一些实施方案中，通过包含M x O y的催化剂将2,3-丁二醇脱水成甲基乙烯基甲醇和/或1,3-丁二烯，然后通过暴露于固体酸催化剂将甲基乙烯基甲醇脱水为1,3-丁二烯。

10. 发明申请

WO1989012058A2 BRIDGED TRANSITION-METAL COMPLEXES AND USES THEREOF FOR HYDROGEN SEPARATION, STORAGE AND HYDROGENATION 审中-公开
标题翻译：桥接过渡金属复合物及其用于氢分离，储存和加氢的用途
公开(公告)号：WO1989012058A2
公开(公告)日：1989-12-14
申请号：PCT/US1989002338
申请日：1989-05-30
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： BATTELLE MEMORIAL INSTITUTE , LILGA, Michael, A. , HALLEN, Richard, T.
IPC分类号： C07F11/00
CPC分类号： C07F15/06 , C07F11/00 , C07F13/00 , C07F15/00
摘要： The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately pi-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancillary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H2 from mixed gas streams such as the product gas from coal gasification processes.

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